A novel phenolic ionic liquid for 1.5 molar CO2 capture: combined experimental and DFT studies

RSC Advances ◽  
2015 ◽  
Vol 5 (71) ◽  
pp. 58005-58009 ◽  
Author(s):  
Majid Vafaeezadeh ◽  
Javad Aboudi ◽  
Mohammad Mahmoodi Hashemi

A phenolic ionic liquid (IL) is introduced for carbon dioxide capture with 50% improvement on the absorption capacity compared to the current reported values for phenolic ILs.

2017 ◽  
Vol 66 ◽  
pp. 120-128 ◽  
Author(s):  
Lingdi Cao ◽  
Jubao Gao ◽  
Shaojuan Zeng ◽  
Haifeng Dong ◽  
Hongshuai Gao ◽  
...  

ChemSusChem ◽  
2017 ◽  
Vol 10 (24) ◽  
pp. 4927-4933 ◽  
Author(s):  
Nathalia M. Simon ◽  
Marcileia Zanatta ◽  
Francisco P. dos Santos ◽  
Marta C. Corvo ◽  
Eurico J. Cabrita ◽  
...  

2010 ◽  
Vol 55 (9) ◽  
pp. 3513-3519 ◽  
Author(s):  
Yansong Zhao ◽  
Xiangping Zhang ◽  
Shaojuan Zeng ◽  
Qing Zhou ◽  
Haifeng Dong ◽  
...  

Author(s):  
Ravinder Kumar ◽  
Mohammad Hossein Ahmadi ◽  
Dipen Kumar Rajak ◽  
Mohammad Alhuyi Nazari

Abstract Greenhouse gases emissions from large scale industries as well as gasoline based vehicles are mainly responsible for global warming since the 1980s. At present, it has triggered global efforts to reduce the level of GHG. The contribution of carbon dioxide (CO2) in polluting the environment is at a peak due to the excessive use of coal in power plants. So, serious attention is required to reduce the level of CO2 using advanced technologies. Carbon dioxide capture and storage may play an important role in this direction. In process industries, various carbon dioxide capture techniques can be used to reduce CO2 emissions. However, post-combustion carbon dioxide capture is on top priority. Nowadays the researcher is focusing their work on CO2 capture using hybrid solvent. This work highlights a review of carbon dioxide capture using various kind of hybrid solvent in a packed column. The various challenges for absorption efficiency enhancement and future direction are also discussed in the present work. It is concluded through the literature survey that hybrid solvent shows better efficiency in comparison to the aqueous solution used for CO2 capture.


2019 ◽  
Vol 2019 ◽  
pp. 1-11 ◽  
Author(s):  
Afaf Syalsabila ◽  
Abdulhalim Shah Maulud ◽  
Humbul Suleman ◽  
Nik Abdul Hadi Md Nordin

In this study, vapour-liquid equilibrium of CO2-loaded aqueous potassium salt of L-histidine was studied for a wide range of temperature (313.15–353.15 K), pressure (150–4000 kPa), and solvent concentrations (1–2.5 molar). The experimental results show that L-histidine has an excellent absorptive capacity for carbon dioxide. When compared to conventional solvent (monoethanolamine) and amino acid salt (potassium L-lysinate) at similar process conditions, L-histidine has superior absorption capacity. Moreover, modified Kent–Eisenberg model was used to correlate the VLE of the studied system with excellent agreement between the model and experimental values. The model exhibited an AARE% of 7.87%, which shows that it can satisfactorily predict carbon dioxide solubilities in aqueous potassium salt of L-histidine at other process conditions. Being a biological component in origin, almost negligibly volatile, and highly resistant to oxidative degradation, L-histidine offers certain operational advantages over other solvents used and has a promising potential for carbon dioxide capture.


ChemSusChem ◽  
2020 ◽  
Vol 13 (8) ◽  
pp. 2025-2031 ◽  
Author(s):  
Loris Lombardo ◽  
Heena Yang ◽  
Kun Zhao ◽  
Paul J. Dyson ◽  
Andreas Züttel

2013 ◽  
Vol 136 (1) ◽  
pp. 436-441 ◽  
Author(s):  
Inga Niedermaier ◽  
Matthias Bahlmann ◽  
Christian Papp ◽  
Claudia Kolbeck ◽  
Wei Wei ◽  
...  

Author(s):  
Peng Pei ◽  
Manohar Kulkarni

Integrated Gasification Combined Cycle (IGCC) is believed to be one of the most promising technologies to offer electricity and other de-carbon fuels with carbon capture requirement as well as to meet other emission regulations at a relatively low cost. As one of the most important parts, different gasification technologies can greatly influence the performance of the system. This paper develops a model to examine the feasibilities and advantages of using Ultra Superheated Steam (USS) gasification technology in IGCC power plant with carbon dioxide capture and storage (CCS). USS gasification technology converts coal into syngas by the endothermic steam reforming reaction, and the heat required for this reaction is provided by the sensible heat in the ultra superheated steam. A burner utilizes synthetic air (21% O2 and 79% H2O) to burn fuel gas to produce the USS flame for the gasification process. The syngas generated from USS gasification has a higher hydrogen fraction (more than 50%) then other gasification processes. This high ratio of hydrogen is considered to be desired for a “capture-ready” IGCC plant. After gas cleanup and water gas shift reaction, the syngas goes to the Selexol process for carbon dioxide removal. Detailed calculations and analysis are performed to test the performance of USS gasification technology used in IGCC generation systems. Final results such as net output, efficiency penalty for CO2 capture part, and net thermal efficiency are calculated and compared when three different coal types are used. This paper uses published data of USS gasification from previous research at the University of North Dakota. The model also tries to treat the IGCC with carbon dioxide capture system as a whole thermal system, the superheated steam used in USS gasification can be provided by extracting steam from the lower pressure turbine in the Rankine Cycle. The model will make reasonable use of various waste energies and steams for both mechanical and chemical processes to improve the performance of the plant, and incorporate CO2 capture system into the design concept of the power plant.


2018 ◽  
Vol 16 (2) ◽  
pp. 115-119
Author(s):  
А. Zhumagaliyeva ◽  
V. Gargiulo ◽  
Ye. Doszhanov ◽  
M. Alfe

In this work carbonized rice husk  was used as carbon-based solid matrix in the preparation of composite materials modified with Fe3O4 particles. Aim of this study is to exploit the advantages and shortcomings of using a real biomass as starting material for the preparation of sorbents for CO2 capture applications. Sorption capacity of the obtained composite materials was tested on fixed-bed  microreactor.


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