Electrochromic properties of novel octa-pinene substituted double-decker Ln(iii) (Ln = Eu, Er, Lu) phthalocyanines with distinctive near-IR absorption

2015 ◽  
Vol 3 (13) ◽  
pp. 3072-3080 ◽  
Author(s):  
Wei Zheng ◽  
Bei-Bei Wang ◽  
Jian-Cheng Lai ◽  
Cheng-Zhang Wan ◽  
Xin-Rong Lu ◽  
...  
Keyword(s):  
Electrochemical Properties ◽  
Near Infrared ◽  
External Potential ◽  
Infrared Range ◽  
Ir Absorption ◽  
Electrochromic Properties ◽  
Near Ir ◽  
Double Decker ◽  
Spectral And Electrochemical Properties ◽  
Near Infrared Range

The introduction of pinene groups into lanthanide(iii) double-decker phthalocyanines results in excellent solubility as well as nontrivial spectral and electrochemical properties. Upon external potential, the new lanthanide(iii) double-decker phthalocyanine complexes show electrochromic properties at both visible and near infrared range.

Plasmon-assisted interaction of Si with light, for cancer hyperthermia and electromagnetic energy harvest

2020 ◽  
Vol 92 (2) ◽  
pp. 20101
Author(s):  
Behnam Kheyraddini Mousavi ◽  
Morteza Rezaei Talarposhti ◽  
Farshid Karbassian ◽  
Arash Kheyraddini Mousavi
Keyword(s):  
Silicon Nanowires ◽  
Metallic Nanoparticles ◽  
Near Infrared ◽  
Optical Transition ◽  
Electromagnetic Energy ◽  
Energy Harvest ◽  
Absorption Enhancement ◽  
Ir Absorption ◽  
Absorption Mechanism ◽  
Near Ir

Metal-assisted chemical etching (MACE) is applied for fabrication of silicon nanowires (SiNWs). We have shown the effect of amorphous sheath of SiNWs by treating the nanowires with SF6 and the resulting reduction of absorption bandwidth, i.e. making SiNWs semi-transparent in near-infrared (IR). For the first time, by treating the fabricated SiNWs with copper containing HF∕H2O2∕H2O solution, we have generated crystalline nanowires with broader light absorption spectrum, up to λ = 1 μm. Both the absorption and photo-luminescence (PL) of the SiNWs are observed from visible to IR wavelengths. It is found that the SiNWs have PL at visible and near Infrared wavelengths, which may infer presence of mechanisms such as forbidden gap transitions other can involvement of plasmonic resonances. Non-radiative recombination of excitons is one of the reasons behind absorption of SiNWs. Also, on the dielectric metal interface, the absorption mechanism can be due to plasmonic dissipation or plasmon-assisted generation of excitons in the indirect band-gap material. Comparison between nanowires with and without metallic nanoparticles has revealed the effect of nanoparticles on absorption enhancement. The broader near IR absorption, paves the way for applications like hyperthermia of cancer while the optical transition in near IR also facilitates harvesting electromagnetic energy at a broad spectrum from visible to IR.

Coupling of Er light emissions to plasmon modes on In2O3: Sn nanoparticle sheets in the near-infrared range

2014 ◽  
Vol 105 (4) ◽  
pp. 041903 ◽  
Author(s):  
Hiroaki Matsui ◽  
Wasanthamala Badalawa ◽  
Takayuki Hasebe ◽  
Shinya Furuta ◽  
Wataru Nomura ◽  
...  
Keyword(s):  
Near Infrared ◽  
Infrared Range ◽  
Near Infrared Range ◽  
Sn Nanoparticle ◽  
Plasmon Modes

scholarly journals Fabrication of Dy2O3 Transparent Ceramics by Vacuum Sintering Using Precipitated Powders

2020 ◽  
Vol 7 (1) ◽  
pp. 6
Author(s):  
Dianjun Hu ◽  
Xin Liu ◽  
Ziyu Liu ◽  
Xiaoying Li ◽  
Feng Tian ◽  
...  
Keyword(s):  
Near Infrared ◽  
Optical Quality ◽  
Precipitation Method ◽  
Infrared Range ◽  
Transparent Ceramics ◽  
Vacuum Sintering ◽  
Hydrogen Carbonate ◽  
Ammonium Hydrogen ◽  
Liquid Precipitation ◽  
Near Infrared Range

