scholarly journals The effect of phosphorus on the catalytic performance of nickel oxide in ethane oxidative dehydrogenation

2016 ◽  
Vol 6 (18) ◽  
pp. 6953-6964 ◽  
Author(s):  
Ştefan-Bogdan Ivan ◽  
Ionel Popescu ◽  
Ioana Fechete ◽  
François Garin ◽  
Vasile I. Pârvulescu ◽  
...  

Adding P to NiO leads to a decrease of ethane conversion with an increase in ODH selectivity.

RSC Advances ◽  
2015 ◽  
Vol 5 (111) ◽  
pp. 91295-91301 ◽  
Author(s):  
Xin Chen ◽  
Qianli Yang ◽  
Bozhao Chu ◽  
Hang An ◽  
Yi Cheng

This work presents a new method of catalyst surface modification by using oxygen plasma to change the oxidation state of active sites in metal oxide catalysts.


2008 ◽  
Vol 9 (10) ◽  
pp. 2059-2062 ◽  
Author(s):  
Ji Chul Jung ◽  
Howon Lee ◽  
Heesoo Kim ◽  
Sunyoung Park ◽  
Young-Min Chung ◽  
...  

2017 ◽  
Vol 534 ◽  
pp. 58-69 ◽  
Author(s):  
E.V. Ishchenko ◽  
R.V. Gulyaev ◽  
T.Yu. Kardash ◽  
A.V. Ishchenko ◽  
E.Yu. Gerasimov ◽  
...  

Author(s):  
Aline Villarreal ◽  
Gabriella Garbarino ◽  
Paola Riani ◽  
Aida Gutiérrez Alejandre ◽  
Jorge Ramírez ◽  
...  

The influence of incorporating a small amount of silica on the catalytic performance of MoO3/Al2O3 catalyst was studied. Molybdenum supported on pure alumina and 5% SiO2-Al2O3 supports were synthesized. The catalysts were characterized by XRD, Raman, UV-Vis and IR spectroscopies, FE-SEM microscopy, and their activity was evaluated in the oxidative dehydrogenation of ethanol to acetaldehyde. Molybdenum supported on pure alumina gives a 74% yield to acetaldehyde (at 573 K) due to the generation of oxy-dehydrogenation active sites by molybdenum and to the decrement of the alumina dehydration sites. For the molybdenum catalyst supported on silica-containing alumina, the molybdenum species were displaced from the strongest alumina’s acid-base couples, located on nanoparticles edges, corners and defects, to weaker ones located on plane faces causing the rise of weakly bonded species with less active redox behavior.  


ACS Catalysis ◽  
2016 ◽  
Vol 6 (7) ◽  
pp. 4775-4781 ◽  
Author(s):  
Mimoun Aouine ◽  
Thierry Epicier ◽  
Jean-Marc M. Millet

2012 ◽  
Vol 445-446 ◽  
pp. 321-328 ◽  
Author(s):  
Piotr Michorczyk ◽  
Piotr Kuśtrowski ◽  
Paula Niebrzydowska ◽  
Anna Wach

Sign in / Sign up

Export Citation Format

Share Document