[{β-SiNi2W10O36(OH)2(H2O)}4]24−: a new robust visible light-driven water oxidation catalyst based on nickel-containing polyoxometalate

2016 ◽  
Vol 52 (100) ◽  
pp. 14494-14497 ◽  
Author(s):  
Li Yu ◽  
Yong Ding ◽  
Min Zheng ◽  
Hongli Chen ◽  
Junwei Zhao
Keyword(s):  
Visible Light ◽  
Nickel Oxide ◽  
Water Oxidation ◽  
Oxidation Catalyst ◽  
Visible Light Driven

We report an all-new nickel-containing POM catalyst [{β-SiNi2W10O36(OH)2(H2O)}4]24− (1) that catalyzes water oxidation under visible light. Multiple experiments confirm that 1 acts as an active and dominant catalyst rather than Ni2+ ions (aq) or nickel oxide during the water oxidation.

scholarly journals Visible light-driven water oxidation using a covalently-linked molecular catalyst–sensitizer dyad assembled on a TiO2 electrode

2016 ◽  
Vol 7 (2) ◽  
pp. 1430-1439 ◽  
Author(s):  
Masanori Yamamoto ◽  
Lei Wang ◽  
Fusheng Li ◽  
Takashi Fukushima ◽  
Koji Tanaka ◽  
...  
Keyword(s):  
Visible Light ◽  
Water Oxidation ◽  
Ruthenium Complex ◽  
Oxidation Catalyst ◽  
Tio2 Electrode ◽  
Molecular Catalyst ◽  
Highly Efficient ◽  
Visible Light Driven ◽  
Artificial Photosynthetic ◽  
Covalently Linked

The combination of porphyrin as a sensitizer and a ruthenium complex as a water oxidation catalyst (WOC) is promising to exploit highly efficient molecular artificial photosynthetic systems.

(Invited) Visible Light-Driven Water Oxidation with Porphyrin Sensitizers and Water Oxidation Catalysts

2018 ◽  
Vol MA2018-01 (31) ◽  
pp. 1852-1852
Author(s):  
Hiroshi Imahori
Keyword(s):  
Excited State ◽  
Visible Light ◽  
Water Oxidation ◽  
Light Harvesting ◽  
Visible Region ◽  
Oxidation Catalyst ◽  
Efficient Production ◽  
Oxidation Catalysts ◽  
Visible Light Driven ◽  
Artificial Photosynthetic

Exporing renewable energy sources is an important task in making our society sustainable. In this regard, use of sunlight as an infinite energy source is fascinating. Specifically, realizing artificial photosynthesis, i.e., integration of light-harvesting, multi-step electron and proton transfer, and water oxidation for the efficient production of solar fuels, is a great challenge in chemistry. For the purpose, dye-sensitized photoelectrosynthesis cells (DSPSC) have been investigated, as the heterogeneous water splitting on inorganic semiconductors is promising for the upcoming large scale device operation. In DSPSC a molecular sensitizer adsorbed on a semiconducting electrode harvests visible light and injects an electron from the excited-state of the sensitizer (S*) to a conduction band (CB) of the electrode. Then, the sensitizer radical cation (S• +) extracts an electron from a water oxidation catalyst (WOC) to regenerate the sensitizer and one-electron oxidized WOC. After reiterating the cycle, high oxidation states of the WOC are produced, eventually transforming two water molecules into four protons and one oxygen molecule. As the sensitizer bis(2,2’-bipyridine)(4,4’-diphosphonato-2,2’-bipyridine)ruthenium(II) (RuP) has been frequently employed for the construction of molecule-based artificial photosynthetic systems, owing to its sufficient first oxidation potential for water oxidation and a long lifetime of its excited state for electron injection. However, the light-harvesting ability of RuP is rather low in visible region beyond 500 nm. Considering that yellow to red photons mainly shower down on the earth from sun, use of photons in visible region is essential for efficient chemical conversion by sunlight. In this context, porphyrins are attractive as the sensitizer due to their excellent light-harvesting in visible region and facile tuning of their excited-states and redox properties by their chemical functionalization. Nevertheless, molecule-based artificial photosynthetic systems with porphyrins as the sensitizer have been very limited as the result of their poor performance. One plausible reason is the occurrence of fast charge recombination (CR) between the electron injected into the CB of TiO2 (denoted as TiO2(e−)) and S• +. CR from TiO2(e−) to the oxidized WOC would also take place within a few microsecond. Undesirable CR from TiO2(e−) to water is indicated. Thus, to overcome the disadvantages, it is crucial to optimize the electron transfer (ET) processes at the interfaces. In this talk, I will give an overview of our recent initiatives on visible light-driven water oxidation with novel porphyrin sensitizers and water oxidation catalysts. [1] M. Yamamoto, L. Wang, F. Li, T. Fukushima, K. Tanaka, L. Sun and H. Imahori, Chem. Sci., 7, 1430-1439 (2016). [2] M. Yamamoto, Y. Nishizawa, P. Chábera, F. Li, T. Pascher, V. Sundström, L. Sun, and H. Imahori, Chem. Commun., 52, 13702-13705 (2016). [3] M. Yamamoto, J. Föhlinger, J. Petersson, L. Hammarström, and H. Imahori, Angew. Chem. Int. Ed., 56, 3329-3333 (2017).

scholarly journals Visible light-driven water oxidation with a ruthenium sensitizer and a cobalt-based catalyst connected with a polymeric platform

2019 ◽  
Vol 215 ◽  
pp. 111-122 ◽  
Author(s):  
Zeynep Kap ◽  
Ferdi Karadas
Keyword(s):  
Visible Light ◽  
Prussian Blue ◽  
Water Oxidation ◽  
Oxidation Catalyst ◽  
Visible Light Driven ◽  
Type Water

A novel PS–WOC dyad which incorporates a ruthenium-based photosensitizer (PS) connected to a Prussian blue type water oxidation catalyst (WOC) through a P4VP platform is presented.

