Catalytic Hydrogenation with Frustrated Lewis Pairs: Selectivity Achieved by Size-Exclusion Design of Lewis Acids

2011 ◽  
Vol 18 (2) ◽  
pp. 574-585 ◽  
Author(s):  
Gábor Erős ◽  
Krisztina Nagy ◽  
Hasan Mehdi ◽  
Imre Pápai ◽  
Péter Nagy ◽  
...  
Keyword(s):  
Catalytic Hydrogenation ◽  
Lewis Acids ◽  
Size Exclusion ◽  
Frustrated Lewis Pairs ◽  
Lewis Pairs

ChemInform Abstract: Catalytic Hydrogenation with Frustrated Lewis Pairs: Selectivity Achieved by Size-Exclusion Design of Lewis Acids.

ChemInform ◽  
2012 ◽  
Vol 43 (21) ◽  
pp. no-no
Author(s):  
Gabor Eros ◽  
Krisztina Nagy ◽  
Hasan Mehdi ◽  
Imre Papai ◽  
Peter Nagy ◽  
...  
Keyword(s):  
Catalytic Hydrogenation ◽  
Lewis Acids ◽  
Size Exclusion ◽  
Frustrated Lewis Pairs ◽  
Lewis Pairs

Frustrated Lewis Pairs Comprising Nitrogen Lewis Acids for Si–H Bond Activation

2020 ◽  
Vol 132 (52) ◽  
pp. 23682-23685
Author(s):  
Idan Avigdori ◽  
Alla Pogoreltsev ◽  
Alexander Kaushanski ◽  
Natalia Fridman ◽  
Mark Gandelman
Keyword(s):  
Lewis Acids ◽  
Bond Activation ◽  
Frustrated Lewis Pairs ◽  
Lewis Pairs

Azaborines: synthesis and use in the generation of stabilized boron-substituted carbocations

2018 ◽  
Vol 47 (6) ◽  
pp. 1791-1795 ◽  
Author(s):  
J. J. Clarke ◽  
P. Eisenberger ◽  
S. S. Piotrkowski ◽  
C. M. Crudden
Keyword(s):  
Lewis Acids ◽  
Ring Expansion ◽  
Lewis Acidity ◽  
Frustrated Lewis Pairs ◽  
Carbene Insertion ◽  
Hydride Abstraction ◽  
Ring Expansion Reaction ◽  
Lewis Pairs

A formal N-heterocyclic carbene insertion into the B–H bond of 9-BBN followed by a ring expansion reaction is reported. NHC-9-BBN adducts were reacted in one or two steps to give the corresponding di- or triazaborines. Hydride abstraction of selected species with [Ph3C]+ is facile, giving rise to 6π-aromatic cations with Lewis acidity comparable to Lewis acids commonly employed in frustrated Lewis pairs.

scholarly journals Progress of Frustrated Lewis Pairs in Catalytic Hydrogenation

2017 ◽  
Vol 37 (2) ◽  
pp. 301 ◽  
Author(s):  
Hui Wang ◽  
Yi Zheng ◽  
Zhentao Pan ◽  
Hongliang Fu ◽  
Fei Ling ◽  
...  
Keyword(s):  
Catalytic Hydrogenation ◽  
Frustrated Lewis Pairs ◽  
Lewis Pairs

“Inverse” Frustrated Lewis Pairs – Activation of Dihydrogen with Organosuperbases and Moderate to Weak Lewis Acids

2016 ◽  
Vol 138 (10) ◽  
pp. 3286-3289 ◽  
Author(s):  
Suresh Mummadi ◽  
Daniel K. Unruh ◽  
Jiyang Zhao ◽  
Shuhua Li ◽  
Clemens Krempner
Keyword(s):  
Lewis Acids ◽  
Frustrated Lewis Pairs ◽  
Lewis Pairs

Alkenylborane-Derived Frustrated Lewis Pairs: Metal-Free Catalytic Hydrogenation Reactions of Electron-Deficient Alkenes

2012 ◽  
Vol 31 (15) ◽  
pp. 5638-5649 ◽  
Author(s):  
J. Sreedhar Reddy ◽  
Bao-Hua Xu ◽  
Tayseer Mahdi ◽  
Roland Fröhlich ◽  
Gerald Kehr ◽  
...  
Keyword(s):  
Catalytic Hydrogenation ◽  
Frustrated Lewis Pairs ◽  
Metal Free ◽  
Hydrogenation Reactions ◽  
Lewis Pairs
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