Designing structurally tunable and functionally versatile synthetic supercontainers

2016 ◽  
Vol 3 (2) ◽  
pp. 243-249 ◽  
Author(s):  
Feng-Rong Dai ◽  
Yupu Qiao ◽  
Zhenqiang Wang
Keyword(s):  
Catalytic Activity ◽  
Selective Binding ◽  
New Family ◽  
Metal Organic ◽  
Flexible Metal

A new family of flexible metal–organic supercontainers exhibit selective binding with cationic guests and tunable supramolecular catalytic activity.

Modulation of pore shape and adsorption selectivity by ligand functionalization in a series of “rob”-like flexible metal–organic frameworks

2018 ◽  
Vol 6 (36) ◽  
pp. 17409-17416 ◽  
Author(s):  
Javier Cepeda ◽  
Manuel Pérez-Mendoza ◽  
Antonio J. Calahorro ◽  
Nicola Casati ◽  
José Manuel Seco ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Pore Shape ◽  
Adsorption Selectivity ◽  
Paddle Wheel ◽  
New Family ◽  
Metal Organic ◽  
Flexible Metal

We report the synthesis of a new family of four new isoreticular metal–organic frameworks (MOFs) based on Cu–Cu paddle-wheel building units.

scholarly journals Synthesis of tetrazolo[1,5-a]pyrimidine-6-carbonitriles using HMTA-BAIL@MIL-101(Cr) as a superior heterogeneous catalyst

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Mohammad Hossein Abdollahi-Basir ◽  
Boshra Mirhosseini-Eshkevari ◽  
Farzad Zamani ◽  
Mohammad Ali Ghasemzadeh
Keyword(s):  
Ionic Liquid ◽  
Catalytic Activity ◽  
Reaction Time ◽  
Metal Organic Framework ◽  
One Pot ◽  
Short Reaction Time ◽  
Three Component Reaction ◽  
Metal Organic ◽  
Ft Ir ◽  
Novel Catalyst

AbstractA one-pot three component reaction of benzaldehydes, 1H-tetrazole-5-amine, and 3-cyanoacetyl indole in the presence of a new hexamethylenetetramine-based ionic liquid/MIL-101(Cr) metal–organic framework as a recyclable catalyst was explored. This novel catalyst, which was fully characterized by XRD, FE-SEM, EDX, FT-IR, TGA, BET, and TEM exhibited outstanding catalytic activity for the preparation of a range of pharmaceutically important tetrazolo[1,5-a]pyrimidine-6-carbonitriles with good to excellent yields in short reaction time.

scholarly journals Corrigendum: Tuning Gate‐Opening of a Flexible Metal–Organic Framework for Ternary Gas Sieving Separation

2021 ◽  
Vol 60 (8) ◽  
pp. 3850-3850
Author(s):  
Qiubing Dong ◽  
Xin Zhang ◽  
Shuang Liu ◽  
Rui‐Biao Lin ◽  
Yanan Guo ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Gate Opening ◽  
Metal Organic ◽  
Flexible Metal ◽  
Organic Framework

From Ru nanoparticle-encapsulated metal–organic frameworks to highly catalytically active Cu/Ru nanoparticle-embedded porous carbon

2017 ◽  
Vol 5 (10) ◽  
pp. 4835-4841 ◽  
Author(s):  
Pradip Pachfule ◽  
Xinchun Yang ◽  
Qi-Long Zhu ◽  
Nobuko Tsumori ◽  
Takeyuki Uchida ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
High Temperature ◽  
Porous Carbon ◽  
Metal Organic Frameworks ◽  
Ammonia Borane ◽  
Carbon Composites ◽  
High Catalytic Activity ◽  
Catalytically Active ◽  
Metal Organic

High-temperature pyrolysis of Ru nanoparticle-encapsulated MOF (Ru@HKUST-1) afforded ultrafine Cu/Ru nanoparticle-embedded porous carbon composites (Cu/Ru@C), which show high catalytic activity for ammonia borane hydrolysis.

Methane storage in flexible metal–organic frameworks with intrinsic thermal management

Nature ◽  
2015 ◽  
Vol 527 (7578) ◽  
pp. 357-361 ◽  
Author(s):  
Jarad A. Mason ◽  
Julia Oktawiec ◽  
Mercedes K. Taylor ◽  
Matthew R. Hudson ◽  
Julien Rodriguez ◽  
...  
Keyword(s):  
Thermal Management ◽  
Metal Organic Frameworks ◽  
Methane Storage ◽  
Metal Organic ◽  
Flexible Metal

A Mesoporous Indium Metal–Organic Framework: Remarkable Advances in Catalytic Activity for Strecker Reaction of Ketones

2016 ◽  
Vol 138 (29) ◽  
pp. 9089-9092 ◽  
Author(s):  
Daniel Reinares-Fisac ◽  
Lina María Aguirre-Díaz ◽  
Marta Iglesias ◽  
Natalia Snejko ◽  
Enrique Gutiérrez-Puebla ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Metal Organic Framework ◽  
Strecker Reaction ◽  
Metal Organic ◽  
Indium Metal ◽  
Organic Framework

scholarly journals Exceptional adsorption-induced cluster and network deformation in the flexible metal–organic framework DUT-8(Ni) observed by in situ X-ray diffraction and EXAFS

2015 ◽  
Vol 17 (26) ◽  
pp. 17471-17479 ◽  
Author(s):  
Volodymyr Bon ◽  
Nicole Klein ◽  
Irena Senkovska ◽  
Andreas Heerwig ◽  
Jürgen Getzschmann ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
X Ray Diffraction ◽  
X Ray ◽  
Gate Opening ◽  
Metal Organic ◽  
Flexible Metal ◽  
Organic Framework

The “gate opening” mechanism in flexible MOF Ni2(2,6-ndc)2dabco was elucidated in detail.

A novel copper(ii)–lanthanum(iii) metal organic framework as a selective catalyst for the aerobic oxidation of benzylic hydrocarbons and cycloalkenes

2016 ◽  
Vol 6 (11) ◽  
pp. 3727-3736 ◽  
Author(s):  
P. Cancino ◽  
A. Vega ◽  
Andrea Santiago-Portillo ◽  
Sergio Navalon ◽  
Mercedes Alvaro ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Metal Organic Framework ◽  
Aerobic Oxidation ◽  
Selective Catalyst ◽  
Pyridinedicarboxylic Acid ◽  
Metal Organic ◽  
Organic Framework

The synthesis and catalytic activity of a novel heteronuclear CuII and LaIII metal organic framework (MOF) having pyridinedicarboxylic acid (CuLa-MOF) is reported.

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