scholarly journals Preparation of high oxygen storage capacity and thermally stable ceria–zirconia solid solution

2016 ◽  
Vol 6 (3) ◽  
pp. 897-907 ◽  
Author(s):  
Jie Li ◽  
Xiaofei Liu ◽  
Wangcheng Zhan ◽  
Yun Guo ◽  
Yanglong Guo ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Solid Solution ◽  
Catalytic Activity ◽  
Storage Capacity ◽  
Oxygen Storage Capacity ◽  
High Oxygen ◽  
Coprecipitation Method ◽  
Oxygen Storage ◽  
Thermally Stable ◽  
High Oxygen Storage Capacity

Ce0.5Zr0.5O2 prepared by the complexing–coprecipitation method (CZ-2) exhibits higher oxygen storage capacity (OSC) and thermal stability than that prepared by coprecipitation (CZ-1) or the complexing–coprecipitation-solution (CZ-3) method. After being aged at 1100 °C for 6 h, CZ-2a exhibited the highest OSC and catalytic activity.

Pt/porous nanorods of ceria as efficient high temperature catalysts with remarkable catalytic stability for carbon dioxide reforming of methane

2015 ◽  
Vol 3 (35) ◽  
pp. 18074-18082 ◽  
Author(s):  
Zhiyun Zhang ◽  
Jing Li ◽  
Wei Gao ◽  
Yuanyuan Ma ◽  
Yongquan Qu
Keyword(s):  
Carbon Dioxide ◽  
Thermal Stability ◽  
Catalytic Activity ◽  
Storage Capacity ◽  
Oxygen Storage Capacity ◽  
Oxygen Storage ◽  
High Catalytic Activity ◽  
Carbon Dioxide Reforming ◽  
Catalytic Stability ◽  
High Oxygen Storage Capacity

Pt/porous nanorods of CeO2 with a large surface area, a high oxygen storage capacity and a remarkable thermal stability exhibit high catalytic activity and stability for the carbon dioxide reforming of methane reaction at 800 °C.

scholarly journals Zr-Ce-Pr-O Mixed Oxide Phases with High Oxygen Storage Capacity (OSC)

2009 ◽  
Vol 73 (4) ◽  
pp. 262-267 ◽  
Author(s):  
Tadatoshi Murota ◽  
Kosuke Sogawa ◽  
Shinya Otsuka-Yao-Matsuo ◽  
Takahisa Omata
Keyword(s):  
Mixed Oxide ◽  
Storage Capacity ◽  
Oxygen Storage Capacity ◽  
High Oxygen ◽  
Oxygen Storage ◽  
Oxide Phases ◽  
High Oxygen Storage Capacity

Oxygen Storage Capacity of CexZr1-xO2 (0.4≤x≤0.8) Solid Solution Using Thermogravimetric Analysis

2013 ◽  
Vol 747 ◽  
pp. 579-582 ◽  
Author(s):  
N. Shanmuga Priya ◽  
Chandramohan Somayaji ◽  
S. Kanagaraj
Keyword(s):  
Solid Solution ◽  
Storage Capacity ◽  
Mixed Oxides ◽  
High Surface ◽  
High Surface Area ◽  
Oxygen Storage Capacity ◽  
Oxygen Storage ◽  
Co Precipitation ◽  
Good Number ◽  
High Oxygen Storage Capacity

The property of high oxygen storage capacity (OSC) of Ceria is an important component in three-way catalysts (TWC), which depends on the low reduction temperature, high surface area and stable crystalline structure. These are required to be improved using mixed oxides for the increased OSC of TWC. Though a good number of literature is available in Ceria-Zirconia mixed oxides, optimization of the composition of oxides based on OSC is very much limited. Hence, an attempt was made to optimize the composition of CexZr1-xO2 (0.4 x 0.8) (CZ) based on the OSC using thermogravimetric technique. The CZ solid solution was prepared by co-precipitation (COP) method using Ceria nitrate, and Zirconia oxy-choloride precursors, where the freshly prepared metal hydroxide precipitates were continuously stirred at 45 °C for 60 minutes followed by washing and drying to obtain the nanosized CZ particles. The formation of single nanocrystallite with less than 8 nm size solid solution was identified by XRD, and the same was confirmed by Micro Raman studies. It is observed that the trend of OSC in CZ solid solution was based on the ratio of Ce to Zr in the starting aqueous solution, where the OSC was found to be maximum at 1.5 and the corresponding OSC of the compound was about 0.14 μmol per gram of Ceria.

Cu-Doped Zr-Ce-Pr-O Mixed Oxide Phases with High Oxygen Storage Capacity (OSC)

2009 ◽  
Vol 73 (4) ◽  
pp. 268-274 ◽  
Author(s):  
Tadatoshi Murota ◽  
Kosuke Sogawa ◽  
Shinya Otsuka-Yao-Matsuo ◽  
Takahisa Omata
Keyword(s):  
Mixed Oxide ◽  
Storage Capacity ◽  
Oxygen Storage Capacity ◽  
High Oxygen ◽  
Oxygen Storage ◽  
Oxide Phases ◽  
High Oxygen Storage Capacity
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