Three-dimensional α-Fe2O3/carbon nanotube sponges as flexible supercapacitor electrodes

2015 ◽  
Vol 3 (42) ◽  
pp. 20927-20934 ◽  
Author(s):  
Xiaoping Cheng ◽  
Xuchun Gui ◽  
Zhiqiang Lin ◽  
Yongjia Zheng ◽  
Ming Liu ◽  
...  

The porous, flexible and compressible CNT@Fe2O3 sponges show high specific capacitance (>300 F g−1).

RSC Advances ◽  
2016 ◽  
Vol 6 (64) ◽  
pp. 58994-59000 ◽  
Author(s):  
Abdul Muqsit Khattak ◽  
Huajie Yin ◽  
Zahid Ali Ghazi ◽  
Bin Liang ◽  
Azhar Iqbal ◽  
...  

Three dimensional iron oxide/graphene aerogel hybrid (Fe2O3/GA) was synthesized and used as electrode materials in flexible supercapacitor devices, which show high specific capacitance of 440 F g−1 with 89% capacitance retention after 2200 cycles.


NANO ◽  
2018 ◽  
Vol 13 (01) ◽  
pp. 1850013 ◽  
Author(s):  
Chuanyin Xiong ◽  
Tiehu Li ◽  
Tingkai Zhao ◽  
Alei Dang ◽  
Xianglin Ji ◽  
...  

In this paper, a facile method is designed to fabricate three-dimensional (3D) graphene (GR)/manganese dioxide (MnO2) nanowall electrode material. The 3D GR/MnO2 hybrid is prepared by a combination of electrochemical deposition (ELD) and electrophoresis deposition (EPD), followed by thermal reduction (TR). Firstly, the 3D graphene oxide (GO)/MnO2 hybrid is obtained by the ELD–EPD method. Secondly, the 3D GR/MnO2 hybrid is obtained through hydrogen reduction at a certain temperature. The as-fabricated hybrid has been characterized by scanning electron microscope (SEM), transmission electron microscope (TEM) and Raman spectroscopy. The electrochemical properties have been also measured by cyclic voltammetry. The results showed that the 3D GR/MnO2 nanowalls hybrid has a high specific capacitance of 266.75[Formula: see text]Fg[Formula: see text] and a high energy density of 25.36[Formula: see text]Whkg[Formula: see text]. Moreover, a high specific capacitance (240.15[Formula: see text]Fg[Formula: see text]) at a high scan rate of 200[Formula: see text]mVs[Formula: see text] (90% capacity retention) has been also obtained. Additionally, the hybrid can serve directly as the electrodes of supercapacitor without adding binder. This work provides a novel road to fabricate a binder-free 3D GR-based hybrid for high-performance energy storage devices.


Materials ◽  
2020 ◽  
Vol 13 (1) ◽  
pp. 181 ◽  
Author(s):  
Ming Zhang ◽  
Xiaoli Dai ◽  
Cuixian Zhang ◽  
Yuanwu Fuan ◽  
Dingyu Yang ◽  
...  

In this work, we used the mixed solution of manganese acetate and sodium sulfate to deposit manganese dioxide on the three-dimensional porous nickel foam that was previously soaked in alcohol, and then the effects of solution concentrations on their capacitance properties were investigated. The surface morphology, microstructure, elemental valence and other information of the material were observed by scanning electron microscope (SEM), Transmission Electron Microscope (TEM), X-ray photoelectron spectroscopy (XPS), etc. The electrochemical properties of the material were tested by Galvanostatic charge-discharge (GCD), Cyclic Voltammetry (CV), Chronoamperometry (CA), Electrochemical impedance spectroscopy (EIS), etc. The MnO2 electrode prepared at lower concentrations can respectively reach a specific capacitance of 529.5 F g−1 and 237.3 F g−1 at the current density of 1 A g−1 and 10 A g−1, and after 2000 cycles, the capacity retention rate was still 79.8% of the initial capacitance, and the energy density can even reach 59.4 Wh Kg−1, while at the same time, it also has a lower electrochemical impedance (Rs = 1.18 Ω, Rct = 0.84 Ω).


