scholarly journals Metal-free electrocatalytic hydrogen oxidation using frustrated Lewis pairs and carbon-based Lewis acids

2016 ◽  
Vol 7 (4) ◽  
pp. 2537-2543 ◽  
Author(s):  
Elliot J. Lawrence ◽  
Ewan R. Clark ◽  
Liam D. Curless ◽  
James M. Courtney ◽  
Robin J. Blagg ◽  
...  
Keyword(s):  
Lewis Acid ◽  
Lewis Acids ◽  
Hydrogen Oxidation ◽  
Synergistic Interaction ◽  
Frustrated Lewis Pairs ◽  
Metal Free ◽  
Carbon Based ◽  
Lewis Pairs

The synergistic interaction of a carbon-centred Lewis acid and borane “hydride shuttle” offers a metal-free, CO tolerant pathway to hydrogen oxidation.

Development of silica-supported frustrated Lewis pairs: highly active transition metal-free catalysts for the Z-selective reduction of alkynes

2016 ◽  
Vol 6 (3) ◽  
pp. 882-889 ◽  
Author(s):  
Kai C. Szeto ◽  
Wissam Sahyoun ◽  
Nicolas Merle ◽  
Jessica Llop Castelbou ◽  
Nicolas Popoff ◽  
...  
Keyword(s):  
Transition Metal ◽  
Lewis Acid ◽  
Selective Reduction ◽  
Frustrated Lewis Pairs ◽  
Acid Base ◽  
Metal Free ◽  
Highly Active ◽  
Active Transition ◽  
Lewis Pairs

Supported Lewis acid/base systems based have been prepared and characterized.

scholarly journals An Electrochemical Study of Frustrated Lewis Pairs: A Metal-Free Route to Hydrogen Oxidation

2014 ◽  
Vol 136 (16) ◽  
pp. 6031-6036 ◽  
Author(s):  
Elliot J. Lawrence ◽  
Vasily S. Oganesyan ◽  
David L. Hughes ◽  
Andrew E. Ashley ◽  
Gregory G. Wildgoose
Keyword(s):  
Hydrogen Oxidation ◽  
Electrochemical Study ◽  
Frustrated Lewis Pairs ◽  
Metal Free ◽  
Lewis Pairs

Reversible, metal-free hydrogenactivation by frustrated Lewis pairs

2011 ◽  
Vol 40 (5) ◽  
pp. 1091-1097 ◽  
Author(s):  
Chunfang Jiang ◽  
Olivier Blacque ◽  
Thomas Fox ◽  
Heinz Berke
Keyword(s):  
Frustrated Lewis Pairs ◽  
Metal Free ◽  
Lewis Pairs

Understanding the Reactivity of Geminal P/B and P/Al Frustrated Lewis Pairs in CO2 Addition and H2 Activation

2021 ◽  
Author(s):  
Muhammad Dzulfahmi Ramadhan ◽  
Panida Surawatanawong
Keyword(s):  
Transition Metal ◽  
Frustrated Lewis Pairs ◽  
Metal Free ◽  
Co2 Addition ◽  
Lewis Pairs

Understanding CO2 addition and H2 activation by geminal P/Z (Z = B, Al) frustrated Lewis pairs (FLPs) is crucial for the development of transition metal-free catalysts for hydrogenation of unsaturated...

Metal-Free Iodoperfluoroalkylation: Photocatalysis versus Frustrated Lewis Pair Catalysis

Synthesis ◽  
2020 ◽  
Vol 53 (01) ◽  
pp. 123-134
Author(s):  
Constantin Czekelius ◽  
Lucas Helmecke ◽  
Michael Spittler ◽  
Bernd M. Schmidt
Keyword(s):  
Visible Light ◽  
Visible Light Irradiation ◽  
Light Irradiation ◽  
Reaction Pathways ◽  
Frustrated Lewis Pairs ◽  
Metal Free ◽  
Comprehensive Account ◽  
Frustrated Lewis Pair ◽  
Catalytic Metal ◽  
Lewis Pairs

A comparison of two catalytic, metal-free iodoperfluoro­alkylation protocols is presented. Frustrated Lewis pairs [ t Bu3P/B(C6F5)3] or phosphines/phosphites under visible light irradiation efficiently mediate the functionalization of non-activated alkenes and alkynes. A comprehensive account of the corresponding substrate scopes as well as insights into the mechanistic details of both reaction pathways are provided.

Frustrated Lewis Pairs Comprising Nitrogen Lewis Acids for Si–H Bond Activation

2020 ◽  
Vol 132 (52) ◽  
pp. 23682-23685
Author(s):  
Idan Avigdori ◽  
Alla Pogoreltsev ◽  
Alexander Kaushanski ◽  
Natalia Fridman ◽  
Mark Gandelman
Keyword(s):  
Lewis Acids ◽  
Bond Activation ◽  
Frustrated Lewis Pairs ◽  
Lewis Pairs

Catalytic Hydrogenation with Frustrated Lewis Pairs: Selectivity Achieved by Size-Exclusion Design of Lewis Acids

2011 ◽  
Vol 18 (2) ◽  
pp. 574-585 ◽  
Author(s):  
Gábor Erős ◽  
Krisztina Nagy ◽  
Hasan Mehdi ◽  
Imre Pápai ◽  
Péter Nagy ◽  
...  
Keyword(s):  
Catalytic Hydrogenation ◽  
Lewis Acids ◽  
Size Exclusion ◽  
Frustrated Lewis Pairs ◽  
Lewis Pairs

Designing metal-free frustrated Lewis pairs for dihydrogen activation based on a carbene–borane system

Polyhedron ◽  
2019 ◽  
Vol 162 ◽  
pp. 1-7 ◽  
Author(s):  
Shahnaz S. Rohman ◽  
Chayanika Kashyap ◽  
Sabnam S. Ullah ◽  
Ankur Kanti Guha
Keyword(s):  
Frustrated Lewis Pairs ◽  
Metal Free ◽  
Lewis Pairs
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