Nanoscale cobalt metal–organic framework as a catalyst for visible light-driven and electrocatalytic water oxidation

2016 ◽  
Vol 40 (4) ◽  
pp. 3032-3035 ◽  
Author(s):  
Qian Xu ◽  
Hui Li ◽  
Fan Yue ◽  
Le Chi ◽  
Jide Wang
Keyword(s):  
Visible Light ◽  
Water Oxidation ◽  
Metal Organic Framework ◽  
Oxidation Catalyst ◽  
Cobalt Metal ◽  
Visible Light Driven ◽  
Metal Organic ◽  
Organic Framework

Co-ZIF-67 is proposed as an efficient water oxidation catalyst under visible light.

scholarly journals Photoinduced hole transfer from tris(bipyridine)ruthenium dye to a high-valent iron-based water oxidation catalyst

2019 ◽  
Vol 215 ◽  
pp. 162-174 ◽  
Author(s):  
Sergii I. Shylin ◽  
Mariia V. Pavliuk ◽  
Luca D’Amario ◽  
Igor O. Fritsky ◽  
Gustav Berggren
Keyword(s):  
Visible Light ◽  
Water Oxidation ◽  
Oxidation Catalyst ◽  
Scavenging Activity ◽  
Hole Transfer ◽  
Cage Complex ◽  
Visible Light Driven ◽  
Iron Based ◽  
High Valent ◽  
Ruthenium Dye

Fast visible light-driven water oxidation catalyzed by the FeIV cage complex relies on its efficient hole scavenging activity in the system utilizing [Ru(bpy)3]2+ as a photosensitizer.

scholarly journals Hybrid photoanodes for visible light-driven water oxidation: the beneficial and detrimental effects of nickel oxide cocatalyst

2020 ◽  
Vol 2 (4) ◽  
pp. 044001
Author(s):  
Pimchanok Longchin ◽  
Dariusz Mitoraj ◽  
Oliver Mendoza Reyes ◽  
Christiane Adler ◽  
Natda Wetchakun ◽  
...  
Keyword(s):  
Visible Light ◽  
Nickel Oxide ◽  
Water Oxidation ◽  
Visible Light Driven

scholarly journals Correction: [{β-SiNi2W10O36(OH)2(H2O)}4]24−: a new robust visible light-driven water oxidation catalyst based on nickel-containing polyoxometalate

2016 ◽  
Vol 52 (100) ◽  
pp. 14498-14499 ◽  
Author(s):  
Li Yu ◽  
Yong Ding ◽  
Min Zheng ◽  
Hongli Chen ◽  
Junwei Zhao
Keyword(s):  
Visible Light ◽  
Water Oxidation ◽  
Oxidation Catalyst ◽  
Li Yu ◽  
Visible Light Driven

Correction for ‘[{β-SiNi2W10O36(OH)2(H2O)}4]24−: a new robust visible light-driven water oxidation catalyst based on nickel-containing polyoxometalate’ by Li Yu et al., Chem. Commun., 2016, DOI: 10.1039/c6cc02728h.

scholarly journals Water splitting with polyoxometalate-treated photoanodes: enhancing performance through sensitizer design

2015 ◽  
Vol 6 (10) ◽  
pp. 5531-5543 ◽  
Author(s):  
John Fielden ◽  
Jordan M. Sumliner ◽  
Nannan Han ◽  
Yurii V. Geletii ◽  
Xu Xiang ◽  
...  
Keyword(s):  
Visible Light ◽  
Water Splitting ◽  
Water Oxidation ◽  
Oxidation Catalyst ◽  
Dye Sensitized ◽  
Visible Light Driven

Improved sensitizer design dramatically enhances visible light-driven water oxidation from dye-sensitized TiO2 photoanodes treated with polyoxometalate water oxidation catalyst [{Ru4O4(OH)2(H2O)4}(γ-SiW10O36)2]10−.

Visible light-driven water oxidation with a subporphyrin sensitizer and a water oxidation catalyst

2016 ◽  
Vol 52 (94) ◽  
pp. 13702-13705 ◽  
Author(s):  
Masanori Yamamoto ◽  
Yusuke Nishizawa ◽  
Pavel Chábera ◽  
Fusheng Li ◽  
Torbjörn Pascher ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Visible Light ◽  
Light Absorption ◽  
Water Oxidation ◽  
Artificial Photosynthesis ◽  
Oxidation Catalyst ◽  
Interfacial Electron Transfer ◽  
Visible Light Absorption ◽  
Visible Light Driven

A newly designed contracted porphyrin achieved efficient visible light absorption and interfacial electron transfer for water oxidation in artificial photosynthesis.

scholarly journals Au decorated BiVO4 inverse opal for efficient visible light driven water oxidation

RSC Advances ◽  
2021 ◽  
Vol 11 (15) ◽  
pp. 8751-8758
Author(s):  
Xiaonong Wang ◽  
Xiaoxia Li ◽  
Jingxiang Low
Keyword(s):  
Visible Light ◽  
Water Splitting ◽  
Water Oxidation ◽  
Inverse Opal ◽  
Photocatalytic Water Splitting ◽  
Visible Light Driven

Photocatalytic water splitting provides an effective way to prepare hydrogen and oxygen.

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