2014 ◽  
Vol 16 (33) ◽  
pp. 17936-17942 ◽  
Author(s):  
Lei Yu ◽  
Nannan Shi ◽  
Qi Liu ◽  
Jun Wang ◽  
Bin Yang ◽  
...  

A novel sandwich-like structured Co–Al LDH–CNT composite has been successfully synthesized. The as-prepared Co–Al LDHs–CNTs composite exhibites a high specific capacitance and a good cycle stability over 2000 cycles


2015 ◽  
Vol 3 (24) ◽  
pp. 13011-13015 ◽  
Author(s):  
Xi Zhou ◽  
Anqi Wang ◽  
Yumei Pan ◽  
Chenfei Yu ◽  
Yun Zou ◽  
...  

An all-solid-state flexible supercapacitor that achieves a high specific capacitance of 442.5 F g−1was facilely synthesized based on a Co3O4@carbon nanotubes/polyindole composite.


2013 ◽  
Vol 2013 ◽  
pp. 1-5 ◽  
Author(s):  
Li Li ◽  
Chen Chen ◽  
Jing Xie ◽  
Zehuai Shao ◽  
Fuxin Yang

In recent years, flexible electronic devices pursued for potential applications. The design and the fabrication of a novel flexible nanoarchitecture by coating electrical conductive MWCNT fiber with ultrathin films of MnO2to achieve high specific capacitance, for micro-supercapacitors electrode applications, are demonstrated here. The MWCNT/MnO2composite fiber electrode was prepared by the electrochemical deposition which was carried out through using two different methods: cyclic voltammetry and potentiostatic methods. The cyclic voltammetry method can get “crumpled paper ball” morphology MnO2which has bigger specific capacitances than that achieved by potentiostatic method. The flexible micro-supercapacitor was fabricated by twisting two aligned MWCNT fibers and showed an area specific capacitance of 2.43 mF/cm2. The flexible micro-supercapacitors also enable promising applications in various fields.


Nanoscale ◽  
2017 ◽  
Vol 9 (45) ◽  
pp. 17710-17716 ◽  
Author(s):  
Zhaodongfang Gao ◽  
Junwei Yang ◽  
Jing Huang ◽  
Chuanxi Xiong ◽  
Quanling Yang

Conducting polymer based supercapacitors usually suffer from the difficulty of achieving high specific capacitance and good long-term stability simultaneously.


2018 ◽  
Vol 47 (47) ◽  
pp. 17146-17152 ◽  
Author(s):  
Xiao Liang ◽  
Qiufan Wang ◽  
Yun Ma ◽  
Daohong Zhang

A two-ply CNT yarn asymmetric supercapacitor was fabricated by assembling a CuCo2O4 nanowire positive electrode and a PPy nanoparticle negative electrode. The full cell exhibits a high specific capacitance of 59.55 mF cm−2 and a high energy density of 0.02 mW h cm−2.


2015 ◽  
Vol 3 (12) ◽  
pp. 6324-6329 ◽  
Author(s):  
Ramendra Sundar Dey ◽  
Hans Aage Hjuler ◽  
Qijin Chi

A facile and cost-effective approach to fabricate all-in-one supercapacitor electrodes is achieved with copper foam integrated three-dimensional reduced graphene oxide networks. The resulting electrodes display high specific capacitance close to the theoretical value of graphene and good charging–discharging stability.


2017 ◽  
Vol 5 (40) ◽  
pp. 21153-21160 ◽  
Author(s):  
Juan Sun ◽  
Qichong Zhang ◽  
Xiaona Wang ◽  
Jingxin Zhao ◽  
Jiabin Guo ◽  
...  

The fabricated electrode delivers high specific capacitance and is applied to fiber-shaped asymmetric supercapacitors.


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