Methane storage in flexible metal–organic frameworks with intrinsic thermal management

Nature ◽  
2015 ◽  
Vol 527 (7578) ◽  
pp. 357-361 ◽  
Author(s):  
Jarad A. Mason ◽  
Julia Oktawiec ◽  
Mercedes K. Taylor ◽  
Matthew R. Hudson ◽  
Julien Rodriguez ◽  
...  
Keyword(s):  
Thermal Management ◽  
Metal Organic Frameworks ◽  
Methane Storage ◽  
Metal Organic ◽  
Flexible Metal

scholarly journals High-throughput gas separation by flexible metal–organic frameworks with fast gating and thermal management capabilities

2020 ◽  
Vol 11 (1) ◽  
Author(s):  
Shotaro Hiraide ◽  
Yuta Sakanaka ◽  
Hiroshi Kajiro ◽  
Shogo Kawaguchi ◽  
Minoru T. Miyahara ◽  
...  
Keyword(s):  
Thermal Management ◽  
Gas Separation ◽  
High Throughput ◽  
Metal Organic Frameworks ◽  
Fast Gating ◽  
Metal Organic ◽  
Flexible Metal ◽  
Management Capabilities

scholarly journals Unravelling thermal stress due to thermal expansion mismatch in metal–organic frameworks for methane storage

2021 ◽  
Author(s):  
Jelle Wieme ◽  
Veronique Van Speybroeck
Keyword(s):  
Thermal Expansion ◽  
Thermal Stress ◽  
Pressure Coefficient ◽  
Metal Organic Frameworks ◽  
Methane Storage ◽  
Thermal Expansion Mismatch ◽  
Thermal Pressure ◽  
Temperature Changes ◽  
Metal Organic ◽  
The Impact

Thermal stress is present in metal–organic frameworks undergoing temperature changes during adsorption and desorption. We computed the thermal pressure coefficient as a proxy for this phenomenon and discuss the impact of thermal expansion mismatch.

High Methane Storage Working Capacity in Metal–Organic Frameworks with Acrylate Links

2016 ◽  
Vol 138 (32) ◽  
pp. 10244-10251 ◽  
Author(s):  
Juncong Jiang ◽  
Hiroyasu Furukawa ◽  
Yue-Biao Zhang ◽  
Omar M. Yaghi
Keyword(s):  
Metal Organic Frameworks ◽  
Methane Storage ◽  
Working Capacity ◽  
Metal Organic

Intermediate states approach for adsorption studies in flexible metal–organic frameworks

2019 ◽  
Vol 21 (6) ◽  
pp. 3294-3303 ◽  
Author(s):  
Justyna Rogacka ◽  
Filip Formalik ◽  
Azahara L. Triguero ◽  
Lucyna Firlej ◽  
Bogdan Kuchta ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
P Adsorption ◽  
Adsorption Studies ◽  
Intermediate States ◽  
Metal Organic ◽  
Flexible Metal

Adsorption studies in flexible metal–organic frameworks are challenging and time-consuming.

scholarly journals Temperature dependence of adsorption hysteresis in flexible metal organic frameworks

2020 ◽  
Vol 3 (1) ◽  
Author(s):  
Shamsur Rahman ◽  
Arash Arami-Niya ◽  
Xiaoxian Yang ◽  
Gongkui Xiao ◽  
Gang (Kevin) Li ◽  
...  
Keyword(s):  
Temperature Dependence ◽  
Capillary Condensation ◽  
Metal Organic Frameworks ◽  
Sorption Isotherms ◽  
Separation Performance ◽  
Process Simulations ◽  
Metal Organic ◽  
Flexible Metal ◽  
Pressure Swing ◽  
External Stimuli

Abstract“Breathing” and “gating” are striking phenomena exhibited by flexible metal-organic frameworks (MOFs) in which their pore structures transform upon external stimuli. These effects are often associated with eminent steps and hysteresis in sorption isotherms. Despite significant mechanistic studies, the accurate description of stepped isotherms and hysteresis remains a barrier to the promised applications of flexible MOFs in molecular sieving, storage and sensing. Here, we investigate the temperature dependence of structural transformations in three flexible MOFs and present a new isotherm model to consistently analyse the transition pressures and step widths. The transition pressure reduces exponentially with decreasing temperature as does the degree of hysteresis (c.f. capillary condensation). The MOF structural transition enthalpies range from +6 to +31 kJ·mol−1 revealing that the adsorption-triggered transition is entropically driven. Pressure swing adsorption process simulations based on flexible MOFs that utilise the model reveal how isotherm hysteresis can affect separation performance.

scholarly journals Amino Acid Residues Determine the Response of Flexible Metal–Organic Frameworks to Guests

2020 ◽  
Vol 142 (35) ◽  
pp. 14903-14913 ◽  
Author(s):  
Yong Yan ◽  
Elliot J. Carrington ◽  
Rémi Pétuya ◽  
George F. S. Whitehead ◽  
Ajay Verma ◽  
...  
Keyword(s):  
Amino Acid ◽  
Metal Organic Frameworks ◽  
Amino Acid Residues ◽  
Metal Organic ◽  
Flexible Metal

Elucidation of flexible metal-organic frameworks: Research progresses and recent developments

2019 ◽  
Vol 389 ◽  
pp. 161-188 ◽  
Author(s):  
Jae Hwa Lee ◽  
Sungeun Jeoung ◽  
Yongchul G. Chung ◽  
Hoi Ri Moon
Keyword(s):  
Metal Organic Frameworks ◽  
Recent Developments ◽  
Metal Organic ◽  
Flexible Metal
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