Visible light-driven water oxidation with a subporphyrin sensitizer and a water oxidation catalyst

2016 ◽  
Vol 52 (94) ◽  
pp. 13702-13705 ◽  
Author(s):  
Masanori Yamamoto ◽  
Yusuke Nishizawa ◽  
Pavel Chábera ◽  
Fusheng Li ◽  
Torbjörn Pascher ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Visible Light ◽  
Light Absorption ◽  
Water Oxidation ◽  
Artificial Photosynthesis ◽  
Oxidation Catalyst ◽  
Interfacial Electron Transfer ◽  
Visible Light Absorption ◽  
Visible Light Driven

A newly designed contracted porphyrin achieved efficient visible light absorption and interfacial electron transfer for water oxidation in artificial photosynthesis.

Efficient difunctional photocatalyst prepared in situ from Prussian blue analogues for catalytic water oxidation and visible-light absorption

2018 ◽  
Vol 8 (24) ◽  
pp. 6375-6383 ◽  
Author(s):  
Jia Guo ◽  
Hui Li ◽  
Di Wang ◽  
Liugen Zhang ◽  
Yuhua Ma ◽  
...  
Keyword(s):  
Visible Light ◽  
Prussian Blue ◽  
Light Absorption ◽  
Water Oxidation ◽  
Cuo Nanoparticles ◽  
Oxidation Catalysts ◽  
Visible Light Absorption ◽  
Prussian Blue Analogues ◽  
Visible Light Driven

Co(OH)2-modified CuO (Co(OH)2/CuO) nanoparticles serve as both visible-light-driven water oxidation catalysts and visible-light-absorption centers.

scholarly journals Visible light-driven water oxidation using a covalently-linked molecular catalyst–sensitizer dyad assembled on a TiO2 electrode

2016 ◽  
Vol 7 (2) ◽  
pp. 1430-1439 ◽  
Author(s):  
Masanori Yamamoto ◽  
Lei Wang ◽  
Fusheng Li ◽  
Takashi Fukushima ◽  
Koji Tanaka ◽  
...  
Keyword(s):  
Visible Light ◽  
Water Oxidation ◽  
Ruthenium Complex ◽  
Oxidation Catalyst ◽  
Tio2 Electrode ◽  
Molecular Catalyst ◽  
Highly Efficient ◽  
Visible Light Driven ◽  
Artificial Photosynthetic ◽  
Covalently Linked

The combination of porphyrin as a sensitizer and a ruthenium complex as a water oxidation catalyst (WOC) is promising to exploit highly efficient molecular artificial photosynthetic systems.

scholarly journals Synergistic effect of Ni–Ag–rutile TiO2 ternary nanocomposite for efficient visible-light-driven photocatalytic activity

RSC Advances ◽  
2020 ◽  
Vol 10 (60) ◽  
pp. 36930-36940 ◽  
Author(s):  
Petri M. Leukkunen ◽  
Ekta Rani ◽  
Assa Aravindh Sasikala Devi ◽  
Harishchandra Singh ◽  
Graham King ◽  
...  
Keyword(s):  
Photocatalytic Activity ◽  
Synergistic Effect ◽  
Visible Light ◽  
Light Absorption ◽  
Charge Separation ◽  
Effective Charge ◽  
Energy Dispersive ◽  
Intimate Contact ◽  
Visible Light Absorption ◽  
Visible Light Driven

Robust photocatalytic activity of Ni–Ag–RTiO2 is attributed to the improved visible light absorption and effective charge separation due to intimate contact between Ni and RTiO2via Ag, as evidenced by Ti3+ in Ti 2p XPS and energy dispersive mapping.

(Invited) Visible Light-Driven Water Oxidation with Porphyrin Sensitizers and Water Oxidation Catalysts

2018 ◽  
Vol MA2018-01 (31) ◽  
pp. 1852-1852
Author(s):  
Hiroshi Imahori
Keyword(s):  
Excited State ◽  
Visible Light ◽  
Water Oxidation ◽  
Light Harvesting ◽  
Visible Region ◽  
Oxidation Catalyst ◽  
Efficient Production ◽  
Oxidation Catalysts ◽  
Visible Light Driven ◽  
Artificial Photosynthetic

