Multicomponent self-assembly of a pentanuclear Ir–Zn heterometal–organic polyhedron for carbon dioxide fixation and sulfite sequestration

2016 ◽  
Vol 52 (29) ◽  
pp. 5104-5107 ◽  
Author(s):  
Xuezhao Li ◽  
Jinguo Wu ◽  
Cheng He ◽  
Rong Zhang ◽  
Chunying Duan
Keyword(s):  
Carbon Dioxide ◽  
Sulfur Dioxide ◽  
Self Assembly ◽  
Atmospheric Carbon Dioxide ◽  
Carbon Dioxide Fixation ◽  
Metal Centers ◽  
Metal Organic ◽  
Atmospheric Carbon

An iridium-containing pentanuclear metal–organic polyhedron was constructedviaa subcomponent self-assembly. The three equatorial Zn(ii) ions in the structure induced atmospheric carbon dioxide transformation as carbonate and sulfur dioxide as sulfite with bonding to the three metal centers.

Rapid Atmospheric Carbon Dioxide Fixation by Nickel(II) Complexes: Meridionally Coordinated Diazepane-based 3N Ligands Facilitate Fixation

2021 ◽  
Author(s):  
Tamilarasan Ajaykamal ◽  
Mitu Sharma ◽  
Nashreen S Islam ◽  
Mallayan Palaniandavar
Keyword(s):  
Carbon Dioxide ◽  
Elemental Analysis ◽  
Atmospheric Carbon Dioxide ◽  
Carbon Dioxide Fixation ◽  
Atmospheric Carbon

Octahedral complexes of the type [Ni(L)(H2O)3](ClO4)2 1, 2, where L is the tridentate 3N ligand 4-methyl-1-(pyrid-2-ylmethyl)-1,4-diazacycloheptane (L1, 1), or 4-methyl-1-(N-methylimidazolyl)-1,4-diazacycloheptane (L2, 2), have been isolated and characterized using elemental analysis,...

Understanding the opportunities of metal-organic frameworks (MOFs) for CO2 capture and gas-phase CO2 conversion processes: a comprehensive overview

2021 ◽  
Author(s):  
Jesus Gandara-Loe ◽  
Laura Pastor-Perez ◽  
Luis F. Bobadilla ◽  
Jose Antonio Odriozola ◽  
Tomas Ramirez Reina
Keyword(s):  
Carbon Dioxide ◽  
Gas Phase ◽  
Co2 Capture ◽  
Atmospheric Carbon Dioxide ◽  
Metal Organic Frameworks ◽  
Co2 Conversion ◽  
Comprehensive Overview ◽  
Metal Organic ◽  
Atmospheric Carbon

TThe rapid increase in the concentrations of atmospheric carbon dioxide is one of the most pressing problems facing our planet. This challenge has motivated the development of different strategies not...

scholarly journals Experimental Proof that Carbon Dioxide does NOT Cause Global Warming

2020 ◽  
Vol 5 (3) ◽  
pp. p91
Author(s):  
Burl Henry
Keyword(s):  
Carbon Dioxide ◽  
Global Warming ◽  
Sulfur Dioxide ◽  
Atmospheric Carbon Dioxide ◽  
Climatic Effect ◽  
Experimental Proof ◽  
Aerosol Pollution ◽  
Co2 Levels ◽  
Atmospheric Carbon ◽  
Carbon Dioxide Co2

Multiple instances of reductions in atmospheric Carbon Dioxide (CO2) and Sulfur Dioxide (SO2) levels were examined, and it was found that the only climatic effect was from reduced levels of anthropogenic SO2 aerosol pollution in the atmosphere. There were no instances of the hypothesized cooling from reduced CO2 levels.

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