Copper(i) complexes with phosphine derived from sparfloxacin. Part I – structures, spectroscopic properties and cytotoxicity

2015 ◽  
Vol 44 (28) ◽  
pp. 12688-12699 ◽  
Author(s):  
Urszula K. Komarnicka ◽  
Radosław Starosta ◽  
Agnieszka Kyzioł ◽  
Małgorzata Jeżowska-Bojczuk

New, water and air stable, CuI/CuNCS complexes with hydroxymethyldiphenylphosphine or phosphine derivatives of sparfloxacin and diimines are presented. Cytotoxic activity of these complexes is strongly dependent on the type of diimine and phosphine.

1970 ◽  
Vol 48 (11) ◽  
pp. 1730-1735 ◽  
Author(s):  
W. R. Cullen ◽  
J. A. J. Thompson

The ditertiary phosphines, [Formula: see text] (n = 1,2) react with [Rh(CO)2X]2 (X = Cl, Br) via unsymmetrical cleavage of the halide bridges to give ionic complexes [(P—P)2Rh]+ [cis-(CO)2RhX2]−. However the diarsine, [Formula: see text] (ffars) reacts in an anomalous manner to give the neutral dimer, [(ffars)Rh(CO)Cl]2. With an excess of the phosphines, (n = 1, 2 or 3) the ionic complexes [(P—P)2Rh]+Cl− are obtained. The physical and spectroscopic properties of the new compounds and the tendency of the ions, [(P—P)2Rh]+, not to undergo facile oxidative-addition reactions are discussed.


2013 ◽  
Vol 66 ◽  
pp. 388-399 ◽  
Author(s):  
Aziz Shahrisa ◽  
Somayeh Esmati ◽  
Ramin Miri ◽  
Omidreza Firuzi ◽  
Najmeh Edraki ◽  
...  

ChemInform ◽  
2005 ◽  
Vol 36 (3) ◽  
Author(s):  
A. A. Gidaspov ◽  
V. V. Bakharev ◽  
E. V. Kachanovskaya ◽  
E. A. Kosareva ◽  
M. V. Galkina ◽  
...  

2014 ◽  
Vol 12 (12) ◽  
pp. 929-936 ◽  
Author(s):  
De-Biao YAN ◽  
Dong-Ping ZHANG ◽  
Ming LI ◽  
Wen-Yuan LIU ◽  
Feng FENG ◽  
...  

ChemInform ◽  
2010 ◽  
Vol 31 (17) ◽  
pp. no-no
Author(s):  
Abdelhakim Elomri ◽  
Sylvie Michel ◽  
Michel Koch ◽  
Elisabeth Seguin ◽  
Francois Tillequin ◽  
...  

1995 ◽  
Vol 14 (1) ◽  
pp. 20-23 ◽  
Author(s):  
Alan H. Cowley ◽  
Christopher S. King ◽  
Andreas Decken

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