As a kind of promising material for a Faraday isolator used in the visible and near infrared range, Dy2O3 transparent ceramics were prepared by vacuum sintering from the nano-powders synthesized by the liquid precipitation method using ammonium hydrogen carbonate as precipitant with no sintering aids. The synthesized precursor was calcinated at 950 °C–1150 °C for 4 h in air. The influences of the calcination temperature on the morphologies and phase composition of Dy2O3 powders were characterized. It is found that the Dy2O3 powder calcinated at 1000 °C for 4 h is superior for the fabrication of Dy2O3 ceramics. The Dy2O3 transparent ceramic sample prepared by vacuum sintering at 1850 °C for 10 h, and subsequently with air annealing at 1400 °C for 10 h, from the 1000 °C-calcined Dy2O3 powders, presents the best optical quality. The values of in-line transmittance of the optimal ceramic specimen with the thickness of 1.0 mm are 75.3% at 2000 nm and 67.9% at 633 nm. The Verdet constant of Dy2O3 ceramics was measured to be −325.3 ± 1.9 rad/(T·m) at 633 nm, about 2.4 times larger than that of TGG (Tb3Ga5O12) single crystals.

scholarly journals Joint Measurements of PM<sub>2.5</sub> and light-absorptive PM in woodsmoke-dominated ambient and plume environments

2017 ◽  
Author(s):  
K. Max Zhang ◽  
Bo Yang ◽  
Geng Chen ◽  
Jiajun Gu ◽  
James Schwab ◽  
...  
Keyword(s):  
Near Infrared ◽  
Uv Light ◽  
Operating Conditions ◽  
Infrared Range ◽  
Wood Combustion ◽  
Near Ultraviolet ◽  
Linear Relationships ◽  
Saranac Lake ◽  
Near Infrared Range ◽  
Strong Linear Relationship

Abstract. DC, also referred to as Delta-C, measures enhanced light absorption of particulate matter (PM) samples at the near-ultraviolet (UV) range relative to the near-infrared range, which has been proposed previously as a woodsmoke marker due to the presence of enhanced UV light absorbing materials from wood combustion. In this paper, we further evaluated the applications and limitations of using DC as both a qualitative and semi-quantitative woodsmoke marker via joint continuous measurements of PM2.5 (by nephelometer pDR-1500) and light-absorptive PM (by 2-wavelength and 7-wavelength Aethalometer®) in three Northeastern U.S. cities/towns including Rutland, VT, Saranac Lake, NY and Ithaca, NY. We compared the pDR-1500 against a FEM PM2.5 sampler (BAM 1020), and identified a close agreement between the two instruments in a woodsmoke-dominated ambient environment. The analysis of seasonal and diurnal trends of DC, BC (880 nm) and PM2.5 concentrations supports the use of DC as an adequate qualitative marker. The strong linear relationships between PM2.5 and DC in both woodsmoke-dominated ambient and plume environments suggest that DC can reasonably serve as a semi-quantitative woodsmoke marker. We proposed a DC-based indicator for woodsmoke emission, which was then shown to exhibit relatively strong linear relationship with heating demand. While we observed reproducible PM2.5-DC relationships in similar woodsmoke-dominated ambient environments, those relationships differ significantly with different environments, and among individual woodsmoke sources. DC correlated much more closely with PM2.5 than EcoChem PAS2000-reported PAH in woodsmoke-dominated ambient environments. Our analysis also indicates the potential for PM2.5-DC relationships to be utilized to distinguish different combustion and operating conditions of woodsmoke sources, and that DC-Heating demand relationships could be adopted to estimate woodsmoke emissions. However, future studies are needed to elucidate those relationships.

scholarly journals Interaction in quasibinary systems based on TlSbP2Se6 and compounds of the Tl2Se-Sb2Se3 system

2019 ◽  
Vol 85 (3) ◽  
pp. 20-26
Author(s):  
Viktoria Sabov ◽  
Мaria Potorij ◽  
Iwan Kityk ◽  
Mykhailo Filep ◽  
Marian Sabov
Keyword(s):  
Cross Sections ◽  
Near Infrared ◽  
Practical Interest ◽  
Infrared Range ◽  
Thermally Stable ◽  
Quaternary Compound ◽  
Metal Compounds ◽  
Temperature Method ◽  
The Family ◽  
Near Infrared Range