Exporing renewable energy sources is an important task in making our society sustainable. In this regard, use of sunlight as an infinite energy source is fascinating. Specifically, realizing artificial photosynthesis, i.e., integration of light-harvesting, multi-step electron and proton transfer, and water oxidation for the efficient production of solar fuels, is a great challenge in chemistry. For the purpose, dye-sensitized photoelectrosynthesis cells (DSPSC) have been investigated, as the heterogeneous water splitting on inorganic semiconductors is promising for the upcoming large scale device operation. In DSPSC a molecular sensitizer adsorbed on a semiconducting electrode harvests visible light and injects an electron from the excited-state of the sensitizer (S*) to a conduction band (CB) of the electrode. Then, the sensitizer radical cation (S• +) extracts an electron from a water oxidation catalyst (WOC) to regenerate the sensitizer and one-electron oxidized WOC. After reiterating the cycle, high oxidation states of the WOC are produced, eventually transforming two water molecules into four protons and one oxygen molecule. As the sensitizer bis(2,2’-bipyridine)(4,4’-diphosphonato-2,2’-bipyridine)ruthenium(II) (RuP) has been frequently employed for the construction of molecule-based artificial photosynthetic systems, owing to its sufficient first oxidation potential for water oxidation and a long lifetime of its excited state for electron injection. However, the light-harvesting ability of RuP is rather low in visible region beyond 500 nm. Considering that yellow to red photons mainly shower down on the earth from sun, use of photons in visible region is essential for efficient chemical conversion by sunlight. In this context, porphyrins are attractive as the sensitizer due to their excellent light-harvesting in visible region and facile tuning of their excited-states and redox properties by their chemical functionalization. Nevertheless, molecule-based artificial photosynthetic systems with porphyrins as the sensitizer have been very limited as the result of their poor performance. One plausible reason is the occurrence of fast charge recombination (CR) between the electron injected into the CB of TiO2 (denoted as TiO2(e−)) and S• +. CR from TiO2(e−) to the oxidized WOC would also take place within a few microsecond. Undesirable CR from TiO2(e−) to water is indicated. Thus, to overcome the disadvantages, it is crucial to optimize the electron transfer (ET) processes at the interfaces. In this talk, I will give an overview of our recent initiatives on visible light-driven water oxidation with novel porphyrin sensitizers and water oxidation catalysts. [1] M. Yamamoto, L. Wang, F. Li, T. Fukushima, K. Tanaka, L. Sun and H. Imahori, Chem. Sci., 7, 1430-1439 (2016). [2] M. Yamamoto, Y. Nishizawa, P. Chábera, F. Li, T. Pascher, V. Sundström, L. Sun, and H. Imahori, Chem. Commun., 52, 13702-13705 (2016). [3] M. Yamamoto, J. Föhlinger, J. Petersson, L. Hammarström, and H. Imahori, Angew. Chem. Int. Ed., 56, 3329-3333 (2017).

Understanding the electron transfer process in ZnO–naphthol azobenzoic acid composites from photophysical characterisation

2016 ◽  
Vol 18 (32) ◽  
pp. 22179-22187 ◽  
Author(s):  
Leena George ◽  
Athira K. Kunhikannan ◽  
Rajith Illathvalappil ◽  
Divya Ottoor ◽  
Sreekumar Kurungot ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Visible Light ◽  
Transfer Process ◽  
Light Absorption ◽  
Organic Molecules ◽  
Semiconductor Nanoparticles ◽  
Electron Transfer Process ◽  
Visible Light Absorption ◽  
Catalytic Sites ◽  
Surface Modified

Semiconductor nanoparticles surface modified with organic molecules capable of visible light absorption and effectively transferring the electrons to the catalytic sites have the potential to be good photocatalysts.

scholarly journals Visible-Light Driven TiO2 Photocatalyst Coated with Graphene Quantum Dots of Tunable Nitrogen Doping

Molecules ◽  
2019 ◽  
Vol 24 (2) ◽  
pp. 344 ◽  
Author(s):  
Xiong Sun ◽  
Hui-Jun Li ◽  
Nanquan Ou ◽  
Bowen Lyu ◽  
Bojie Gui ◽  
...  
Keyword(s):  
Quantum Dots ◽  
Photocatalytic Activity ◽  
Visible Light ◽  
Light Absorption ◽  
Photocatalytic Performance ◽  
Light Emission ◽  
Graphene Quantum Dots ◽  
Visible Light Absorption ◽  
Visible Light Driven ◽  
Nitrogen Doped Graphene

Nitrogen doped graphene quantum dots (NGQDs) were successfully prepared via a hydrothermal method using citric acid and urea as the carbon and nitrogen precursors, respectively. Due to different post-treatment processes, the obtained NGQDs with different surface modifications exhibited blue light emission, while their visible-light absorption was obviously different. To further understand the roles of nitrogen dopants and N-containing surface groups of NGQDs in the photocatalytic performance, their corresponding composites with TiO2 were utilized to degrade RhB solutions under visible-light irradiation. A series of characterization and photocatalytic performance tests were carried out, which demonstrated that NGQDs play a significant role in enhancing visible-light driven photocatalytic activity and the carrier separation process. The enhanced photocatalytic activity of the NGQDs/TiO2 composites can possibly be attributed to an enhanced visible light absorption ability, and an improved separation and transfer rate of photogenerated carriers.

scholarly journals Visible light-driven water oxidation with a ruthenium sensitizer and a cobalt-based catalyst connected with a polymeric platform

2019 ◽  
Vol 215 ◽  
pp. 111-122 ◽  
Author(s):  
Zeynep Kap ◽  
Ferdi Karadas
Keyword(s):  
Visible Light ◽  
Prussian Blue ◽  
Water Oxidation ◽  
Oxidation Catalyst ◽  
Visible Light Driven ◽  
Type Water

A novel PS–WOC dyad which incorporates a ruthenium-based photosensitizer (PS) connected to a Prussian blue type water oxidation catalyst (WOC) through a P4VP platform is presented.

Nanoscale cobalt metal–organic framework as a catalyst for visible light-driven and electrocatalytic water oxidation

2016 ◽  
Vol 40 (4) ◽  
pp. 3032-3035 ◽  
Author(s):  
Qian Xu ◽  
Hui Li ◽  
Fan Yue ◽  
Le Chi ◽  
Jide Wang
Keyword(s):  
Visible Light ◽  
Water Oxidation ◽  
Metal Organic Framework ◽  
Oxidation Catalyst ◽  
Cobalt Metal ◽  
Visible Light Driven ◽  
Metal Organic ◽  
Organic Framework

Co-ZIF-67 is proposed as an efficient water oxidation catalyst under visible light.

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