Rational design of a novel indole-based microporous organic polymer: enhanced carbon dioxide uptake via local dipole–π interactions

2016 ◽  
Vol 4 (7) ◽  
pp. 2517-2523 ◽  
Author(s):  
Guanjun Chang ◽  
Zhenfang Shang ◽  
Tao Yu ◽  
Li Yang
Keyword(s):  
Carbon Dioxide ◽  
Rational Design ◽  
Organic Polymer ◽  
Π Interactions ◽  
Carbon Dioxide Uptake

An indole-based microporous organic polymer (PINK) is achieved and it exhibits good performance for carbon dioxide uptake via the local dipole–π interactions.

A nitrogen-rich, azaindole-based microporous organic network: synergistic effect of local dipole–π and dipole–quadrupole interactions on carbon dioxide uptake

2016 ◽  
Vol 7 (37) ◽  
pp. 5768-5772 ◽  
Author(s):  
Guanjun Chang ◽  
Li Yang ◽  
Junxiao Yang ◽  
Yawen Huang ◽  
Ke Cao ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Synergistic Effect ◽  
Organic Polymer ◽  
Carbon Dioxide Uptake ◽  
Quadrupole Interactions ◽  
New Type

A new type of microporous organic polymer with azaindole units (N-PEINK) has been designed.

Remarkable gas adsorption by carbonized nitrogen-rich hypercrosslinked porous organic polymers

2014 ◽  
Vol 2 (36) ◽  
pp. 15139-15145 ◽  
Author(s):  
Xiao Yang ◽  
Miao Yu ◽  
Yang Zhao ◽  
Chong Zhang ◽  
Xiaoyan Wang ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Surface Area ◽  
Gas Adsorption ◽  
High Surface ◽  
High Surface Area ◽  
Organic Polymer ◽  
High Carbon ◽  
Porous Organic Polymer ◽  
Carbon Dioxide Uptake ◽  
High Carbon Dioxide

Carbonized materials from a nitrogen-rich hypercrosslinked porous organic polymer exhibit a high surface area of 2065 m2 g−1 and an exceptionally high carbon dioxide uptake up to 6.51 mmol g−1 (1.13 bar/273 K).

EFFECTS OF HERBICIDES ON CARBON DIOXIDE UPTAKE BY PINE SEEDLINGS

1967 ◽  
Vol 45 (7) ◽  
pp. 961-971 ◽  
Author(s):  
S. Sasaki ◽  
T. T. Kozlowski
Keyword(s):  
Carbon Dioxide ◽  
Gas Exchange ◽  
Soil Surface ◽  
Pinus Resinosa ◽  
Spray Application ◽  
Leaf Color ◽  
Carbon Dioxide Uptake ◽  
Chlorophyll Breakdown ◽  
Pine Seedlings ◽  
Steady Rate

Experiments were conducted on effects of herbicides applied to soil or sprayed on shoots on CO2 uptake of 3-year-old Pinus resinosa Ait. seedlings. When applied to the soil, atrazine, monuron, EPTC, and 2,4-D at 20 lb/ac (soil surface basis) or at 4000 p.p.m. variously decreased absorption of CO2. Monuron checked gas exchange most rapidly, with no CO2 uptake measurable after 10 days. Atrazine and 2,4-D inhibited absorption of CO2 at a steady rate. EPTC caused a delayed inhibition of CO2 uptake. DCPA, CDAA, CDEC, and NPA did not affect gas exchange significantly. Monuron applied as a spray depressed CO2 uptake somewhat faster than the soil-applied herbicide. Very rapid inhibition of CO2 uptake was observed after spray application of 2,4-D or EPTC. Atrazine affected gas exchange similarly when applied as a spray or incorporated in the soil. DCPA, applied as a spray, did not affect absorption of CO2 significantly. Possible reasons for differences in CO2 uptake after spray and soil-application of certain herbicides are discussed. Inert ingredients of EPTC applied as sprays at a concentration of 4000 p.p.m. greatly reduced CO2 absorption 3 days after treatment. However, the rapid early depression of gas exchange was followed by recovery, with no obvious deleterious effects on growth up to 3 months after treatment. Some herbicides checked CO2 absorption without chlorophyll breakdown whereas others did not. Monuron completely inhibited CO2 uptake long before any changes in leaf color were evident. In contrast, depression of CO2 absorption by atrazine and 2,4-D rather closely paralleled development of toxicity symptoms, especially chlorosis. These observations suggested that some herbicides such as monuron affected the photosynthetic mechanism more directly than others such as atrazine, 2,4-D, and EPTC.

Novel melamine-based porous organic polymers: synthesis, characterizations, morphology modifications, and their applications in lithium-sulfur batteries

2021 ◽  
Author(s):  
Haiyang Liu ◽  
Jiaxing Wang ◽  
Miao SUN ◽  
Yu Wang ◽  
Runing Zhao ◽  
...  
Keyword(s):  
High Performance ◽  
Rational Design ◽  
Specific Capacity ◽  
High Capacity ◽  
Lithium Ion ◽  
Organic Polymer ◽  
Energy Storage Devices ◽  
Shuttle Effect ◽  
Physical Constraints ◽  
Lithium Sulfur

Abstract Lithium-sulfur (Li-S) batteries have been considered to be one of the most promising energy storage devices in the next generation. However, the insulating properties of sulfur and the shuttle effect of soluble lithium polysulfides (LiPSs) seriously hinder the practical application of Li-S batteries. In this paper, a novel porous organic polymer (HUT3) was prepared based on the polycondensation between melamine and 1,4-phenylene diisocyanate. The micro morphology of HUT3 was improved by in-situ growth on different mass fractions of rGO (5%, 10%, 15%), and the obtained HUT3-rGO composites were employed as sulfur carriers in Li-S batteries with promoted the sulfur loading ratio and lithium ion mobility. Attributed to the synergistic effect of the chemisorption of polar groups and the physical constraints of HUT3 structure, HUT3-rGO/S electrodes exhibits excellent capacity and cyclability performance. For instance, HUT3-10rGO/S electrode exhibits a high initial specific capacity of 950 mAh g-1 at 0.2 C and retains a high capacity of 707 mAh g-1 after 500 cycles at 1 C. This work emphasizes the importance of the rational design of the chemical structure and opens up a simple way for the development of cathode materials suitable for high-performance Li-S batteries.

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