Adducts of transition metal complexes with redox-active ligands: the structure and spin-state-switching rearrangements

2018 ◽  
Vol 87 (11) ◽  
pp. 1049-1079 ◽  
Author(s):  
A A Starikova ◽  
V I Minkin
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Spin State ◽  
Redox Active Ligands ◽  
State Switching ◽  
Redox Active

Transition metal complexes with redox-active ligands in hydrogen sulfide activation

2009 ◽  
Vol 427 (1) ◽  
pp. 147-152 ◽  
Author(s):  
I. V. Smolyaninov ◽  
A. O. Okhlobystin ◽  
A. I. Poddel’sky ◽  
N. T. Berberova ◽  
I. L. Eremenko
Keyword(s):  
Hydrogen Sulfide ◽  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Redox Active Ligands ◽  
Redox Active

Switching and redox isomerism in first-row transition metal complexes containing redox active Schiff base ligands

2014 ◽  
Vol 43 (42) ◽  
pp. 15958-15967 ◽  
Author(s):  
Ashok Sasmal ◽  
Eugenio Garribba ◽  
Carlos J. Gómez-García ◽  
Cédric Desplanches ◽  
Samiran Mitra
Keyword(s):  
Electron Transfer ◽  
Schiff Base ◽  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Schiff Base Ligands ◽  
Redox Active Ligands ◽  
Redox Active ◽  
Redox Isomerism

Switching and redox isomerism in first row transition metal complexes through the metal-to-ligand or ligand-to-ligand electron transfer stabilize redox isomeric forms in transition metal complexes with redox-active ligands.

scholarly journals Light-controlled spin-state-switching rearrangements of transition metal complexes with photochromic ligands

2017 ◽  
Vol 89 (8) ◽  
pp. 985-1005 ◽  
Author(s):  
Vladimir I. Minkin ◽  
Andrey G. Starikov ◽  
Alyona A. Starikova
Keyword(s):  
Magnetic Properties ◽  
Transition Metal ◽  
Dft Calculations ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Spin State ◽  
Spin Crossover ◽  
State Switching ◽  
Configurational Isomerization

Abstract New families of the transition metal complexes with photochromic ligands manifesting photoswitchable magnetic properties determined by the light-induced spin-crossover and configurational isomerization rearrangements are theoretically designed by means of DFT calculations of electromeric forms of the complexes.

Computational insight into magnetic behavior and properties of the transition metal complexes with redox-active ligands: a DFT approach

2018 ◽  
Vol 90 (5) ◽  
pp. 811-824 ◽  
Author(s):  
Vladimir I. Minkin ◽  
Andrey G. Starikov ◽  
Alyona A. Starikova
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Magnetic Behavior ◽  
Dft Method ◽  
Correct Choice ◽  
Model Compounds ◽  
Redox Active Ligands ◽  
Redox Active ◽  
Insight Into

AbstractVarious aspects related to the use of DFT method for the study of magnetic, geometry and energetic properties of transition metal complexes with redox-active ligands are considered. Particular attention is given to the correct choice of model compounds and methodology of the calculations.

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