scholarly journals Exploring a novel preparation method of 1D metal organic frameworks based on supercritical CO2

2015 ◽  
Vol 44 (16) ◽  
pp. 7548-7553 ◽  
Author(s):  
A. López-Periago ◽  
O. Vallcorba ◽  
C. Frontera ◽  
C. Domingo ◽  
J. A. Ayllón
Keyword(s):  
Supercritical Co2 ◽  
Preparation Method ◽  
Metal Organic Frameworks ◽  
One Dimensional ◽  
Metal Organic

The preparation of copper(ii) one-dimensional MOFs using scCO2 as solvent is reported.

Accurate tuning of rare earth metal–organic frameworks with unprecedented topology for white-light emission

2020 ◽  
Vol 8 (4) ◽  
pp. 1374-1379 ◽  
Author(s):  
Yutong Wang ◽  
Kai Zhang ◽  
Xiaokang Wang ◽  
Xuelian Xin ◽  
Xiurong Zhang ◽  
...  
Keyword(s):  
White Light ◽  
Light Emission ◽  
Metal Organic Frameworks ◽  
Three Dimensional ◽  
Earth Metal ◽  
White Light Emission ◽  
One Dimensional ◽  
1D Chain ◽  
Secondary Building Units ◽  
Metal Organic

An unprecedented three-dimensional (3D) (3,4,5)-czkf topological framework (UPC-38) with one-dimensional (1D) chain secondary building units exhibits strong white light emission.

One-dimensional (1D) helical and 2D homochiral metal–organic frameworks built from a new chiral octahydrobinaphthalene-derived dicarboxylic acid

2008 ◽  
Vol 11 (9) ◽  
pp. 948-950 ◽  
Author(s):  
Xiang Ouyang ◽  
Zhenxia Chen ◽  
Xiaofeng Liu ◽  
Yongtai Yang ◽  
Mingli Deng ◽  
...  
Keyword(s):  
Dicarboxylic Acid ◽  
Metal Organic Frameworks ◽  
One Dimensional ◽  
Metal Organic

Syntheses, Crystal Structures and Luminescent Properties of Two Isostructural Fluorinated Metal–organic Frameworks Based on Mixed 2,3,5,6-tetrafluoro-1,4-bis(imidazole-1-yl-methyl)Benzene and Oxalate Ligands

2016 ◽  
Vol 40 (12) ◽  
pp. 763-766
Author(s):  
Sheng-Chun Chen ◽  
Feng Tian ◽  
Ming-Yang He ◽  
Qun Chen
Keyword(s):  
Fluorescence Spectra ◽  
Metal Organic Frameworks ◽  
Luminescent Properties ◽  
Hydrothermal Conditions ◽  
One Dimensional ◽  
Metal Organic ◽  
Solid State Fluorescence ◽  
The One ◽  
Methyl Benzene

Two isostructural fluorinated metal-organic frameworks [M(Fbix)(ox)]n (where M = Zn or Mn, Fbix = 2,3,5,6-tetrafluoro-1,4-bis(imidazole-1-yl-methyl)benzene, ox = oxalate) have been synthesised from Fbix and oxamide under hydrothermal conditions, where oxalate is generated by the in situ hydrolysation of oxamide. The complexes are isostructural and display similar two-dimensional undulating sql nets formed by pillaring the one-dimensional [M(ox)]n chains through Fbix linkers. Their solid-state fluorescence spectra indicate a ligand-based emission for both complexes.

scholarly journals Entropic Separations of Mixtures of Aromatics by Selective Face-to-Face Molecular Stacking in One-Dimensional Channels of Metal-Organic Frameworks and Zeolites

ChemPhysChem ◽  
2014 ◽  
Vol 16 (3) ◽  
pp. 532-535 ◽  
Author(s):  
Ariana Torres-Knoop ◽  
Salvador R. G. Balestra ◽  
Rajamani Krishna ◽  
Sofía Calero ◽  
David Dubbeldam
Keyword(s):  
Metal Organic Frameworks ◽  
One Dimensional ◽  
Face To Face ◽  
Metal Organic ◽  
Molecular Stacking

scholarly journals Exact matrix treatment of an osmotic ensemble model of adsorption and pressure induced structural transitions in metal organic frameworks

2016 ◽  
Vol 45 (10) ◽  
pp. 4213-4217 ◽  
Author(s):  
Lawrence J. Dunne ◽  
George Manos
Keyword(s):  
Metal Organic Frameworks ◽  
Structural Transformations ◽  
Ensemble Model ◽  
Structural Transitions ◽  
One Dimensional ◽  
Metal Organic ◽  
Statistical Mechanical ◽  
Exact Matrix

Here we present an exactly treated quasi-one dimensional statistical mechanical osmotic ensemble model of pressure and adsorption induced breathing structural transformations of metal–organic frameworks (MOFs).

scholarly journals Phosphonate Metal-Organic Frameworks: A Novel Family of Semiconductors

2020 ◽  
Author(s):  
Konrad Siemensmeyer ◽  
Craig A. Peeples ◽  
Patrik Tholen ◽  
Bünyemin Çoşut ◽  
Gabriel Hanna ◽  
...  
Keyword(s):  
Solid State ◽  
Dft Calculations ◽  
Band Gap ◽  
Narrow Band ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
One Dimensional ◽  
Metal Organic ◽  
Copper Dimers ◽  
Electrodes For Supercapacitors

<p>Herein is reported the first semiconducting and magnetic phosphonate metal-organic framework (MOF), TUB75, which contains a one-dimensional inorganic building unit composed of a zig-zag chain of corner-sharing copper dimers. The solid-state UV-Vis spectrum of TUB75 reveals the existence of a narrow band gap of 1.4 eV, which agrees well with the 1.77 eV one obtained from DFT calculations. Magnetization measurements show that TUB75 is composed of antiferromagnetically coupled copper dimer chains. Due to their rich structural chemistry and exceptionally high thermal/chemical stabilities, phosphonate MOFs like TUB75 may open new vistas in engineerable electrodes for supercapacitors. </p>

Structural variation of transition metal–organic frameworks using deep eutectic solvents with different hydrogen bond donors

2019 ◽  
Vol 48 (27) ◽  
pp. 10199-10209 ◽  
Author(s):  
Ming-Yu Zhao ◽  
Jian-Nan Zhu ◽  
Peng Li ◽  
Wei Li ◽  
Ting Cai ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Transition Metal ◽  
Structural Variation ◽  
Metal Organic Frameworks ◽  
Three Dimensional ◽  
Deep Eutectic Solvents ◽  
One Dimensional ◽  
Metal Organic ◽  
Hydrogen Bond Donors

Seven transition metal–organic frameworks with structures ranging from one-dimensional chains to three-dimensional networks have been synthesized in deep eutectic solvents.

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