Deep eutectic solvent system based on choline chloride-urea as a pre-treatment for nanofibrillation of wood cellulose

2015 ◽  
Vol 17 (6) ◽  
pp. 3401-3406 ◽  
Author(s):  
Juho Antti Sirviö ◽  
Miikka Visanko ◽  
Henrikki Liimatainen
Keyword(s):  
Choline Chloride ◽  
Deep Eutectic Solvent ◽  
Solvent System ◽  
Wood Cellulose ◽  
Pre Treatment ◽  
Mechanical Nanofibrillation

Deep eutectic solvent of choline chloride-urea was used as a sustainable pre-treatment media prior mechanical nanofibrillation of wood cellulose.

Efficient synthesis of a novel series of indeno-fused pyrido[2,3-d]pyrimidines using a deep eutectic solvent system comprised of choline chloride/urea

2017 ◽  
Vol 41 (7) ◽  
pp. 430-433
Author(s):  
Mohammad Hakimi Roknabadi ◽  
Mohammad Hossein Mosslemin ◽  
Razieh Mohebat
Keyword(s):  
Choline Chloride ◽  
Deep Eutectic Solvent ◽  
Environmentally Friendly ◽  
Solvent System ◽  
Efficient Synthesis ◽  
Reaction Conditions ◽  
Three Component Reaction ◽  
High Yields

A series of 13 aryl indeno[2′,1′:5,6]pyrido[2,3- d]pyrimidine-2,4,6-(3 H,5 H,11 H)-triones, eight of which are new, were synthesised regioselectively in high yields by a three-component reaction of 1,3-indanedione, an araldehyde and 6-aminopyrimidin-2,4(1 H,3 H)-dione in the presence of a deep eutectic solvent comprised of choline chloride/urea (1:2) as the catalyst. The reaction conditions were mild and did not require additional catalysts. Given the inexpensive, nontoxic and recyclable nature of the deep eutectic solvent, these reaction conditions are simple to carry out and environmentally friendly.

scholarly journals A detailed study of cholinium chloride and levulinic acid deep eutectic solvent system for CO2 capture via experimental and molecular simulation approaches

2015 ◽  
Vol 17 (32) ◽  
pp. 20941-20960 ◽  
Author(s):  
Ruh Ullah ◽  
Mert Atilhan ◽  
Baraa Anaya ◽  
Majeda Khraisheh ◽  
Gregorio García ◽  
...  
Keyword(s):  
Molecular Simulation ◽  
Co2 Capture ◽  
Levulinic Acid ◽  
Choline Chloride ◽  
Deep Eutectic Solvent ◽  
Solvent System ◽  
Suitable Material

Choline chloride + levulinic acid deep eutectic solvent is studied as a suitable material for CO2 capturing purposes.

scholarly journals Mass transfer intensification in bioactive compounds recovery by alternative extraction methods: effects of solvent

2018 ◽  
Vol 21 (1) ◽  
pp. 30-36
Keyword(s):  
Bioactive Compounds ◽  
Choline Chloride ◽  
Low Frequency ◽  
Deep Eutectic Solvents ◽  
Solvent System ◽  
Extraction Methods ◽  
Ultrasound Assisted Extraction ◽  
Power Intensity ◽  
Natural Deep Eutectic Solvents ◽  
Pre Treatment

<p>Recently, the exploration of new alternatives to common organic solvents in combination with non-conventional energy sources is a subject of intense research and development as tools for green extraction of plant-derived natural products. This paper deals with the use of low frequency ultrasound (100 W, 32 kHz) and pulsed electrical fields (0.86 kV cm-1, 13 Hz) to raise the efficiency of the extraction of selected plant species rich in valuable phenolic compounds.Four types of natural deep eutectic solvents were applied for the ultrasound-assisted extraction of silymarin from milk thistle among which a choline-chloride-based mixture with glycerol was proved to be the most promising one. Additionally, the usage of high ultrasound power significantly increased the concentration of sylimarin as compared to traditional ethanol extraction, generating rapidly for 10 min considerable temperature rise as a side effect under non-cooling conditions. The application of PEF as a pre-treatment for 0.8 s to the extraction allowed reducing the ethanol percentage in the ethanol/water mixtures giving comparable phenolic yields, without any, or very little, increase in temperature. As such, optimized power intensity in conjunction with appropriate solvent system provides a potential to improve the release of thermally unstable bioactive compounds under mild processing conditions.</p>

Silver nanoparticles synthesized by laser ablation confined in urea choline chloride deep-eutectic solvent

2016 ◽  
Vol 12 ◽  
pp. 1-4 ◽  
Author(s):  
David O. Oseguera-Galindo ◽  
Roberto Machorro-Mejia ◽  
Nina Bogdanchikova ◽  
Josue D. Mota-Morales
Keyword(s):  
Silver Nanoparticles ◽  
Laser Ablation ◽  
Choline Chloride ◽  
Deep Eutectic Solvent

