Synthesis of copper nanoparticles within the interlayer space of titania nanosheet transparent films

2016 ◽  
Vol 4 (7) ◽  
pp. 1476-1481 ◽  
Author(s):  
Kazuhisa Sasaki ◽  
Kazuki Matsubara ◽  
Shiori Kawamura ◽  
Kenji Saito ◽  
Masayuki Yagi ◽  
...  

We report the first in situ synthesis of copper nanoparticles (CuNPs) within the interlayer space of inorganic layered semiconductor (titania nanosheets; TNSs) transparent films.

Author(s):  
Kazuhisa Sasaki ◽  
Kazuki Matsubara ◽  
Shiori Kawamura ◽  
Kenji Saito ◽  
Masayuki Yagi ◽  
...  

2021 ◽  
Vol 35 (7) ◽  
pp. 6250-6264
Author(s):  
Kai Fang ◽  
Liujia Ma ◽  
Ya-Jun Cheng ◽  
Senlin Xia ◽  
Zhaohui Yang ◽  
...  

2015 ◽  
Vol 33 (3) ◽  
pp. 627-634 ◽  
Author(s):  
Zahoor H. Farooqi ◽  
Zonarah Butt ◽  
Robina Begum ◽  
Shanza Rhauf Khan ◽  
Ahsan Sharif ◽  
...  

Abstract Poly(N-isopropylacrylamide-co-methacrylic acid) microgels [p(NIPAM-co-MAAc)] were synthesized by precipitation polymerization of N-isopropylacrylamide and methacrylic acid in aqueous medium. These microgels were characterized by dynamic light scattering and Fourier transform infrared spectroscopy. These microgels were used as micro-reactors for in situ synthesis of copper nanoparticles using sodium borohydride (NaBH4) as reducing agent. The hybrid microgels were used as catalysts for the reduction of nitrobenzene in aqueous media. The reaction was performed with different concentrations of cat­alyst and reducing agent. A linear relationship was found between apparent rate constant (kapp) and amount of catalyst. When the amount of catalyst was increased from 0.13 to 0.76 mg/mL then kapp was increased from 0.03 to 0.14 min-1. Activation parameters were also determined by performing reaction at two different temperatures. The catalytic process has been discussed in terms of energy of activation, enthalpy of activation and entropy of activation. The synthesized particles were found to be stable even after 14 weeks and showed catalytic activity for the reduction of nitrobenzene.


2018 ◽  
Vol 3 (48) ◽  
pp. 13759-13764 ◽  
Author(s):  
Soumya Poshala ◽  
Sanjeeva Thunga ◽  
Saikumar Manchala ◽  
Hari Prasad Kokatla

Author(s):  
Konghu Tian ◽  
Cailin Liu ◽  
Haijun Yang ◽  
Xianyan Ren

Author(s):  
Washington C.M. Gomes ◽  
Alcides de Oliveira Wanderley Neto ◽  
Patrícia Mendonça Pimentel ◽  
Dulce Maria de Araújo Melo ◽  
Fabiana Roberta Gonçalves e Silva

2022 ◽  
pp. 257-260
Author(s):  
M. Yeadon ◽  
J.C. Yang ◽  
R.S. Averback ◽  
J.W. Bullard ◽  
J.M. Gibson

2020 ◽  
Vol 68 (4) ◽  
Author(s):  
Ming–xue Shen ◽  
Kang–jie Rong ◽  
Chun–hong Li ◽  
Bin Xu ◽  
Guang–yao Xiong ◽  
...  

2019 ◽  
Vol 44 (60) ◽  
pp. 31892-31901
Author(s):  
Stefanie Kreft ◽  
Marcel Sonneck ◽  
Henrik Junge ◽  
Ayla Päpcke ◽  
Anja Kammer ◽  
...  

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