Surface plasmon resonance of silver and gold nanoparticles in the proximity of graphene studied using the discrete dipole approximation method

2016 ◽  
Vol 18 (3) ◽  
pp. 2230-2241 ◽  
Author(s):  
Vincenzo Amendola

Surface plasmon resonance (SPR) of Ag and Au nanoparticles (spheres, rods, discs) is damped when they are located at less than 5 nm from graphene flakes or embedded in a graphene matrix.

Nanomaterials ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 1644 ◽  
Author(s):  
Luca Spitaleri ◽  
Chiara M. A. Gangemi ◽  
Roberto Purrello ◽  
Giuseppe Nicotra ◽  
Giuseppe Trusso Sfrazzetto ◽  
...  

Gold nanoparticles show important electronic and optical properties, owing to their size, shape, and electronic structures. Indeed, gold nanoparticles containing no more than 30–40 atoms are only luminescent, while nanometer-sized gold nanoparticles only show surface plasmon resonance. Therefore, it appears that gold nanoparticles can alternatively be luminescent or plasmonic and this represents a severe restriction for their use as optical material. The aim of our study was the fabrication of nanoscale assembly of Au nanoparticles with bi-functional porphyrin molecules that work as bridges between different gold nanoparticles. This functional architecture not only exhibits a strong surface plasmon, due to the Au nanoparticles, but also a strong luminescence signal due to porphyrin molecules, thus, behaving as an artificial organized plasmonic and fluorescent network. Mutual Au nanoparticles–porphyrin interactions tune the Au network size whose dimension can easily be read out, being the position of the surface plasmon resonance strongly indicative of this size. The present system can be used for all the applications requiring plasmonic and luminescent emitters.


Nanomaterials ◽  
2020 ◽  
Vol 10 (8) ◽  
pp. 1490
Author(s):  
Enrico Gazzola ◽  
Michela Cittadini ◽  
Marco Angiola ◽  
Laura Brigo ◽  
Massimo Guglielmi ◽  
...  

Solution processed TiO2 anatase film was used as sensitive layer for H2 detection for two plasmonic sensor configurations: A grating-coupled surface plasmon resonance sensor and a localized surface plasmon resonance sensor with gold nanoparticles. The main purpose of this paper is to elucidate the different H2 response observed for the two types of sensors which can be explained considering the hydrogen dissociation taking place on TiO2 at high temperature and the photocatalytic activity of the gold nanoparticles.


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