Lanthanide Complexes with Multidentate Oxime Ligands as Single-Molecule Magnets and Atmospheric Carbon Dioxide Fixation Systems

2015 ◽  
Vol 21 (38) ◽  
pp. 13321-13329 ◽  
Author(s):  
Małgorzata Hołyńska ◽  
Rodolphe Clérac ◽  
Mathieu Rouzières
Keyword(s):  
Carbon Dioxide ◽  
Single Molecule ◽  
Lanthanide Complexes ◽  
Atmospheric Carbon Dioxide ◽  
Carbon Dioxide Fixation ◽  
Single Molecule Magnets ◽  
Atmospheric Carbon

Rapid Atmospheric Carbon Dioxide Fixation by Nickel(II) Complexes: Meridionally Coordinated Diazepane-based 3N Ligands Facilitate Fixation

2021 ◽  
Author(s):  
Tamilarasan Ajaykamal ◽  
Mitu Sharma ◽  
Nashreen S Islam ◽  
Mallayan Palaniandavar
Keyword(s):  
Carbon Dioxide ◽  
Elemental Analysis ◽  
Atmospheric Carbon Dioxide ◽  
Carbon Dioxide Fixation ◽  
Atmospheric Carbon

Octahedral complexes of the type [Ni(L)(H2O)3](ClO4)2 1, 2, where L is the tridentate 3N ligand 4-methyl-1-(pyrid-2-ylmethyl)-1,4-diazacycloheptane (L1, 1), or 4-methyl-1-(N-methylimidazolyl)-1,4-diazacycloheptane (L2, 2), have been isolated and characterized using elemental analysis,...

Multicomponent self-assembly of a pentanuclear Ir–Zn heterometal–organic polyhedron for carbon dioxide fixation and sulfite sequestration

2016 ◽  
Vol 52 (29) ◽  
pp. 5104-5107 ◽  
Author(s):  
Xuezhao Li ◽  
Jinguo Wu ◽  
Cheng He ◽  
Rong Zhang ◽  
Chunying Duan
Keyword(s):  
Carbon Dioxide ◽  
Sulfur Dioxide ◽  
Self Assembly ◽  
Atmospheric Carbon Dioxide ◽  
Carbon Dioxide Fixation ◽  
Metal Centers ◽  
Metal Organic ◽  
Atmospheric Carbon

An iridium-containing pentanuclear metal–organic polyhedron was constructedviaa subcomponent self-assembly. The three equatorial Zn(ii) ions in the structure induced atmospheric carbon dioxide transformation as carbonate and sulfur dioxide as sulfite with bonding to the three metal centers.

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