Four new metal–organic frameworks based on bi-, tetra-, penta-, and hexa-nuclear clusters derived from 5-(phenyldiazenyl)isophthalic acid: syntheses, structures and properties

CrystEngComm ◽  
2015 ◽  
Vol 17 (5) ◽  
pp. 1201-1209 ◽  
Author(s):  
Hongming He ◽  
Jianshi Du ◽  
Hongmin Su ◽  
Yinhong Yuan ◽  
Yang Song ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Isophthalic Acid ◽  
Structures And Properties ◽  
Nuclear Clusters ◽  
Metal Organic ◽  
Solvothermal Conditions

Four new metal–organic frameworks (MOFs) were synthesized under solvothermal conditions based on a new rigid ligand 5-(phenyldiazenyl)isophthalic acid (H2PDIA) with azobenzene.

scholarly journals Synthesis, structures and properties of metal–organic frameworks prepared using a semi-rigid tricarboxylate linker

CrystEngComm ◽  
2022 ◽  
Author(s):  
Daniel Rixson ◽  
Güneş Günay Sezer ◽  
Emre Alp ◽  
Mary F. Mahon ◽  
Andrew D. Burrows
Keyword(s):  
Single Crystal ◽  
Metal Organic Frameworks ◽  
Isophthalic Acid ◽  
Crystal Transformation ◽  
Structures And Properties ◽  
Metal Organic

A series of MOFs constructed from 5-((carboxymethyl)amino)isophthalic acid (H3cmai) have been prepared and characterised, with [Cd3(cmai)2(H2O)4]·4H2O demonstrating loss of water in a single-crystal-to-single-crystal transformation.

Syntheses, topological structures and properties of six metal–organic frameworks constructed from a flexible tetracarboxylate ligand

CrystEngComm ◽  
2015 ◽  
Vol 17 (16) ◽  
pp. 3162-3170 ◽  
Author(s):  
Yu Peng ◽  
Guanghua Li ◽  
Jia Hua ◽  
Zhan Shi ◽  
Shouhua Feng
Keyword(s):  
Metal Organic Frameworks ◽  
Topological Structures ◽  
Structures And Properties ◽  
Metal Organic ◽  
Solvothermal Conditions

Six new metal–organic frameworks (MOFs), Co2O(odip)(py)2(DMSO)2·3H2O (1), Co2(odip)(H2O)(DMA)2·2DMA (2), Co4(odip)2(H2O)4(DMSO)2·5DMSO (3), [Zn2(odip)(DMF)2(H2O)]·2DMF·2H2O (4), Zn2(odip)(H2O) (5) and In(odip)·3ACN (6), have been synthesized from the 5,5′-oxydiisophthalic acid (H4odip) ligand under solvothermal conditions.

scholarly journals Two Lanthanide Metal–Organic Frameworks Based on Semi-Rigid T-Shaped Tricarboxylate Ligand: Syntheses, Structures, and Properties

Polymers ◽  
2019 ◽  
Vol 11 (5) ◽  
pp. 868
Author(s):  
Yun-Shan Xue ◽  
Zhuo-Lin Chen ◽  
Youzhen Dong ◽  
Wei-Wei Cheng
Keyword(s):  
Near Infrared ◽  
Metal Organic Frameworks ◽  
Infrared Emission ◽  
Tripodal Ligand ◽  
Structures And Properties ◽  
3D Network ◽  
Metal Organic ◽  
Lanthanide Metal ◽  
Near Infrared Emission ◽  
Solvothermal Conditions

By using a semi-rigid tripodal ligand 5-(4-carboxybenzyloxy)isophthalic acid (H3L) and lanthanide metal ions (Nd3+, Tb3+), two novel lanthanide metal–organic frameworks, namely, {[Nd2L2(DMF)4] DMF}n (1), and {TbL(DMF)(H2O)}n (2), were synthesized under mild solvothermal conditions and structurally characterized by X-ray single crystal diffraction. Compounds 1 and 2 are isostructural, in which L3– ligands linked dinuclear lanthanide metal–carboxylate units to form non-interpenetrated 3D network with (3,6)-connected topology. Luminescent investigations reveal that compound 1 displays the near-infrared emission at room temperature, and compound 2 can be employed as selective probe for Cr2O72− anion in aqueous solution based on luminescence quenching. Moreover, compound 2 exhibits catalytic activity for cyclo-addition of CO2 and epoxides under relatively mild conditions.

Li-based MOF-derived multifunctional PEO polymer solid-state electrolyte for lithium energy storage

2022 ◽  
Author(s):  
Xiang Han ◽  
Tiantian Wu ◽  
Lanhui Gu ◽  
Dian Tian
Keyword(s):  
Energy Storage ◽  
Solid State ◽  
Metal Organic Framework ◽  
Three Dimensional ◽  
Isophthalic Acid ◽  
Solid State Electrolyte ◽  
Metal Organic ◽  
Solvothermal Conditions ◽  
Organic Framework

A three-dimensional (3D) metal-organic framework containing Li-oxygen clusters, namely {[Li2(IPA)]·DMF}n (1) (H2IPA = isophthalic acid), has been constructed under solvothermal conditions. The Li-based MOF can be applied to lithium energy...

Metal–Organic Frameworks with Pyridyl-Based Isophthalic Acid and Their Catalytic Applications in Microwave Assisted Peroxidative Oxidation of Alcohols and Henry Reaction

2016 ◽  
Vol 16 (4) ◽  
pp. 1837-1849 ◽  
Author(s):  
Anirban Karmakar ◽  
Luísa M. D. R. S. Martins ◽  
Susanta Hazra ◽  
M. Fátima C. Guedes da Silva ◽  
Armando J. L. Pombeiro
Keyword(s):  
Metal Organic Frameworks ◽  
Isophthalic Acid ◽  
Henry Reaction ◽  
Microwave Assisted ◽  
Oxidation Of Alcohols ◽  
Metal Organic ◽  
Catalytic Applications

Elucidation of the Formation Mechanism of Metal–Organic Frameworks via in-Situ Raman and FTIR Spectroscopy under Solvothermal Conditions

2018 ◽  
Vol 122 (23) ◽  
pp. 12267-12278 ◽  
Author(s):  
Heidemarie Embrechts ◽  
Martin Kriesten ◽  
Kilian Hoffmann ◽  
Wolfgang Peukert ◽  
Martin Hartmann ◽  
...  
Keyword(s):  
Ftir Spectroscopy ◽  
Formation Mechanism ◽  
Metal Organic Frameworks ◽  
In Situ Raman ◽  
Metal Organic ◽  
Solvothermal Conditions
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