A computational study of radical initiated protein backbone homolytic dissociation on all natural amino acids

2016 ◽  
Vol 18 (45) ◽  
pp. 30972-30981 ◽  
Author(s):  
Jon Uranga ◽  
Oier Lakuntza ◽  
Eloy Ramos-Cordoba ◽  
Jon M. Matxain ◽  
Jon I. Mujika
Keyword(s):  
Amino Acids ◽  
Hydroxyl Radical ◽  
Computational Study ◽  
Reactive Species ◽  
Protein Backbone ◽  
Natural Amino Acids ◽  
Homolytic Dissociation

Hydroxyl radical (˙OH) is known to be one of the most reactive species. The attack of this radical onto the backbone of all natural amino acids is investigated.

Synthesis and characteristics of ethylenediamine-N,N'-di-S-α-isovalerate and isomers of its cobalt(III) complexes

1982 ◽  
Vol 47 (1) ◽  
pp. 210-216 ◽  
Author(s):  
Milan Strašák ◽  
František Bachratý ◽  
Jaroslav Majer
Keyword(s):  
Amino Acids ◽  
Absolute Configuration ◽  
Electronic Absorption ◽  
Electronic Absorption Spectra ◽  
Chemical Parameters ◽  
Methyl Group ◽  
Nmr Data ◽  
Physico Chemical ◽  
Natural Amino Acids ◽  
C Nmr

The synthesis and physico-chemical parameters are described of a new complexone based on natural amino acids, viz. ethylenediamine-N,N'-di-S-α-isovalerate (SS-EDDIV). 1H- and 13C-NMR data revealed that the methyl group in the substance are not equivalent. The isomers of the cobalt(III) complex with the asymmetric tetradentate SS-EDDIV ligand were prepared and separated; their characteristics are given. The absolute configuration of two of the five theoretically feasible isomers was determined based on their electronic absorption spectra and circular dichroism data.

Biomimetic synthesis of esters of natural amino acids

2008 ◽  
Vol 19 (3) ◽  
pp. 252-255 ◽  
Author(s):  
Ivan T. Devedjiev ◽  
Stanislav G. Bairyamov ◽  
Vladimira S. Videva
Keyword(s):  
Amino Acids ◽  
Biomimetic Synthesis ◽  
Natural Amino Acids

Derivatives of natural amino acids as radioprotectors (review)

1995 ◽  
Vol 29 (7) ◽  
pp. 454-458 ◽  
Author(s):  
S. A. Kazaryan ◽  
K. P. Grigoryan ◽  
S. N. Airapetyan ◽  
O. L. Mndzhoyan
Keyword(s):  
Amino Acids ◽  
Natural Amino Acids ◽  
Derivatives Of
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