Active Hydrogenation Catalyst with a Structured, Peptide-Based Outer-Coordination Sphere

ACS Catalysis ◽  
2012 ◽  
Vol 2 (10) ◽  
pp. 2114-2118 ◽  
Author(s):  
Avijita Jain ◽  
Garry W. Buchko ◽  
Matthew L. Reback ◽  
Molly O’Hagan ◽  
Bojana Ginovska-Pangovska ◽  
...  
Keyword(s):  
Coordination Sphere ◽  
Hydrogenation Catalyst ◽  
Outer Coordination Sphere

Phenol Reduces Nitrite to NO at Copper(II): Role of a Proton-Responsive Outer Coordination Sphere in Phenol Oxidation

2020 ◽  
Vol 142 (4) ◽  
pp. 1726-1730 ◽  
Author(s):  
Aditesh Mondal ◽  
Kiran P. Reddy ◽  
Jeffery A. Bertke ◽  
Subrata Kundu
Keyword(s):  
Coordination Sphere ◽  
Phenol Oxidation ◽  
Outer Coordination Sphere

Macromolecular Engineering of the Outer Coordination Sphere of [2Fe-2S] Metallopolymers to Enhance Catalytic Activity for H2 Production

2018 ◽  
Vol 7 (11) ◽  
pp. 1383-1387 ◽  
Author(s):  
William P. Brezinski ◽  
Metin Karayilan ◽  
Kayla E. Clary ◽  
Keelee C. McCleary-Petersen ◽  
Liye Fu ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Coordination Sphere ◽  
H2 Production ◽  
Outer Coordination Sphere

Outer Coordination Sphere Proton Relay Base and Proximity Effects on Hydrogen Oxidation with Iron Electrocatalysts

2019 ◽  
Vol 38 (6) ◽  
pp. 1391-1396 ◽  
Author(s):  
Neeraj Kumar ◽  
Jonathan M. Darmon ◽  
Charles J. Weiss ◽  
Monte L. Helm ◽  
Simone Raugei ◽  
...  
Keyword(s):  
Coordination Sphere ◽  
Hydrogen Oxidation ◽  
Proximity Effects ◽  
Proton Relay ◽  
Outer Coordination Sphere

Chicken fat for catalysis: a scaffold is as important for molecular complexes for energy transformations as it is for enzymes in catalytic function

2019 ◽  
Vol 3 (12) ◽  
pp. 3260-3278 ◽  
Author(s):  
Joseph A. Laureanti ◽  
Molly O'Hagan ◽  
Wendy J. Shaw
Keyword(s):  
Coordination Sphere ◽  
Molecular Complexes ◽  
Catalytic Performance ◽  
Chicken Fat ◽  
Catalytic Function ◽  
Outer Coordination Sphere

The outer coordination sphere, sometimes called chicken fat, is essential to achieving the best catalytic performance for energy transductions.

scholarly journals Cover Picture: The Role of a Dipeptide Outer-Coordination Sphere on H2 -Production Catalysts: Influence on Catalytic Rates and Electron Transfer (Chem. Eur. J. 6/2013)

2013 ◽  
Vol 19 (6) ◽  
pp. 1837-1837
Author(s):  
Matthew L. Reback ◽  
Bojana Ginovska-Pangovska ◽  
Ming-Hsun Ho ◽  
Avijita Jain ◽  
Thomas C. Squier ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Coordination Sphere ◽  
H2 Production ◽  
Outer Coordination Sphere

Using the Outer Coordination Sphere to Tune the Strength of Metal Extractants

2011 ◽  
Vol 50 (10) ◽  
pp. 4515-4522 ◽  
Author(s):  
Ross S. Forgan ◽  
Benjamin D. Roach ◽  
Peter A. Wood ◽  
Fraser J. White ◽  
John Campbell ◽  
...  
Keyword(s):  
Coordination Sphere ◽  
Outer Coordination Sphere

Optimizing conditions for utilization of an H2 oxidation catalyst with outer coordination sphere functionalities

2016 ◽  
Vol 45 (24) ◽  
pp. 9786-9793 ◽  
Author(s):  
Arnab Dutta ◽  
Bojana Ginovska ◽  
Simone Raugei ◽  
John A. S. Roberts ◽  
Wendy J. Shaw
Keyword(s):  
Coordination Sphere ◽  
Oxidation Catalyst ◽  
Outer Coordination Sphere ◽  
H2 Oxidation

[Ni(PCy2NArginine2)2]2+ (CyArg) or [Ni(PCy2NBenzyl2)2]2+ (CyBn) were evaluated for H2 oxidation as a function of temperature, pressure, and solvent. 70 °C and 100 atm H2 result in a TOF of 1.1 × 106 s−1 and an overpotential of 240 mV for CyArg in water. In methanol the rates were 280 s−1 for CyArg and 80 s−1 for CyBn, demonstrating the importance of water and the outer coordination sphere (OCS).

Incorporating Peptides in the Outer-Coordination Sphere of Bioinspired Electrocatalysts for Hydrogen Production

2011 ◽  
Vol 50 (9) ◽  
pp. 4073-4085 ◽  
Author(s):  
Avijita Jain ◽  
Sheri Lense ◽  
John C. Linehan ◽  
Simone Raugei ◽  
Herman Cho ◽  
...  
Keyword(s):  
Hydrogen Production ◽  
Coordination Sphere ◽  
Outer Coordination Sphere
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