scholarly journals Metal-phosphide-doped Li7P3S11 glass-ceramic electrolyte with high ionic conductivity for all-solid-state lithium-sulfur batteries

2018 ◽  
Vol 97 ◽  
pp. 100-104 ◽  
Author(s):  
Qi Ge ◽  
Lei Zhou ◽  
Yi-meng Lian ◽  
Xiaoling Zhang ◽  
Renjie Chen ◽  
...  
2017 ◽  
Vol 5 (6) ◽  
pp. 2829-2834 ◽  
Author(s):  
Ruo-chen Xu ◽  
Xin-hui Xia ◽  
Xiu-li Wang ◽  
Yan Xia ◽  
Jiang-ping Tu

A novel high-quality MoS2-doped Li2S–P2S5glass-ceramic electrolyte (Li7P2.9S10.85Mo0.01) is successfully prepared by a facile combined method of high-energy ball milling plus annealing. The Li7P2.9S10.85Mo0.01electrolyte shows a high ionic conductivity and excellent electrochemical stability.


2020 ◽  
Vol 380 ◽  
pp. 122419 ◽  
Author(s):  
Zhijun Wu ◽  
Zhengkun Xie ◽  
Akihiro Yoshida ◽  
Xiaowei An ◽  
Zhongde Wang ◽  
...  

2017 ◽  
Vol 5 (13) ◽  
pp. 6310-6317 ◽  
Author(s):  
Ruo-chen Xu ◽  
Xin-hui Xia ◽  
Shu-han Li ◽  
Sheng-zhao Zhang ◽  
Xiu-li Wang ◽  
...  

A lithium superionic conductor of Li7P2.9Mn0.1S10.7I0.3 as solid electrolyte was successfully prepared via high-energy milling, possessing high ionic conductivity and excellent electrochemical stability. The prepared all solid state LSBs shows a large capacity of 796 mA h g−1 with good cycling stability.


2017 ◽  
Vol 5 (25) ◽  
pp. 12934-12942 ◽  
Author(s):  
Ouwei Sheng ◽  
Chengbin Jin ◽  
Jianmin Luo ◽  
Huadong Yuan ◽  
Cong Fang ◽  
...  

The solid-state Li–S batteries using N-CNs/S cathode and composite polymer electrolyte added IL@ZrO2can work at the human body temperature of 37 °C.


2021 ◽  
Vol 8 ◽  
Author(s):  
Chao Zheng ◽  
Kai Wang ◽  
Lujie Li ◽  
Hui Huang ◽  
Chu Liang ◽  
...  

Among many lithium secondary batteries, lithium–sulfur batteries stand out because of their high theoretical specific energy, low cost, non-toxicity and the fact that they cause no environmental pollution. However, due to poor electronic and ionic conductivity, shuttle effect, lithium dendrites and other defects, it remains a big challenge to achieve large-scale application of lithium-sulfur batteries. Here we report an all-solid-state lithium–sulfur battery based on Li-argyrodite Li6PS5Cl solid-state electrolytes through a slurry-coating method. Li6PS5Cl with a high ionic conductivity of 1.3 × 10–3 S cm−1 at room temperature is used as the solid electrolyte and the ion conductive additive in the electrode. The sulfur-based composite cathode is fabricated through a slurry-coating process by dispersing sulfur, Li6PS5Cl, ethyl cellulose, and carbon black in 1,3-dioxolane (DOL). This method can disperse the Li6PS5Cl around sulfur particles well, and the solvent does not react with any component of composite cathodes during preparation. The battery delivers a high discharge capacity of 962 mA h g−1 at room temperature for the first cycle at 80 mA g−1. While the Coulombic efficiency is approximately 99.5% during 100 cycles. This work provides a new insight into the combination method between the sulfide-type SSEs and sulfur cathodes, which is critical to the electrochemical performance of all-solid-state lithium-sulfur batteries.


2016 ◽  
Vol 18 (13) ◽  
pp. 3796-3803 ◽  
Author(s):  
Yue Lin ◽  
Jie Li ◽  
Kathy Liu ◽  
Yexiang Liu ◽  
Jin Liu ◽  
...  

Food grade starch flexible electrolyte with unique ionic conductivity at room temperature is reported for all-solid-state lithium sulfur batteries that deliver average capacities of 864 mA h g−1 at 0.1 C for 100 cycles and 388 mA h g−1 at 2 C for 2000 cycles.


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