Supramolecular bidentate phosphine ligand scaffolds from deconstructed Hamilton receptors

2017 ◽  
Vol 53 (3) ◽  
pp. 561-564 ◽  
Author(s):  
Daniel T. Seidenkranz ◽  
Jacqueline M. McGrath ◽  
Lev N. Zakharov ◽  
Michael D. Pluth
Keyword(s):  
Self Assembly ◽  
Phosphine Ligand ◽  
Bidentate Phosphine ◽  
Ligand Scaffolds ◽  
Bidentate Phosphine Ligand

The metal-assisted self-assembly of a phosphine-modified, deconstructed Hamilton receptor is reported as a new supramolecular ligand scaffold.

P–N bond formation as a route to a highly electron rich bidentate phosphine ligand and its application in homogenous catalysis

2001 ◽  
pp. 969-971 ◽  
Author(s):  
Mireia Rodriguez i Zubiri ◽  
Matthew L. Clarke ◽  
Douglas F. Foster ◽  
David J. Cole-Hamilton ◽  
Alexandra M. Z. Slawin ◽  
...  
Keyword(s):  
Bond Formation ◽  
Phosphine Ligand ◽  
Homogenous Catalysis ◽  
Bidentate Phosphine ◽  
Bidentate Phosphine Ligand

A new strategy to synthesize three-coordinate mononuclear copper(i) halide complexes containing a bulky terphenyl bidentate phosphine ligand and their luminescent properties

2019 ◽  
Vol 43 (8) ◽  
pp. 3390-3399 ◽  
Author(s):  
Li-Ping Liu ◽  
Rui Zhang ◽  
Li Liu ◽  
Xin-Xin Zhong ◽  
Fa-Bao Li ◽  
...  
Keyword(s):  
Solid State ◽  
Room Temperature ◽  
Green Emission ◽  
Luminescent Properties ◽  
Phosphine Ligand ◽  
New Strategy ◽  
Bidentate Phosphine ◽  
Halide Complexes ◽  
Bidentate Phosphine Ligand

Three mononuclear three-coordinate Cu(i) halide complexes were synthesized by a new strategy and they exhibit green to yellow green emission in the solid state at room temperature.

[1,3-Bis(diphenylphosphino)propane]tetracarbonylchromium(0)

2006 ◽  
Vol 62 (5) ◽  
pp. m1086-m1087 ◽  
Author(s):  
Omar bin Shawkataly ◽  
Shahinoor Dulal Islam ◽  
Hoong-Kun Fun ◽  
Claude Didierjean
Keyword(s):  
Phosphine Ligand ◽  
Carbonyl Ligands ◽  
Bond Lengths ◽  
Bidentate Phosphine ◽  
Title Molecule ◽  
Bidentate Phosphine Ligand

In the title molecule, [Cr(C27H26P2)(CO)4], the Cr atom is octahedrally coordinated by the four carbonyl ligands and a bidentate phosphine ligand, which is bonded as a chelate in a cis position. The average Cr—P and Cr—C bond lengths are 2.3770 (5) and 1.865 (2) Å, respectively.

Notizen: Darstellung und Kristallstruktur einkerniger, paramagnetischer Pd- und Pt-Komplexe/ Preparation and Crystal Structure of Mononuclear, Paramagnetic Pd- and Pt-Complexes

1985 ◽  
Vol 40 (8) ◽  
pp. 1093-1096 ◽  
Author(s):  
Dieter Fenske ◽  
Walter Bensmann
Keyword(s):  
Crystal Structure ◽  
Unpaired Electron ◽  
Phosphine Ligand ◽  
X Ray ◽  
Mononuclear Complexes ◽  
Bidentate Phosphine ◽  
Bidentate Phosphine Ligand

Abstract[2,3-Bis(diphenylphosphino)m aleicanhydride]- MCl2 (M = Pd, Pt) reacts with M (PPh3)4 (M = Pd, Pt) to form paramagnetic, mononuclear complexes of Pd (Pt). It is shown by EPR , IR and X-ray examination, that the unpaired electron is delocalized on the bidentate phosphine ligand.

scholarly journals Crystal structure of [1,2-bis(diphenylphosphanyl)benzene]heptacarbonyldi-μ-hydrido-(μ3-2,4,6-trimethylphenylphosphinidene)-triangulo-triruthenium

2017 ◽  
Vol 73 (7) ◽  
pp. 945-948
Author(s):  
Taeko Kakizawa
Keyword(s):  
Crystal Structure ◽  
Title Compound ◽  
Benzene Molecule ◽  
Phosphine Ligand ◽  
Asymmetric Unit ◽  
Ruthenium Cluster ◽  
Bidentate Phosphine ◽  
Independent Molecules ◽  
Bidentate Phosphine Ligand

The title trinuclear ruthenium cluster, [Ru3(C30H24P2)(C9H11P)(CO)7(μ-H)2], has a triangular Ru3core that is capped with a mesitylphosphinidene ligand, μ3-PMes (Mes = mesityl = 2,4,6-trimethylphenyl). The 1,2-bis(diphenylphosphanyl)benzene molecule acts as a bidentate phosphine ligandviatwo P atoms connecting to a single Ru atom. The title compound crystallizes with two independent molecules in the asymmetric unit.

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