Complex chalcogenides display semiconductor properties. In particular, heavy metal compounds that are formed in the Tl2Se-Sb2Se3 system are good thermoelectric materials. At the same time TlSbP2Se6 compound belongs to the family of hexaseleno-hypodiphosphates, which representatives have a number of interesting properties (optoelectric, non-linear, etc.) in the near infrared range. The combination of these properties in one material causes some scientific and practical interest, therefore our research was aimed to study the nature of the interaction between TlSbP2Se6 and the thermally stable phases of the Tl2Se-Sb2Se3 system in order to find new promising candidate for applications in electronic devices. The alloys were prepared from corresponding binary, ternary compounds and quaternary TlSbP2Se6 by a direct one-temperature method in evacuated quartz ampoules at temperatures above the melting point of the initial and final products. The initial compounds were synthesized by the reaction of their high purity component elements in stoichiometric proportion. According to the results of the research, it was found that cross-sections based on TlSbP2Se6 and the thermally stable compounds of the Tl2Se-Sb2Se3 section are quasibinary: Sb2Se3–TlSbP2Se6 and TlSbSe2–TlSbP2Se6. Tl9SbSe6 – TlSbP2Se6 and Tl2Se - TlSbP2Se6 systems are not quasibinary, instead quasibinary sections Tl2Se-Tl4P2Se6 and Tl9SbSe6-Tl4P2Se6 which crossing their. The phase equilibrium in Sb2Se3 – TlSbP2Se6 and TlSbSe2 – TlSbP2Se6 systems were studied by common differential thermal analysis (DTA), X-ray powder diffraction (XRD) and microstructure analysis. The eutectic interactions are observed in both systems. The invariant points coordinates are: 77 mol.% TlSbP2Se6, 709 K (system Sb2Se3 – TlSbP2Se6) and 45 mol.% TISbSe2, 680 K (system TlSbSe2 – TlSbP2Se6). Significant boundary solid solutions are formed on the basis of the quaternary compound. Their region extends up to 10 mol% in the system Sb2Se3 – TlSbP2Se6 and to about 18 mol.% in the system TlSbSe2 –TlSbP2Se6 at annealing temperature (573 К). Near the Sb2Se3 and TlSbSe2, the solubility limits do not exceed several mol.%.

3D Plant Modelling Using Spectral Data from Visible to Near Infrared Range

2015 ◽  
pp. 273-294
Author(s):  
Ali Zia ◽  
Jie Liang
Keyword(s):  
Hyperspectral Imaging ◽  
Material Properties ◽  
Near Infrared ◽  
Infrared Range ◽  
Plant Surface ◽  
Imaging Device ◽  
Plant Phenomics ◽  
Physical Traits ◽  
Plant Modelling ◽  
Near Infrared Range

Plant phenomics research requires different types of sensors employed to measure the physical traits of plant surface and to estimate the biomass. Of particular interests is the hyperspectral imaging device which captures wavelength indexed band images that characterize material properties of objects under study. This chapter introduces a proof of concept research that builds 3D plant model directly from hyperspectral images captured in a controlled lab environment. The method presented in this chapter allows fine structural-spectral information of an object be captured and integrated into the 3D model, which can be used to support further research and applications. The hyperspectral imaging has shown clear advantages in segmenting plant from its background and is very promising in generating comprehensive 3D plant models.

Epitaxial synthesis of ultrathin β-In2Se3/MoS2 heterostructures with high visible/near-infrared photoresponse

Nanoscale ◽  
2020 ◽  
Vol 12 (11) ◽  
pp. 6480-6488 ◽  
Author(s):  
Zixing Zou ◽  
Dong Li ◽  
Junwu Liang ◽  
Xuehong Zhang ◽  
Huawei Liu ◽  
...  
Keyword(s):  
Near Infrared ◽  
Infrared Range ◽  
Near Infrared Range

Novel β-In2Se3/MoS2 vertically stacked heterostructures were synthesized, and can be further utilized as excellent photodetectors in the visible and near-infrared range.

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