Heterometallic coordination polymers: syntheses, structures and heterogeneous catalytic applications

2015 ◽  
Vol 39 (12) ◽  
pp. 9772-9781 ◽  
Author(s):  
Deepak Bansal ◽  
Saurabh Pandey ◽  
Geeta Hundal ◽  
Rajeev Gupta
Keyword(s):  
Coordination Polymers ◽  
Heterogeneous Catalysts ◽  
Preferential Interaction ◽  
Heterogeneous Catalytic ◽  
Heterometallic Coordination Polymers ◽  
Catalytic Applications

Heterometallic coordination polymers function as heterogeneous catalysts for various organic transformation reactions via preferential interaction with the substrates.

Creation and stabilisation of tuneable open metal sites in thiocyanato-bridged heterometallic coordination polymers to be used as heterogeneous catalysts

2019 ◽  
Vol 48 (45) ◽  
pp. 17063-17069 ◽  
Author(s):  
Hiroyasu Tabe ◽  
Masaaki Matsushima ◽  
Rika Tanaka ◽  
Yusuke Yamada
Keyword(s):  
Single Crystal ◽  
Coordination Polymers ◽  
Heterogeneous Catalysts ◽  
X Ray ◽  
Open Metal Sites ◽  
Heterometallic Coordination Polymers

A series of {MII[PtIV(SCN)6]}n and {MII(CH3OH)x[PtIV(SCN)6]}n were characterised by single-crystal X-ray analyses and examined as heterogeneous catalysts to clarify the requisites for better catalysis.

Construction of Co/Ni-based coordination polymers with three-dimensional isostructural frameworks and multiple catalytic applications

2021 ◽  
Vol 296 ◽  
pp. 121979
Author(s):  
Xiuling Zhang ◽  
Yaoqiang Jin ◽  
Guangyin Wang ◽  
Aizhen Liu ◽  
Da-Shuai Zhang ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Three Dimensional ◽  
Catalytic Applications

Functionalized resorcin[4]arene-based coordination polymers as heterogeneous catalysts for click reactions

2021 ◽  
Vol 45 (6) ◽  
pp. 3181-3187
Author(s):  
Fei-Fei Wang ◽  
Jia-Hui Li ◽  
Hai-Yan Liu ◽  
Shu-Ping Deng ◽  
Ying-Ying Liu ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Heterogeneous Catalysts ◽  
Click Reactions

One Cu(i) and two Cd(ii) coordination polymers have been achieved using a 4-mercaptopyridine-functionalized resorcin[4]arene. 1 exhibits predominant efficiency and excellent recyclability for the synthesis of 1,2,3-triazoles and β-OH-1,2,3-triazoles.

Three-dimensional lanthanide–silver heterometallic coordination polymers: syntheses, structures and properties

CrystEngComm ◽  
2010 ◽  
Vol 12 (10) ◽  
pp. 3267 ◽  
Author(s):  
Man-Sheng Chen ◽  
Zhi Su ◽  
Min Chen ◽  
Shui-Sheng Chen ◽  
Yi-Zhi Li ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Three Dimensional ◽  
Structures And Properties ◽  
Heterometallic Coordination Polymers

Homo- and Heterometallic Coordination Polymers from the F Elements

ChemInform ◽  
2007 ◽  
Vol 38 (51) ◽  
Author(s):  
Christopher L. Cahill ◽  
Daniel T. de Lill ◽  
Mark Frisch
Keyword(s):  
Coordination Polymers ◽  
Heterometallic Coordination Polymers

Porous cross-linked polymer copper and iridium catalyzed the synthesis of quinoxalines and functionalized ketones under solvent-free conditions

2021 ◽  
Author(s):  
Jiahao Li ◽  
Minyi Yu ◽  
Zheng-Chao Duan ◽  
Haiyan Zhu ◽  
Wei Yao ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Solvent Free ◽  
Highly Active ◽  
Solvent Free Conditions ◽  
Catalytic Applications

The development of highly active and efficient ligands is recognized to be crucial for catalytic applications of coordination polymers under specific conditions, such as solvent-free or in water. A new...

scholarly journals Chemocatalytic Production of Lactates from Biomass-Derived Sugars

2018 ◽  
Vol 2018 ◽  
pp. 1-18 ◽  
Author(s):  
Heng Zhang ◽  
Yulin Hu ◽  
Liying Qi ◽  
Jian He ◽  
Hu Li ◽  
...  
Keyword(s):  
Lactic Acid ◽  
Heterogeneous Catalysts ◽  
Catalytic Performance ◽  
Green Solvents ◽  
Separation And Purification ◽  
Sustainable Resources ◽  
Base Catalysts ◽  
Heterogeneous Catalytic ◽  
Acid And Base ◽  
Relative Separation

In recent decades, a great deal of attention has been paid to the exploration of alternative and sustainable resources to produce biofuels and valuable chemicals, with aims of reducing the reliance on depleting confined fossil resources and alleviating serious economic and environmental issues. In line with this, lignocellulosic biomass-derived lactic acid (LA, 2-hydroxypropanoic acid), to be identified as an important biomass-derived commodity chemical, has found wide applications in food, pharmaceuticals, and cosmetics. In spite of the current fermentation of saccharides to produce lactic acid, sustainability issues such as environmental impact and high cost derived from the relative separation and purification process will be growing with the increasing demands of necessary orders. Alternatively, chemocatalytic approaches to manufacture LA from biomass (i.e., inedible cellulose) have attracted extensive attention, which may give rise to higher productivity and lower costs related to product work-up. This work presents a review of the state-of-the-art for the production of LA using homogeneous, heterogeneous acid, and base catalysts, from sugars and real biomass like rice straw, respectively. Furthermore, the corresponding bio-based esters lactate which could serve as green solvents, produced from biomass with chemocatalysis, is also discussed. Advantages of heterogeneous catalytic reaction systems are emphasized. Guidance is suggested to improve the catalytic performance of heterogeneous catalysts for the production of LA.

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