scholarly journals A fishing rod-like conjugated polymer bearing pillar[5]arenes

2016 ◽  
Vol 52 (40) ◽  
pp. 6662-6664 ◽  
Author(s):  
Yingjie Ma ◽  
Long Chen ◽  
Chen Li ◽  
Klaus Müllen

A novel diethynyl functionalized pillar[5]arene, that is a pentabenzenacyclodecaphane derivative, has been synthesized and polymerized with p-dihalobenzene to form a fishing rod-like conjugated polymer, where one of the benzenes in the pillar[5]arene rings is incorporated into a poly(arylene ethynylene) backbone.

2011 ◽  
Author(s):  
K. A. Vishnumurthy ◽  
A. Vasudeva Adhikari ◽  
M. S. Sunitha ◽  
Reji Philip ◽  
P. Predeep ◽  
...  

2019 ◽  
Vol 17 (37) ◽  
pp. 8537-8540 ◽  
Author(s):  
Tomoyuki Ikai ◽  
Takumu Yoshida

Asymmetric allylation of aldehydes was conducted inside the helical cavity of a helically folded π-conjugated polymer bearing pyridine N-oxide pendants.


2016 ◽  
Vol 7 (48) ◽  
pp. 7522-7529 ◽  
Author(s):  
Tomoyuki Ikai ◽  
Syo Shimizu ◽  
Seiya Awata ◽  
Tomoya Kudo ◽  
Takayuki Yamada ◽  
...  

Naturally occurring ellagitannins provide us with inspiration for the development of a chiral π-conjugated polymer bearing glucose-linked biphenyl units in the main chain.


2017 ◽  
Vol 5 (34) ◽  
pp. 17909-17919 ◽  
Author(s):  
Sai Gourang Patnaik ◽  
Raman Vedarajan ◽  
Noriyoshi Matsumi

A bis-imino-acenaphthenequinone (BIAN)–fluorene copolymer (π conjugated polymer bearing BIAN and fluorene units) binder was designed, synthesised and used for the fabrication of a graphite electrode in lithium-ion batteries.


2012 ◽  
Vol 159 ◽  
pp. 6-11 ◽  
Author(s):  
Yan Rong Wang ◽  
Hong Juan Zheng ◽  
Shen Gang Xu ◽  
Ya Ping Li ◽  
Shao Kui Cao

A carbazole-based conjugated polymer bearing ruthenium complexes Pbpy(Ru)-Cz was synthesized aiming to obtain a material with dual functionalities of both light absorption and hole-transport for photovoltaic cells. Chemical structures of the monomers and polymers were confirmed by ¹H NMR, IR, and elemental analysis. Pbpy(Ru)-Cz showed good thermal stability and solubility. The absorption spectrum of Pbpy(Ru)-Cz showed a broader peak covering the wavelength range from 380 to 650 nm. Preliminary photovoltaic behavior was evaluated by fabricating photovoltaic cells. As measured under a 55 mW cm‾² compact white arc lamp, Voc, Jsc, FF and ηe of the device ITO/Pbpy(Ru)-Cz:PCBM/Al were 0.18 V, 0.019 mA cm‾², 0.22 and 1.40×10‾³%, pectively.


2010 ◽  
Vol 114 (32) ◽  
pp. 10294-10301 ◽  
Author(s):  
Samdae Park ◽  
Taek Joon Lee ◽  
Dong Min Kim ◽  
Jin Chul Kim ◽  
Kyungtae Kim ◽  
...  

2003 ◽  
Vol 771 ◽  
Author(s):  
M. Kemerink ◽  
S.F. Alvarado ◽  
P.M. Koenraad ◽  
R.A.J. Janssen ◽  
H.W.M. Salemink ◽  
...  

AbstractScanning-tunneling spectroscopy experiments have been performed on conjugated polymer films and have been compared to a three-dimensional numerical model for charge injection and transport. It is found that field enhancement near the tip apex leads to significant changes in the injected current, which can amount to more than an order of magnitude, and can even change the polarity of the dominant charge carrier. As a direct consequence, the single-particle band gap and band alignment of the organic material can be directly obtained from tip height-voltage (z-V) curves, provided that the tip has a sufficiently sharp apex.


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