A fluorophosphate glass–ceramic electrolyte with superior ionic conductivity and stability for Na-ion batteries

2015 ◽  
Vol 3 (34) ◽  
pp. 17558-17562 ◽  
Author(s):  
Yiwen Ni ◽  
Ruilin Zheng ◽  
Xiaowen Tan ◽  
Weiyan Yue ◽  
Peng Lv ◽  
...  
Keyword(s):  
Ionic Conductivity ◽  
Glass Ceramic ◽  
Ion Conductivity ◽  
Conductive Phase ◽  
Ceramic Electrolyte ◽  
Ion Conductivities ◽  
Fluorophosphate Glass

A new fluorophosphate (Na2O + NaF)–TiO2–B2O3–P2O5–ZrF4 (NTBPZ) glass and glass–ceramic have Na-ion conductivities up to 7 × 10−9 S cm−1 and 3 × 10−5 S cm−1, respectively. Na-ion conductivity improves due to formation of conductive phase NaTi2(PO4)3.

Na3+x[CrxTi2-x(PO4)3] glass-ceramic electrolyte: ionic conductivity and structural correlations for different heat treating temperatures and time schedules

Ionics ◽  
2019 ◽  
Vol 25 (9) ◽  
pp. 4179-4188
Author(s):  
Shyam Sundar Gandi ◽  
Suman Gandi ◽  
Venkata Rao Madduluri ◽  
Naresh Kumar Katari ◽  
Dimple P. Dutta ◽  
...  
Keyword(s):  
Ionic Conductivity ◽  
Glass Ceramic ◽  
Heat Treating ◽  
Ceramic Electrolyte

Preparation and characterization of highly sodium ion conducting Na3PS4–Na4SiS4 solid electrolytes

RSC Advances ◽  
2014 ◽  
Vol 4 (33) ◽  
pp. 17120-17123 ◽  
Author(s):  
Naoto Tanibata ◽  
Kousuke Noi ◽  
Akitoshi Hayashi ◽  
Masahiro Tatsumisago
Keyword(s):  
Glass Ceramic ◽  
Solid Electrolytes ◽  
Ion Conductivity ◽  
Sodium Ion ◽  
Ceramic Electrolyte ◽  
Ion Conducting

Glass–ceramic electrolyte in the system Na3PS4–Na4SiS4 exhibits a high Na+ ion conductivity of 7.4 × 10−4 S cm−1 at 25 °C.

Enhanced room temperature ionic conductivity of the LiBH4·1/2NH3–Al2O3 composite

2021 ◽  
Author(s):  
Ruixue Zhang ◽  
Wanying Zhao ◽  
Zhenzhen Liu ◽  
Shanghai Wei ◽  
Yigang Yan ◽  
...  
Keyword(s):  
Ionic Conductivity ◽  
Room Temperature ◽  
Ion Conductivity ◽  
Al2o3 Composite

In situ formed amorphous LiBH4·1/2NH3 on the surface of Al2O3 nanoparticles results in an enhanced ion conductivity of 1.1 × 10−3 S cm−1 at room temperature.

scholarly journals Upscaling of LATP synthesis: Stoichiometric screening of phase purity and microstructure to ionic conductivity maps

Ionics ◽  
2021 ◽  
Vol 27 (5) ◽  
pp. 2017-2025
Author(s):  
Nikolas Schiffmann ◽  
Ethel C. Bucharsky ◽  
Karl G. Schell ◽  
Charlotte A. Fritsch ◽  
Michael Knapp ◽  
...  
Keyword(s):  
Ionic Conductivity ◽  
Sol Gel ◽  
Ion Conductivity ◽  
Process Window ◽  
Lithium Aluminum ◽  
Potential Candidate ◽  
Secondary Phases ◽  
X Ray Diffraction ◽  
Battery Cell ◽  
Li Ion

AbstractLithium aluminum titanium phosphate (LATP) is known to have a high Li-ion conductivity and is therefore a potential candidate as a solid electrolyte. Via sol-gel route, it is already possible to prepare the material at laboratory scale in high purity and with a maximum Li-ion conductivity in the order of 1·10−3 s/cm at room temperature. However, for potential use in a commercial, battery-cell upscaling of the synthesis is required. As a first step towards this goal, we investigated whether the sol-gel route is tolerant against possible deviations in the concentration of the precursors. In order to establish a possible process window for sintering, the temperature interval from 800 °C to 1100 °C and holding times of 10 to 480 min were evaluated. The resulting phase compositions and crystal structures were examined by X-ray diffraction. Impedance spectroscopy was performed to determine the electrical properties. The microstructure of sintered pellets was analyzed by scanning electron microscopy and correlated to both density and ionic conductivity. It is shown that the initial concentration of the precursors strongly influences the formation of secondary phases like AlPO4 and LiTiOPO4, which in turn have an influence on ionic conductivity, densification behavior, and microstructure evolution.

Stabilizing Interface between Li2S–P2S5 Glass-Ceramic Electrolyte and Ether Electrolyte by Tuning Solvation Reaction

2021 ◽  
Author(s):  
Bo Fan ◽  
Wenzhi Li ◽  
Zhongkuan Luo ◽  
Xianghua Zhang ◽  
Hongli Ma ◽  
...  
Keyword(s):  
Glass Ceramic ◽  
Ceramic Electrolyte

Solid-State Dendrite Suppressing Glass-Ceramic Electrolyte for Enabling Lithium Metal Anode

2021 ◽  
Vol 168 (2) ◽  
pp. 020526
Author(s):  
Adrian Grant ◽  
Lazbourne Allie ◽  
Devon Lyman ◽  
Kenechukwu Nwabufoh ◽  
Eleston Maxie ◽  
...  
Keyword(s):  
Solid State ◽  
Glass Ceramic ◽  
Lithium Metal ◽  
Metal Anode ◽  
Ceramic Electrolyte ◽  
Lithium Metal Anode
Sign in / Sign up

Export Citation Format

Share Document