A Self-Binding, Melt-Castable, Crystalline Organic Electrolyte for Sodium Ion Conduction

2016 ◽  
Vol 55 (49) ◽  
pp. 15254-15257 ◽  
Author(s):  
Parameswara Rao Chinnam ◽  
Birane Fall ◽  
Dmitriy A. Dikin ◽  
AbdelAziz Jalil ◽  
Clifton R. Hamilton ◽  
...  
Keyword(s):  
Sodium Ion ◽  
Organic Electrolyte ◽  
Ion Conduction

A Self-Binding, Melt-Castable, Crystalline Organic Electrolyte for Sodium Ion Conduction

2016 ◽  
Vol 128 (49) ◽  
pp. 15480-15483 ◽  
Author(s):  
Parameswara Rao Chinnam ◽  
Birane Fall ◽  
Dmitriy A. Dikin ◽  
AbdelAziz Jalil ◽  
Clifton R. Hamilton ◽  
...  
Keyword(s):  
Sodium Ion ◽  
Organic Electrolyte ◽  
Ion Conduction

scholarly journals Under Pressure: Mechanochemical Effects on Structure and Ion Conduction in the Sodium-Ion Solid Electrolyte Na3PS4

2020 ◽  
Vol 142 (43) ◽  
pp. 18422-18436 ◽  
Author(s):  
Theodosios Famprikis ◽  
Ö. Ulaş Kudu ◽  
James A. Dawson ◽  
Pieremanuele Canepa ◽  
François Fauth ◽  
...  
Keyword(s):  
Solid Electrolyte ◽  
Sodium Ion ◽  
Ion Conduction

Sodium-ion conduction in Na2Zn2TeO6 solid electrolytes

2018 ◽  
Vol 402 ◽  
pp. 513-518 ◽  
Author(s):  
Jian-Fang Wu ◽  
Qi Wang ◽  
Xin Guo
Keyword(s):  
Solid Electrolytes ◽  
Sodium Ion ◽  
Ion Conduction

scholarly journals Sodium Ion Conductivity in Superionic IL-Impregnated Metal-Organic Frameworks: Enhancing Stability Through Structural Disorder

2019 ◽  
Author(s):  
Vahid Nozari ◽  
Courtney Calahoo ◽  
Joshua M. Tuffnell ◽  
Philipp Adelhelm ◽  
Katrin Wondraczek ◽  
...  
Keyword(s):  
Ionic Conductivity ◽  
Room Temperature ◽  
Metal Organic Frameworks ◽  
Ambient Air ◽  
Ion Conductivity ◽  
Sodium Ion ◽  
Composite Electrolytes ◽  
Ion Conduction ◽  
General Importance ◽  
Metal Organic

<p>Metal—organic frameworks (MOFs) are intriguing host materials in composite electrolytes due to their ability for tailoring host-guest interactions by chemical tuning of the MOF backbone. Here, we introduce particularly high sodium ion conductivity into the zeolitic imidazolate framework ZIF-8 by impregnation with the sodium-salt-containing ionic liquid (IL) (Na0.1¬EMIM0.9)TFSI. We demonstrate an ionic conductivity exceeding 2×10-4 S ⋅cm-1 at room temperature, with an activation energy as low as 0.26 eV, i.e., the highest reported performance for room temperature Na+-related ion conduction in MOF-based composite electrolytes to date. Partial amorphization of the ZIF-backbone by ball-milling results in significant enhancement of the composite stability, reflecting in persistent and stable ionic conductivity during exposure to ambient air over up to 20 days. While the introduction of network disorder decelerates IL exudation and interactions with ambient contaminants, the ion conductivity is only marginally affected, decreasing linearly with decreasing crystallinity but still maintaining superionic behavior. This highlights the general importance of 3D networks of interconnected pores for efficient ion conduction in MOF/IL blends, whereas pore symmetry is a presumably less stringent condition.</p>

scholarly journals Non-flammable organic electrolyte for sodium-ion batteries

2020 ◽  
Vol 110 ◽  
pp. 106635 ◽  
Author(s):  
Yan Yu ◽  
Haiying Che ◽  
Xinrong Yang ◽  
Yonghong Deng ◽  
Linsen Li ◽  
...  
Keyword(s):  
Sodium Ion ◽  
Organic Electrolyte ◽  
Sodium Ion Batteries
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