A novel fluorescence probe for sensing organic amine vapors from a Eu3+β-diketonate functionalized bio-MOF-1 hybrid system

2015 ◽  
Vol 3 (27) ◽  
pp. 7038-7044 ◽  
Author(s):  
Xiang Shen ◽  
Bing Yan
Keyword(s):  
Hybrid System ◽  
Organic Molecules ◽  
Fluorescence Probe ◽  
Metal Organic Framework ◽  
Organic Amine ◽  
System P ◽  
Volatile Organic ◽  
Metal Organic ◽  
Volatile Amines ◽  
Organic Framework

A classic anionic metal–organic framework (bio-MOF-1) for Eu3+-β-diketonate complex encapsulation has the utility of a sensory material for sensing volatile organic molecules, especially volatile amines.

Novel photofunctional hybrid materials (alumina and titania) functionalized with both MOF and lanthanide complexes through coordination bonds

RSC Advances ◽  
2014 ◽  
Vol 4 (73) ◽  
pp. 38761-38768 ◽  
Author(s):  
X. Y. Xu ◽  
B. Yan
Keyword(s):  
Hybrid Materials ◽  
Hybrid System ◽  
Lanthanide Complexes ◽  
Metal Organic Framework ◽  
Sol Gel ◽  
System P ◽  
Metal Organic ◽  
Coordination Bonds ◽  
Organic Framework

Multi-component sol–gel derived alumina and titania hybrid materials are assembled by the functionalization of both lanthanide complexes and a special metal organic framework compound: Al-MIL-53-COOH through coordination bonds. Multi-color luminescence and white colored light can be tuned by controlling the different units in the hybrid system.

scholarly journals Volatile Organic Compound Vapour Measurements Using a Localised Surface Plasmon Resonance Optical Fibre Sensor Decorated with a Metal-Organic Framework

Sensors ◽  
2021 ◽  
Vol 21 (4) ◽  
pp. 1420
Author(s):  
Chenyang He ◽  
Liangliang Liu ◽  
Sergiy Korposh ◽  
Ricardo Correia ◽  
Stephen P. Morgan
Keyword(s):  
Surface Plasmon Resonance ◽  
Volatile Organic Compounds ◽  
Organic Compounds ◽  
Surface Plasmon ◽  
Optical Fibre ◽  
Plasmon Resonance ◽  
Metal Organic Framework ◽  
Volatile Organic ◽  
Metal Organic ◽  
Organic Framework

A tip-based fibreoptic localised surface plasmon resonance (LSPR) sensor is reported for the sensing of volatile organic compounds (VOCs). The sensor is developed by coating the tip of a multi-mode optical fibre with gold nanoparticles (size: 40 nm) via a chemisorption process and further functionalisation with the HKUST-1 metal–organic framework (MOF) via a layer-by-layer process. Sensors coated with different cycles of MOFs (40, 80 and 120) corresponding to different crystallisation processes are reported. There is no measurable response to all tested volatile organic compounds (acetone, ethanol and methanol) in the sensor with 40 coating cycles. However, sensors with 80 and 120 coating cycles show a significant redshift of resonance wavelength (up to ~9 nm) to all tested volatile organic compounds as a result of an increase in the local refractive index induced by VOC capture into the HKUST-1 thin film. Sensors gradually saturate as VOC concentration increases (up to 3.41%, 4.30% and 6.18% in acetone, ethanol and methanol measurement, respectively) and show a fully reversible response when the concentration decreases. The sensor with the thickest film exhibits slightly higher sensitivity than the sensor with a thinner film. The sensitivity of the 120-cycle-coated MOF sensor is 13.7 nm/% (R2 = 0.951) with a limit of detection (LoD) of 0.005% in the measurement of acetone, 15.5 nm/% (R2 = 0.996) with an LoD of 0.003% in the measurement of ethanol and 6.7 nm/% (R2 = 0.998) with an LoD of 0.011% in the measurement of methanol. The response and recovery times were calculated as 9.35 and 3.85 min for acetone; 5.35 and 2.12 min for ethanol; and 2.39 and 1.44 min for methanol. The humidity and temperature crosstalk of 120-cycle-coated MOF was measured as 0.5 ± 0.2 nm and 0.5 ± 0.1 nm in the humidity range of 50–75% relative humidity (RH) and temperature range of 20–25 °C, respectively.

Improving the genistein oral bioavailability via its formulation into the metal–organic framework MIL-100(Fe)

2021 ◽  
Vol 9 (9) ◽  
pp. 2233-2239
Author(s):  
Adrià Botet-Carreras ◽  
Cristina Tamames-Tabar ◽  
Fabrice Salles ◽  
Sara Rojas ◽  
Edurne Imbuluzqueta ◽  
...  
Keyword(s):  
Oral Bioavailability ◽  
Metal Organic Framework ◽  
Drug Carrier ◽  
Aqueous Solubility ◽  
Carrier System ◽  
System P ◽  
Metal Organic ◽  
Drug Carrier System ◽  
Organic Framework

Despite the interesting chemopreventive, antioxidant and antiangiogenic effects of the natural bioflavonoid genistein (GEN), its low aqueous solubility and bioavailability make it necessary to administer it using a suitable drug carrier system.

scholarly journals A metal organic framework-ultrafiltration hybrid system for removing selected pharmaceuticals and natural organic matter

2020 ◽  
Vol 382 ◽  
pp. 122920 ◽  
Author(s):  
Sewoon Kim ◽  
Juan C. Muñoz-Senmache ◽  
Byung-Moon Jun ◽  
Chang Min Park ◽  
Am Jang ◽  
...  
Keyword(s):  
Organic Matter ◽  
Natural Organic Matter ◽  
Hybrid System ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework

The highly efficient elimination of intracellular bacteria via a metal organic framework (MOF)-based three-in-one delivery system

Nanoscale ◽  
2019 ◽  
Vol 11 (19) ◽  
pp. 9468-9477 ◽  
Author(s):  
Xu Zhang ◽  
Lizhi Liu ◽  
Lunjie Huang ◽  
Wentao Zhang ◽  
Rong Wang ◽  
...  
Keyword(s):  
Hyaluronic Acid ◽  
Delivery System ◽  
Metal Organic Framework ◽  
Intracellular Bacteria ◽  
Highly Efficient ◽  
System P ◽  
Metal Organic ◽  
Efficient Elimination ◽  
Organic Framework

Highly efficient elimination of intracellular bacteria via a hyaluronic acid-functionalized metal organic framework(MOF)/antibiotic system.

Strategic hierarchical improvement of superprotonic conductivity in a stable metal–organic framework system

2019 ◽  
Vol 7 (43) ◽  
pp. 25165-25171 ◽  
Author(s):  
Xiao-Min Li ◽  
Jiang Liu ◽  
Chen Zhao ◽  
Jia-Lin Zhou ◽  
Ling Zhao ◽  
...  
Keyword(s):  
Proton Conductivity ◽  
Metal Organic Framework ◽  
Efficient Strategy ◽  
System P ◽  
Metal Organic ◽  
Framework System ◽  
Organic Framework

An efficient strategy to hierarchically improve the proton conductivity of MOFs by increasing the number of proton sources and hopping sites has been proposed.

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