Increased ion conduction in dual cation [sodium][tetraalkylammonium] poly[4-styrenesulfonyl(trifluoromethylsulfonyl)imide-co-ethylacrylate] ionomers

2015 ◽  
Vol 3 (39) ◽  
pp. 19989-19995 ◽  
Author(s):  
Jiaye Li ◽  
Haijin Zhu ◽  
Xiaoen Wang ◽  
Douglas R. MacFarlane ◽  
Michel Armand ◽  
...  

Three dual-cation polymeric ionomers that contain tetraalkylammonium ions and sodium ions have been synthesized and exhibited higher conductivity than the analogous single sodium ion polymers.

2016 ◽  
Vol 128 (49) ◽  
pp. 15480-15483 ◽  
Author(s):  
Parameswara Rao Chinnam ◽  
Birane Fall ◽  
Dmitriy A. Dikin ◽  
AbdelAziz Jalil ◽  
Clifton R. Hamilton ◽  
...  

1967 ◽  
Vol 45 (12) ◽  
pp. 1795-1807 ◽  
Author(s):  
Paula Strasberg ◽  
K. A. C. Elliott

Factors which can interfere with the paper chromatographic – ninhydrin method for determining γ-aminobutyric acid (GABA) are described. The GABA–ninhydrin reaction does not involve loss of CO2. GABA that is occluded in subcellular particles in plain sucrose homogenates of rat brain does not readily exchange with radioactive GABA in solution. The relevant particles are found mostly in the "mitochondrial fraction". These particles deteriorate with time and manipulations, and tend to lose much of their GABA content. The presence of sodium (but not of potassium, calcium, or magnesium) in the suspending medium allows considerably more GABA to be bound. The extra bound GABA is exchangeable with free labelled GABA. Sodium also promotes some exchange between free and occluded GABA. It is concluded from the present and previous results that in brain in vivo very little GABA exists in a freely diffusing situation. There are two forms of bound GABA. One of these is an occluded or storage form which does not readily exchange with free GABA though exchange is to some extent promoted by sodium ions. The other is a form which occurs only in the presence of sodium ion and is freely exchangeable with GABA in solution.


1971 ◽  
Vol 40 (4) ◽  
pp. 293-303 ◽  
Author(s):  
G. S. Harris ◽  
W. A. Palmer

1. The presence of mucopolysaccharides within arterial walls may be associated with the high concentration of sodium ions within this tissue. These polyanions are sensitive to enzymatic depolymerization which results in a loss of the cation binding properties of the molecule. 2. In this study testicular hyaluronidase perfused through isolated arterial segments resulted in a decrease in reactivity of the artery to 65% that of control arteries. Associated with this finding was a 33% decrease in the sodium ion content of the stimulated hyaluronidase-treated artery. When a variety of other sympathetically innervated tissues were treated with hyaluronidase there was no decrease in reactivity or sodium ion content.


2014 ◽  
Vol 4 (1) ◽  
Author(s):  
Zhaohui Ma ◽  
Yuesheng Wang ◽  
Chunwen Sun ◽  
J. A. Alonso ◽  
M. T. Fernández-Díaz ◽  
...  

2020 ◽  
Vol 142 (43) ◽  
pp. 18422-18436 ◽  
Author(s):  
Theodosios Famprikis ◽  
Ö. Ulaş Kudu ◽  
James A. Dawson ◽  
Pieremanuele Canepa ◽  
François Fauth ◽  
...  

2018 ◽  
Vol 402 ◽  
pp. 513-518 ◽  
Author(s):  
Jian-Fang Wu ◽  
Qi Wang ◽  
Xin Guo

2020 ◽  
Vol 22 (35) ◽  
pp. 20114-20122
Author(s):  
Arianna Massaro ◽  
Jocasta Avila ◽  
Kateryna Goloviznina ◽  
Ivan Rivalta ◽  
Claudio Gerbaldi ◽  
...  

Understanding the transport of sodium ions in ionic liquids is the key to design novel electrolyte materials for sodium-ion batteries.


2016 ◽  
Vol 55 (49) ◽  
pp. 15254-15257 ◽  
Author(s):  
Parameswara Rao Chinnam ◽  
Birane Fall ◽  
Dmitriy A. Dikin ◽  
AbdelAziz Jalil ◽  
Clifton R. Hamilton ◽  
...  

1973 ◽  
Vol 61 (2) ◽  
pp. 222-250 ◽  
Author(s):  
R. A. Sjodin ◽  
L. A. Beaugé

Net sodium influx under K-free conditions was independent of the intracellular sodium ion concentration, [Na]i, and was increased by ouabain. Unidirectional sodium influx was the sum of a component independent of [Na]i and a component that increased linearly with increasing [Na]i. Net influx of sodium ions in K-free solutions varied with the external sodium ion concentration, [Na]o, and a steady-state balance of the sodium ion fluxes occurred at [Na]o = 40 mM. When solutions were K-free and contained 10-4 M ouabain, net sodium influx varied linearly with [Na]o and a steady state for the intracellular sodium was observed at [Na]o = 13 mM. The steady state observed in the presence of ouabain was the result of a pump-leak balance as the external sodium ion concentration with which the muscle sodium would be in equilibrium, under these conditions, was 0.11 mM. The rate constant for total potassium loss to K-free Ringer solution was independent of [Na]i but dependent on [Na]o. Replacing external NaCl with MgCl2 brought about reductions in net potassium efflux. Ouabain was without effect on net potassium efflux in K-free Ringer solution with [Na]o = 120 mM, but increased potassium efflux in a medium with NaCl replaced by MgCl2. When muscles were enriched with sodium ions, potassium efflux into K-free, Mg++-substituted Ringer solution fell to around 0.1 pmol/cm2·s and was increased 14-fold by addition of ouabain.


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