scholarly journals Modulation of the ligand-based fluorescence of 3d metal complexes upon spin state change

2015 ◽  
Vol 3 (30) ◽  
pp. 7925-7935 ◽  
Author(s):  
Charles Lochenie ◽  
Kristina G. Wagner ◽  
Matthias Karg ◽  
Birgit Weber
Keyword(s):  
Metal Complexes ◽  
Spin State ◽  
State Change ◽  
Metal Centre ◽  
3D Metal Complexes

Complexes bearing a polyheteroaromatic fluorophore show a modulation of the fluorescence depending on the spin state of the metal centre.

scholarly journals Synthesis of Some 3d Metal Complexes of Quinine and their Toxicological Studies

1970 ◽  
Vol 25 ◽  
pp. 19-28 ◽  
Author(s):  
Adedibu C. Tella ◽  
Joshua A. Obaleya
Keyword(s):  
Stability Constant ◽  
Metal Complexes ◽  
Chemical Society ◽  
Cinchona Alkaloids ◽  
Albino Rats ◽  
Spectroscopic Techniques ◽  
Tetrahedral Geometry ◽  
Toxicological Studies ◽  
3D Metal Complexes ◽  
The Stability

Four metal complexes of antimalarials cinchona alkaloids; [Co(Quin)Cl3]-1,[Fe(Quin)Cl2H2O]SO3H2O-2, [Cu(Quin)ClSO4]∞-3 and [Cd(Quin)ClSO4]∞-4 have beensynthesized and characterized by elemental analysis, conductivity, magnetic moment, IR,UV-Vis and mass spectroscopic techniques. The tetrahedral geometry is assigned for all thefour complexes and the quinine ligand is protonated at quinuclidine N atom with thecoordination of the metal at quinoline N atom for all the complexes. Complexes 1 and 2have zwitterionic structures while complexes 3 and 4 are polymeric in nature with zig-zagextended chains (MCl- O -SO2- O -MCl- O –SO2---).Stability constant of the complexes were evaluated for the metal salts. The value of thestability constant (β) was found to be log 10.48, 9.92, 7.98 and 7.81 for Cu(II), Fe(III),Co(II) and Cd(II), respectively and the order of β was found to beCu(II)>Fe(III)>Co(II)>Cd(II). The stability constant data revealed that concomitantlyadministration of quinine with preparation containing these metals may reduce theirefficacy. Toxicological study was carried out by investigating the effect of administration ofthe complexes on alkaline phosphatase activity of kidney, liver and serum of Albino rats. Allthe examined four metal complexes were found to be non-toxic.Keywords: Quinine, stability constant, FTIR, MS, phosphates activity.DOI:  10.3126/jncs.v25i0.3280Journal of Nepal Chemical Society Volume 25, 2010 pp 19-28

Five coordination in 3d metal complexes

1968 ◽  
Vol 17 (1) ◽  
pp. 95-128 ◽  
Author(s):  
Luigi Sacconi
Keyword(s):  
Metal Complexes ◽  
3D Metal Complexes

A diamagnetic iron complex and its twisted sister – Structural evidence on partial spin state change in a crystalline iron complex

2021 ◽  
Author(s):  
Esko Salojärvi ◽  
Anssi Peuronen ◽  
Jani Moilanen ◽  
Hannu Huhtinen ◽  
Johan Linden ◽  
...  
Keyword(s):  
Spin State ◽  
Iron Complex ◽  
State Change ◽  
Tert Butyl ◽  
Fe Complex

We report here the syntheses of a diamagnetic Fe complex [Fe(HL)2] (1), prepared by reacting a redox non-innocent ligand precursor N,N’-bis(3,5-di-tert-butyl-2-hydroxy-phenyl)-1,2-phenylenediamine (H4L) with FeCl3, and its phenoxazine derivative [Fe(L’)2] (2),...

scholarly journals Thermal, spectroscopic, X-ray and theoretical studies of metal complexes (sodium, manganese, copper, nickel, cobalt and zinc) with pyrimidine-5-carboxylic and pyrimidine-2-carboxylic acids

2019 ◽  
Vol 138 (4) ◽  
pp. 2813-2837 ◽  
Author(s):  
G. Świderski ◽  
R. Świsłocka ◽  
R. Łyszczek ◽  
S. Wojtulewski ◽  
M. Samsonowicz ◽  
...  
Keyword(s):  
Carboxylic Acid ◽  
Nitrogen Atom ◽  
Metal Complexes ◽  
General Formula ◽  
Pyrimidine Ring ◽  
Carboxylate Ligand ◽  
Metal Centers ◽  
X Ray ◽  
Carboxylate Oxygen ◽  
3D Metal Complexes

Abstract The new 3d metal complexes of pyrimidine-2-carboxylic (2PCA) and pyrimidine-5-carboxylic (5PCA) acids were synthesized and characterized using thermal analysis (TG–DSC, TG–FTIR), X-ray, spectroscopic (IR, Raman) methods and theoretical (DFT) studies. In the complexes of pyrimidine-2-carboxylic acid of the general formula M(2PCA)2·xH2O (where 2PCA-pyrimidine-2-carboxylate; M = Mn(II), Co(II), Ni(II), Cu(II) and Zn; x = 0 for Mn and Cu; x = 2 for Co, Ni and Zn) coordination of metal ions occurs through nitrogen atom from pyrimidine ring and carboxylate oxygen atom. The complexes of pyrimidine-5-carboxylic acid of the general formula M(5PCA)2·xH2O (where 5PCA—pyrimidine-5-carboxylate; M = Mn(II), Co(II), Ni(II), Cu(II) and Zn; x = 6 for Cu and 4 for remaining complexes) were obtained as monomeric isostructural compounds. Coordination of metal centers occurs through two nitrogen atom from different pyrimidine-5-carboxylate ligand and four oxygen atoms from water molecules. The IR and Raman spectra of free acids as well as obtained metal(II) complexes were described in detail. Aromaticity (HOMA, EN, GEO and I6) of complexes was determined and discussed. The investigated compounds decompose in air in two main stages connected with dehydration and decomposition/burning of anhydrous compounds to the suitable metal oxides. Thermal decomposition in nitrogen leads to the evolution of water, carbon oxides, ammonia and pyrimidine molecules.

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