A Utilization of Choline Chloride-Based Deep Eutectic Solvent Integrated with Alkaline Earth Metal Hexahydrate in the Pretreatment of Oil Palm Fronds

2021 ◽  
Vol 60 (5) ◽  
pp. 2011-2026
Author(s):  
Eng Kein New ◽  
Ta Yeong Wu ◽  
Khai Shing Voon ◽  
Alessandra Procentese ◽  
Katrina Pui Yee Shak ◽  
...  
Keyword(s):  
Oil Palm ◽  
Alkaline Earth ◽  
Choline Chloride ◽  
Deep Eutectic Solvent ◽  
Earth Metal ◽  
Alkaline Earth Metal ◽  
Oil Palm Fronds ◽  
Palm Fronds

scholarly journals Generation of highly amenable cellulose-Iβ via selective delignification of rice straw using a reusable cyclic ether-assisted deep eutectic solvent system

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Chiranjeevi Thulluri ◽  
Ravi Balasubramaniam ◽  
Harshad Ravindra Velankar
Keyword(s):  
Enzymatic Hydrolysis ◽  
Rice Straw ◽  
Deep Eutectic Solvent ◽  
Solvent System ◽  
Cyclic Ether ◽  
Cellulolytic Enzymes ◽  
Ammonium Bromide ◽  
Selective Delignification ◽  
Cellulose Iβ ◽  
Hydrolysis Of

AbstractCellulolytic enzymes can readily access the cellulosic component of lignocellulosic biomass after the removal of lignin during biomass pretreatment. The enzymatic hydrolysis of cellulose is necessary for generating monomeric sugars, which are then fermented into ethanol. In our study, a combination of a deep eutectic (DE) mixture (of 2-aminoethanol and tetra-n-butyl ammonium bromide) and a cyclic ether (tetrahydrofuran) was used for selective delignification of rice straw (RS) under mild conditions (100 °C). Pretreatment with DE-THF solvent system caused ~ 46% delignification whereas cellulose (~ 91%) and hemicellulose (~ 67%) recoveries remained higher. The new solvent system could be reused upto 10 subsequent cycles with the same effectivity. Interestingly, the DE-THF pretreated cellulose showed remarkable enzymatic hydrolysability, despite an increase in its crystallinity to 72.3%. Contrary to conventional pretreatments, we report for the first time that the enzymatic hydrolysis of pretreated cellulose is enhanced by the removal of lignin during DE-THF pretreatment, notwithstanding an increase in its crystallinity. The current study paves way for the development of newer strategies for biomass depolymerization with DES based solvents.

scholarly journals Comparison of Corn Stover Pretreatments with Lewis Acid Catalyzed Choline Chloride, Glycerol and Choline Chloride-Glycerol Deep Eutectic Solvent

Polymers ◽  
2021 ◽  
Vol 13 (7) ◽  
pp. 1170
Author(s):  
Yuan Zhu ◽  
Benkun Qi ◽  
Xinquan Liang ◽  
Jianquan Luo ◽  
Yinhua Wan
Keyword(s):  
Corn Stover ◽  
Lewis Acid ◽  
Choline Chloride ◽  
Deep Eutectic Solvent ◽  
Enzymatic Saccharification ◽  
Glycerol Solution ◽  
Cellulose Conversion ◽  
Biomass Processing ◽  
Acid Catalyzed ◽  
Highly Correlated

Herein, corn stover (CS) was pretreated by less corrosive lewis acid FeCl3 acidified solutions of neat and aqueous deep eutectic solvent (DES), aqueous ChCl and glycerol at 120 °C for 4 h with single FeCl3 pretreatment as control. It was unexpected that acidified solutions of both ChCl and glycerol were found to be more efficient at removing lignin and xylan, leading to higher enzymatic digestibility of pretreated CS than acidified DES. Comparatively, acidified ChCl solution exhibited better pretreatment performance than acidified glycerol solution. In addition, 20 wt% water in DES dramatically reduced the capability of DES for delignification and xylan removal and subsequent enzymatic cellulose saccharification of pretreated CS. Correlation analysis showed that enzymatic saccharification of pretreated CS was highly correlated to delignification and cellulose crystallinity, but lowly correlated to xylan removal. Recyclability experiments of different acidified pretreatment solutions showed progressive decrease in the pretreatment performance with increasing recycling runs. After four cycles, the smallest decrease in enzymatic cellulose conversion (22.07%) was observed from acidified neat DES pretreatment, while the largest decrease (43.80%) was from acidified ChCl pretreatment. Those findings would provide useful information for biomass processing with ChCl, glycerol and ChCl-glycerol DES.

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