scholarly journals A functional mesoporous ionic crystal based on polyoxometalate

2016 ◽  
Vol 45 (7) ◽  
pp. 2805-2809 ◽  
Author(s):  
Ryosuke Kawahara ◽  
Kazuma Niinomi ◽  
Junko N. Kondo ◽  
Mitsuhiro Hibino ◽  
Noritaka Mizuno ◽  
...  

A mesoporous ionic crystal is synthesized with a polyoxometalate and a macrocation with polar cyano groups. The compound possesses one-dimensional mesopores and shows high proton conductivity and catalytic activity, which are due to the water molecules in the mesopores.

2019 ◽  
Vol 48 (6) ◽  
pp. 2190-2196 ◽  
Author(s):  
Shuai-Liang Yang ◽  
Yue-Ying Yuan ◽  
Fei Ren ◽  
Chen-Xi Zhang ◽  
Qing-Lun Wang

A novel 2D nickel(ii) complex (1) has been successfully synthesized using a 2,2′-bipyridyl, polycarboxylsulfonate ligand H4SBTC and Ni2+ ions. Owing to the presence of abundant water molecules, hydrogen bond networks and other protons, 1 and its hybrid membranes demonstrate high proton conductivity.


RSC Advances ◽  
2020 ◽  
Vol 10 (13) ◽  
pp. 7803-7811 ◽  
Author(s):  
Yasuaki Matsuda ◽  
Kousei Funakoshi ◽  
Ryosuke Sebe ◽  
Genki Kobayashi ◽  
Masao Yonemura ◽  
...  

A fast proton conductor exhibiting high proton conductivity of 7.0 × 10−3 S cm−1 at 200 °C in a dry Ar gas flow was developed by designing water chains in a rigid tunnel framework.


2015 ◽  
Vol 3 (44) ◽  
pp. 22347-22352 ◽  
Author(s):  
Yuan Gao ◽  
Richard Broersen ◽  
Wouter Hageman ◽  
Ning Yan ◽  
Marjo C. Mittelmeijer-Hazeleger ◽  
...  

Hop hop hop: the proton conductivity of the [Nd(mpca)2Nd(H2O)6Mo(CN)8]·nH2O is enabled by lattice water molecules in its channels.


2017 ◽  
Vol 19 (43) ◽  
pp. 29077-29083 ◽  
Author(s):  
Sayaka Uchida ◽  
Reina Hosono ◽  
Ryo Eguchi ◽  
Ryosuke Kawahara ◽  
Ryota Osuga ◽  
...  

Li+ in an alkali metal ion-exchanged porous ionic crystal forms a dense and extensive hydrogen-bonding network of water molecules with mobile protons leading to a high proton conductivity (>10−3 S cm−1).


2009 ◽  
Vol 8 (10) ◽  
pp. 831-836 ◽  
Author(s):  
Sareeya Bureekaew ◽  
Satoshi Horike ◽  
Masakazu Higuchi ◽  
Motohiro Mizuno ◽  
Takashi Kawamura ◽  
...  

2009 ◽  
Vol 131 (9) ◽  
pp. 3144-3145 ◽  
Author(s):  
Teppei Yamada ◽  
Masaaki Sadakiyo ◽  
Hiroshi Kitagawa

2010 ◽  
pp. 232-237 ◽  
Author(s):  
Sareeya Bureekaew ◽  
Satoshi Horike ◽  
Masakazu Higuchi ◽  
Motohiro Mizuno ◽  
Takashi Kawamura ◽  
...  

2017 ◽  
Vol 53 (54) ◽  
pp. 7592-7595 ◽  
Author(s):  
C. Klumpen ◽  
S. Gödrich ◽  
G. Papastavrou ◽  
J. Senker

High proton conductivity mediated by water molecules adsorbed within the micro- and mesopores of the sulfonated porous polymer PAF-1.


2019 ◽  
Vol 59 (11) ◽  
pp. 2279-2289 ◽  
Author(s):  
Asheesh Singh ◽  
Anaparthi G. Kumar ◽  
Sayantani Saha ◽  
Rajdeep Mukherjee ◽  
Soumendu Bisoi ◽  
...  

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