Syntheses, topological structures and properties of six metal–organic frameworks constructed from a flexible tetracarboxylate ligand

CrystEngComm ◽  
2015 ◽  
Vol 17 (16) ◽  
pp. 3162-3170 ◽  
Author(s):  
Yu Peng ◽  
Guanghua Li ◽  
Jia Hua ◽  
Zhan Shi ◽  
Shouhua Feng
Keyword(s):  
Metal Organic Frameworks ◽  
Topological Structures ◽  
Structures And Properties ◽  
Metal Organic ◽  
Solvothermal Conditions

Six new metal–organic frameworks (MOFs), Co2O(odip)(py)2(DMSO)2·3H2O (1), Co2(odip)(H2O)(DMA)2·2DMA (2), Co4(odip)2(H2O)4(DMSO)2·5DMSO (3), [Zn2(odip)(DMF)2(H2O)]·2DMF·2H2O (4), Zn2(odip)(H2O) (5) and In(odip)·3ACN (6), have been synthesized from the 5,5′-oxydiisophthalic acid (H4odip) ligand under solvothermal conditions.

scholarly journals Two Lanthanide Metal–Organic Frameworks Based on Semi-Rigid T-Shaped Tricarboxylate Ligand: Syntheses, Structures, and Properties

Polymers ◽  
2019 ◽  
Vol 11 (5) ◽  
pp. 868
Author(s):  
Yun-Shan Xue ◽  
Zhuo-Lin Chen ◽  
Youzhen Dong ◽  
Wei-Wei Cheng
Keyword(s):  
Near Infrared ◽  
Metal Organic Frameworks ◽  
Infrared Emission ◽  
Tripodal Ligand ◽  
Structures And Properties ◽  
3D Network ◽  
Metal Organic ◽  
Lanthanide Metal ◽  
Near Infrared Emission ◽  
Solvothermal Conditions

By using a semi-rigid tripodal ligand 5-(4-carboxybenzyloxy)isophthalic acid (H3L) and lanthanide metal ions (Nd3+, Tb3+), two novel lanthanide metal–organic frameworks, namely, {[Nd2L2(DMF)4] DMF}n (1), and {TbL(DMF)(H2O)}n (2), were synthesized under mild solvothermal conditions and structurally characterized by X-ray single crystal diffraction. Compounds 1 and 2 are isostructural, in which L3– ligands linked dinuclear lanthanide metal–carboxylate units to form non-interpenetrated 3D network with (3,6)-connected topology. Luminescent investigations reveal that compound 1 displays the near-infrared emission at room temperature, and compound 2 can be employed as selective probe for Cr2O72− anion in aqueous solution based on luminescence quenching. Moreover, compound 2 exhibits catalytic activity for cyclo-addition of CO2 and epoxides under relatively mild conditions.

Four new metal–organic frameworks based on bi-, tetra-, penta-, and hexa-nuclear clusters derived from 5-(phenyldiazenyl)isophthalic acid: syntheses, structures and properties

CrystEngComm ◽  
2015 ◽  
Vol 17 (5) ◽  
pp. 1201-1209 ◽  
Author(s):  
Hongming He ◽  
Jianshi Du ◽  
Hongmin Su ◽  
Yinhong Yuan ◽  
Yang Song ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Isophthalic Acid ◽  
Structures And Properties ◽  
Nuclear Clusters ◽  
Metal Organic ◽  
Solvothermal Conditions

Four new metal–organic frameworks (MOFs) were synthesized under solvothermal conditions based on a new rigid ligand 5-(phenyldiazenyl)isophthalic acid (H2PDIA) with azobenzene.

Elucidation of the Formation Mechanism of Metal–Organic Frameworks via in-Situ Raman and FTIR Spectroscopy under Solvothermal Conditions

2018 ◽  
Vol 122 (23) ◽  
pp. 12267-12278 ◽  
Author(s):  
Heidemarie Embrechts ◽  
Martin Kriesten ◽  
Kilian Hoffmann ◽  
Wolfgang Peukert ◽  
Martin Hartmann ◽  
...  
Keyword(s):  
Ftir Spectroscopy ◽  
Formation Mechanism ◽  
Metal Organic Frameworks ◽  
In Situ Raman ◽  
Metal Organic ◽  
Solvothermal Conditions

Experimental, DFT and quantum Monte Carlo studies of a series of peptide-based metal–organic frameworks: synthesis, structures and properties

2014 ◽  
Vol 1 (7) ◽  
pp. 526-533 ◽  
Author(s):  
Gui-lin Zhuang ◽  
Li Tan ◽  
Wu-lin Chen ◽  
Jun Zheng ◽  
Hong-zhou Yao ◽  
...  
Keyword(s):  
Monte Carlo ◽  
Quantum Monte Carlo ◽  
Monte Carlo Calculation ◽  
Metal Organic Frameworks ◽  
Experimental Measurements ◽  
Function Structure ◽  
Structures And Properties ◽  
Structure Relation ◽  
Monte Carlo Studies ◽  
Metal Organic

Properties and the function–structure relation of four peptide-based MOFs were identified by experimental measurements, DFT and quantum Monte Carlo calculation.

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