Shape-dependent catalytic activity of Fe3O4 nanostructures under the influence of an external magnetic field for multicomponent reactions in aqueous media

RSC Advances ◽  
2015 ◽  
Vol 5 (90) ◽  
pp. 74091-74101 ◽  
Author(s):  
E. Rafiee ◽  
M. Joshaghani ◽  
P. Ghaderi-Shekhi Abadi

Fe3O4 nanostructures were synthesized under external magnetic field, shown shape-dependent catalytic activity for the synthesis of imidazole derivatives in water.

Catalysts ◽  
2018 ◽  
Vol 8 (2) ◽  
pp. 69 ◽  
Author(s):  
Ana Ribeiro ◽  
Inês Matias ◽  
Elisabete Alegria ◽  
Ana Ferraria ◽  
Ana Botelho do Rego ◽  
...  

For the first time, a magnetic C-scorpionate catalyst was prepared from the iron(II) complex [FeCl2{κ3-HC(pz)3}] (pz = pyrazol-1-yl) and ferrite, using the sustainable mechanochemical synthetic procedure. Its catalytic activity for the cyclohexane oxidation with tert-butyl hydroperoxide (TBHP) was evaluated in different conditions, namely under microwave irradiation and under the effect of an external magnetic field. The use of such magnetic conditions significantly shifted the catalyst alcohol/ketone selectivity, thus revealing a promising, easy new protocol for tuning selectivity in important catalytic processes.


RSC Advances ◽  
2015 ◽  
Vol 5 (97) ◽  
pp. 79548-79555 ◽  
Author(s):  
Xiaohua Zhao ◽  
Xiang Liu

A novel NiFe2O4@GN–Pd was used as outstanding catalyst for the Suzuki reaction in EtOH/H2O. The hybrid catalyst could be recycled and reused with the simple application of an external magnetic field, while keeping similar catalytic activity for six successive reactions.


2020 ◽  
pp. 174751982092473
Author(s):  
Weisen Yang ◽  
Yingying Du ◽  
Feiyan Yi ◽  
Mingzhong Cai

Heterogeneous tandem cyclization of 2-alkynylbenzamides with ammonium acetate is achieved in acetonitrile at 85 °C using a magnetic nanoparticles-immobilized bipy-gold(III) complex and AgSbF6 as catalysts to afford a variety of 1-aminoisoquinoline derivatives in moderate to high yields. This heterogeneous gold catalyst can be easily recovered from the reaction mixture by simply applying an external magnetic field and can be recycled at least seven times without any apparent loss of catalytic activity.


1980 ◽  
Vol 41 (C1) ◽  
pp. C1-445-C1-445
Author(s):  
G. Langouche ◽  
N. S. Dixon ◽  
L. Gettner ◽  
S. S. Hanna

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