A new insight into the nanostructure of alkylammonium alkanoates based ionic liquids in water

2016 ◽  
Vol 18 (16) ◽  
pp. 11497-11502 ◽  
Author(s):  
Umme Salma ◽  
Paolo Ballirano ◽  
Marianna Usula ◽  
Ruggero Caminiti ◽  
Natalia V. Plechkova ◽  
...  

In this paper, small angle X-ray scattering has been used to study a series of ionic liquids, alkylammonium alkanoates ([N0 0 0 n][CmCO2]), with varying alkyl chain lengths in the cation and the anion.

Soft Matter ◽  
2019 ◽  
Vol 15 (25) ◽  
pp. 5060-5066 ◽  
Author(s):  
Qintang Li ◽  
Kun Tong ◽  
Juan Qiu ◽  
Minhao Yan ◽  
Qiang Tian ◽  
...  

Surface active ionic liquids CnmimBr of different chain lengths would self-assemble into different aggregates in a deep eutectic solvent ChG.


2020 ◽  
Vol 22 (6) ◽  
pp. 3490-3498 ◽  
Author(s):  
Shurui Miao ◽  
Rob Atkin ◽  
Gregory G. Warr

The liquid structures of six choline carboxylate/amino acid ionic liquids (bio-ILs) and their mixtures with water and various n-alkanols have been investigated by small-angle X-ray scattering (SAXS).


2011 ◽  
Vol 115 (21) ◽  
pp. 6827-6837 ◽  
Author(s):  
Joëlle Eyssautier ◽  
Pierre Levitz ◽  
Didier Espinat ◽  
Jacques Jestin ◽  
Jérémie Gummel ◽  
...  

2010 ◽  
Vol 22 (3) ◽  
pp. 803-812 ◽  
Author(s):  
S. S. Sekhon ◽  
Jin-Soo Park ◽  
Ji-Suk Baek ◽  
Sung-Dae Yim ◽  
Tae-Hyun Yang ◽  
...  

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Joanna Korpanty ◽  
Lucas R. Parent ◽  
Nicholas Hampu ◽  
Steven Weigand ◽  
Nathan C. Gianneschi

AbstractHerein, phase transitions of a class of thermally-responsive polymers, namely a homopolymer, diblock, and triblock copolymer, were studied to gain mechanistic insight into nanoscale assembly dynamics via variable temperature liquid-cell transmission electron microscopy (VT-LCTEM) correlated with variable temperature small angle X-ray scattering (VT-SAXS). We study thermoresponsive poly(diethylene glycol methyl ether methacrylate) (PDEGMA)-based block copolymers and mitigate sample damage by screening electron flux and solvent conditions during LCTEM and by evaluating polymer survival via post-mortem matrix-assisted laser desorption/ionization imaging mass spectrometry (MALDI-IMS). Our multimodal approach, utilizing VT-LCTEM with MS validation and VT-SAXS, is generalizable across polymeric systems and can be used to directly image solvated nanoscale structures and thermally-induced transitions. Our strategy of correlating VT-SAXS with VT-LCTEM provided direct insight into transient nanoscale intermediates formed during the thermally-triggered morphological transformation of a PDEGMA-based triblock. Notably, we observed the temperature-triggered formation and slow relaxation of core-shell particles with complex microphase separation in the core by both VT-SAXS and VT-LCTEM.


Soft Matter ◽  
2019 ◽  
Vol 15 (41) ◽  
pp. 8372-8380 ◽  
Author(s):  
Harald Rennhofer ◽  
Sven F. Plappert ◽  
Helga C. Lichtenegger ◽  
Sigrid Bernstorff ◽  
Michael Fitzka ◽  
...  

In this article we report on the nanostructural changes of a cellulose II aerogel network during compressive strain of up to 80%, which are investigated by in situ small angle X-ray scattering and linked to the corresponding stress–strain curves.


2015 ◽  
pp. 169-213 ◽  
Author(s):  
Joshua A. Hammons ◽  
Jan Ilavsky ◽  
Fan Zhang

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