Effects of electrostatic interaction on the properties of ionic liquids correlated with the change of free volume

2017 ◽  
Vol 19 (7) ◽  
pp. 5389-5395 ◽  
Author(s):  
Zhengjian Chen ◽  
Yanan Huo ◽  
Panfeng Long ◽  
Hujun Shen ◽  
Jong-Min Lee
Keyword(s):  
Ionic Liquids ◽  
Free Volume ◽  
Electrostatic Interaction

Nearly half of the free volume was found to be compressed by the strong inter-ion electrostatic interaction in ionic liquids, which shows an inner connection with other properties.

scholarly journals Spectroscopic evidence of ‘jumping and pecking’ of cholinium and H-bond enhanced cation–cation interaction in ionic liquids

2015 ◽  
Vol 17 (46) ◽  
pp. 30978-30982 ◽  
Author(s):  
Anne Knorr ◽  
Koichi Fumino ◽  
Anne-Marie Bonsa ◽  
Ralf Ludwig
Keyword(s):  
Hydrogen Bonding ◽  
Ionic Liquids ◽  
Electrostatic Interaction ◽  
Spectroscopic Evidence

Spectroscopic evidence for cation–cation interaction in ionic liquids. The repulsive electrostatic interaction is overcome by hydrogen bonding between ions of like charge.

Modulating the immobilization process of Au nanoparticles on TiO2(110) by electrostatic interaction between the surface and ionic liquids

2011 ◽  
Vol 13 (30) ◽  
pp. 13585 ◽  
Author(s):  
Shushi Suzuki ◽  
Yasuhiro Ohta ◽  
Takashi Kurimoto ◽  
Susumu Kuwabata ◽  
Tsukasa Torimoto
Keyword(s):  
Ionic Liquids ◽  
Electrostatic Interaction ◽  
Au Nanoparticles

Carboxylate Ionic Liquids with Large Free Volume and Strong Hydrogen Bonding Basicity for Efficient Separation of Butadiene and n-Butene

2018 ◽  
Vol 57 (40) ◽  
pp. 13519-13527 ◽  
Author(s):  
Yuqi Huang ◽  
Tian Ke ◽  
Yuqi Ke ◽  
Qilong Ren ◽  
Qiwei Yang ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Ionic Liquids ◽  
Free Volume ◽  
Efficient Separation

scholarly journals Acidic Gases Solubility in Bis(2-Ethylhexyl) Sulfosuccinate Based Ionic Liquids Using the Predictive Thermodynamic Model

Membranes ◽  
2020 ◽  
Vol 10 (12) ◽  
pp. 429
Author(s):  
Amal Mechergui ◽  
Alsu I. Akhmetshina ◽  
Olga V. Kazarina ◽  
Maria E. Atlaskina ◽  
Anton N. Petukhov ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Ionic Liquids ◽  
Thermodynamic Properties ◽  
Present Article ◽  
Free Volume ◽  
Molecular Interactions ◽  
Thermodynamic Model ◽  
Acidic Gases ◽  
Screening Model ◽  
Hydrogen Bonding Interactions

To properly design ionic liquids (ILs) adopted for gases separation uses, a knowledge of ILs thermodynamic properties as well their solubilities with the gases is essential. In the present article, solubilities of CO2 and H2S in bis(2-Ethylhexyl)sulfosuccinate based ILs were predicted using the conductor like screening model for real solvents COSMO-RS. According to COSMO-RS calculations, the influence of the cation change was extensively analyzed. The obtained data are used for the prediction of adequate solvent candidates. Moreover, to understand the intrinsic behavior of gases solubility the free volume of the chosen ILs and their molecular interactions with respectively CO2 and H2S were computed. The results suggest that hydrogen bonding interactions in ILs and between ILs and the gases have a pivotal influence on the solubility.

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