Dicarboxylate ligand-modulated assembly of new luminescent zinc(ii) coordination polymers with in situ formed tetrazole ligands: an experimental and theoretical study

RSC Advances ◽  
2016 ◽  
Vol 6 (4) ◽  
pp. 3341-3349 ◽  
Author(s):  
Rong-Yi Huang ◽  
Hao Jiang ◽  
Chang-Hai Zhu ◽  
Heng Xu
Keyword(s):  
Coordination Polymers ◽  
Theoretical Study ◽  
Photoluminescence Properties ◽  
Hydrothermal Reactions ◽  
Dicarboxylate Ligand

In situ hydrothermal reactions of 4-(1H-imidazol-1-yl)benzonitrile, Zn(NO3)2 and NaN3 with H2DPA or H2PYDC gave rise to two new zinc(ii) coordination polymers, which exhibit different intriguing architectures and photoluminescence properties.

A New Route for Preparing Coordination Polymers from Hydrothermal Reactions Involving in Situ Ligand Synthesis

2004 ◽  
Vol 43 (7) ◽  
pp. 2261-2266 ◽  
Author(s):  
Xi-Xue Hu ◽  
Ji-Qing Xu ◽  
Peng Cheng ◽  
Xiao-Yan Chen ◽  
Xiao-Bing Cui ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Hydrothermal Reactions ◽  
Ligand Synthesis

Crystal engineering of cadmium coordination polymers decorated with nitro-functionalized thiophene-2,5-dicarboxylate and structurally related bis(imidazole) ligands with varying flexibility

CrystEngComm ◽  
2015 ◽  
Vol 17 (33) ◽  
pp. 6441-6449 ◽  
Author(s):  
Li-Ping Xue ◽  
Zhao-Hao Li ◽  
Lu-Fang Ma ◽  
Li-Ya Wang
Keyword(s):  
Carboxylic Acid ◽  
Coordination Polymers ◽  
Crystal Engineering ◽  
Imidazole Ligand ◽  
Dicarboxylate Ligand ◽  
Ligand Synthesis ◽  
Imidazole Ligands

Five bis(imidazole) ligand modulated cadmium coordination polymers based on a new nitro-functionalized thiophene-2,5-dicarboxylate ligand or 4-nitro-thiophene-2-carboxylic acid involving in situ ligand synthesis.

One- and Three-Dimensional Coordination Polymers Containing Organic Ligands Produced Through in situ Hydrothermal Reactions

2004 ◽  
Vol 2004 (7) ◽  
pp. 1566-1569 ◽  
Author(s):  
Xi-Xue Hu ◽  
Cheng-Ling Pan ◽  
Ji-Qing Xu ◽  
Xiao-Bing Cui ◽  
Guang-Di Yang ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Three Dimensional ◽  
Organic Ligands ◽  
Hydrothermal Reactions

Novel, Acentric Metal–Organic Coordination Polymers from Hydrothermal Reactions Involving In Situ Ligand Synthesis

2002 ◽  
Vol 114 (20) ◽  
pp. 3954-3957 ◽  
Author(s):  
Ren-Gen Xiong ◽  
Xiang Xue ◽  
Hong Zhao ◽  
Xiao-Zeng You ◽  
Brendan F. Abrahams ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Hydrothermal Reactions ◽  
Metal Organic ◽  
Ligand Synthesis

Photocurrent-generating properties of bulk and few-layered Cd(ii) coordination polymers based on a rigid dicarboxylate ligand

2016 ◽  
Vol 45 (11) ◽  
pp. 4603-4613 ◽  
Author(s):  
Peng Gang Jiang ◽  
Pan Zhang ◽  
Yun Gong ◽  
Jian Hua Lin
Keyword(s):  
Coordination Polymers ◽  
Photocurrent Density ◽  
Dicarboxylate Ligand

Two Cd(ii) CPs based on a rigid ligand exhibit different photocurrent responses, and the in situ synthesized few-layered CP shows enhanced photocurrent density with respect to the bulk CP.

scholarly journals Morphology Controlled Synthesis of γ-Al2O3 Nano-Crystallites in Al@Al2O3 Core–Shell Micro-Architectures by Interfacial Hydrothermal Reactions of Al Metal Substrates

Nanomaterials ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 310
Author(s):  
Dohyeon Han ◽  
Doohwan Lee
Keyword(s):  
Electrostatic Interactions ◽  
Heterogeneous Catalysts ◽  
Metal Substrate ◽  
Inorganic Anions ◽  
Core Shell ◽  
Hydroxyl Groups ◽  
Hydrothermal Reactions ◽  
Fine Control ◽  
Reaction Processes

Fine control of morphology and exposed crystal facets of porous γ-Al2O3 is of significant importance in many application areas such as functional nanomaterials and heterogeneous catalysts. Herein, a morphology controlled in situ synthesis of Al@Al2O3 core–shell architecture consisting of an Al metal core and a porous γ-Al2O3 shell is explored based on interfacial hydrothermal reactions of an Al metal substrate in aqueous solutions of inorganic anions. It was found that the morphology and structure of boehmite (γ-AlOOH) nano-crystallites grown at the Al-metal/solution interface exhibit significant dependence on temperature, type of inorganic anions (Cl−, NO3−, and SO42−), and acid–base environment of the synthesis solution. Different extents of the electrostatic interactions between the protonated hydroxyl groups on (010) and (001) facets of γ-AlOOH and the inorganic anions (Cl−, NO3−, SO42−) appear to result in the preferential growth of γ-AlOOH toward specific crystallographic directions due to the selective capping of the facets by adsorption of the anions. It is hypothesized that the unique Al@Al2O3 core–shell architecture with controlled morphology and exposed crystal-facets of the γ-Al2O3 shell can provide significant intrinsic catalytic properties with enhanced heat and mass transport to heterogeneous catalysts for applications in many thermochemical reaction processes. The direct fabrication of γ-Al2O3 nano-crystallites from Al metal substrate with in-situ modulation of their morphologies and structures into 1D, 2D, and 3D nano-architectures explored in this work is unique and can offer significant opportunities over the conventional methods.

In situ construction of a MOF-derived carbon-encapsulated LiCoO2 heterostructure as a superior cathode for elevated-voltage lithium storage: from experimental to theoretical study

2020 ◽  
Vol 8 (14) ◽  
pp. 6607-6618 ◽  
Author(s):  
Jia Lin ◽  
Chenghui Zeng ◽  
Yueying Chen ◽  
Xiaoming Lin ◽  
Chao Xu ◽  
...  
Keyword(s):  
Carbon Coating ◽  
Theoretical Study ◽  
Lithium Storage ◽  
Surface Modified

A strategy is proposed for a surface-modified LiCoO2 heterostructure by in situ MOF-derived carbon coating to achieve a distinguished performance for elevated-voltage lithium storage.

Influence of Angular Dicarboxylate Ligand on the Structures of Single and Double Pillared-Layer Coordination Polymers of Co(II)

2015 ◽  
Vol 15 (8) ◽  
pp. 4156-4161 ◽  
Author(s):  
In-Hyeok Park ◽  
Raghavender Medishetty ◽  
Hyeong-Hwan Lee ◽  
Tun Seng Herng ◽  
Jun Ding ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Dicarboxylate Ligand
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