scholarly journals The construction of a two-dimensional supramolecular organic framework with parallelogram pores and stepwise fluorescence enhancement

2015 ◽  
Vol 51 (91) ◽  
pp. 16417-16420 ◽  
Author(s):  
Shun-Qi Xu ◽  
Xiang Zhang ◽  
Cheng-Bin Nie ◽  
Zhong-Fu Pang ◽  
Xiao-Na Xu ◽  
...  

A novel single-layer two-dimensional (2D) supramolecular organic framework (SOF) with parallelogram pores has been assembled and a stepwise fluorescence emission enhancement was observed.

2016 ◽  
Vol 52 (48) ◽  
pp. 7588-7591 ◽  
Author(s):  
Ying Zhang ◽  
Tian-Guang Zhan ◽  
Tian-You Zhou ◽  
Qiao-Yan Qi ◽  
Xiao-Na Xu ◽  
...  

A novel two-dimensional (2D) supramolecular organic framework (SOF) has been assembled, which was further used as a fluorescent chemosensor to detect picric acid with high selectivity and sensitivity.


The Analyst ◽  
2019 ◽  
Vol 144 (10) ◽  
pp. 3357-3363 ◽  
Author(s):  
Marina A. Dominguez ◽  
Matías Insausti ◽  
Romina Ilari ◽  
Graciela P. Zanini

Fluorescence emission enhancement by adsorption as a promising tool for the development of future green sensors.


2013 ◽  
Vol 135 (47) ◽  
pp. 17913-17918 ◽  
Author(s):  
Kang-Da Zhang ◽  
Jia Tian ◽  
David Hanifi ◽  
Yuebiao Zhang ◽  
Andrew Chi-Hau Sue ◽  
...  

2014 ◽  
Vol 5 (16) ◽  
pp. 4715-4721 ◽  
Author(s):  
Liang Zhang ◽  
Tian-You Zhou ◽  
Jia Tian ◽  
Hui Wang ◽  
Dan-Wei Zhang ◽  
...  

Without or with the assistance of CB[8], a triangular radical monomer can self-assemble into 2D supramolecular organic frameworks in water.


Research ◽  
2019 ◽  
Vol 2019 ◽  
pp. 1-8 ◽  
Author(s):  
Hongbo Xu ◽  
Lingxiao Liu ◽  
Fei Teng ◽  
Nan Lu

Traditional fluorescence enhancement based on a match of the maximum excitation or emission of fluorescence molecule with the spectra of the nanostructure can hardly enhance blue and red fluorescent molecules. Here, an enhanced method which is a new strategy based on the antireflective array has been developed to enhance the emission of blue and red fluorescent molecules. The fluorescence emission is enhanced by increasing the absorption at excitation wavelengths of the fluorescent molecules and reducing the fluorescent energy dissipation with an antireflective array. By introducing the antireflective arrays, the emission enhancement of blue and red fluorescent molecules is, respectively, up to 14 and 18 fold. It is a universal and effective strategy for enhancing fluorescence emission, which could be applied to enhance the intensity of organic LED and imaging.


2018 ◽  
Vol 3 (6) ◽  
pp. 598-605 ◽  
Author(s):  
Heyu Chen ◽  
Yuanzheng Li ◽  
Weizhen Liu ◽  
Haiyang Xu ◽  
Guochun Yang ◽  
...  

A high-temperature driven carrier transfer process of multilayer WS2 is proposed and demonstrated for significant fluorescence emission enhancement.


2020 ◽  
Vol 17 (6) ◽  
pp. 472-478
Author(s):  
Wei-tao Gong ◽  
Wei-dong Qu ◽  
Guiling Ning

Two pyridinium amide-based receptors L1 and L2 with a small difference of H-bond position of the amide have been synthesized and characterized. Interestingly, they exhibited a huge difference in sensing towards AcO- and H2PO4 -, respectively. Receptor L1 was found to be ‘naked-eye’ selective for AcO- anions, while receptor L2 showed clear fluorescence enhancement selective to H2PO4 - anion. The recognition ability has been established by fluorescence emission, UV-vis spectra, and 1HNMR titration.


2008 ◽  
Vol 73 (1) ◽  
pp. 24-31
Author(s):  
Dayu Wu ◽  
Genhua Wu ◽  
Wei Huang ◽  
Zhuqing Wang

The compound [Cd(4,4'-bpy)2(H2O)2](ClO4)2·(L)2 was obtained by the reaction of Cd(ClO4)2, bis(1-pyrazinylethylidene)hydrazine (L) and 4,4'-bipyridine in aqueous MeOH. Single-crystal X-ray diffraction has revealed its two-dimensional metal-organic framework. The 2-D layers superpose on each other, giving a channel structure. The square planar grids consist of two pairs of shared edges with Cd(II) ion and a 4,4'-bipyridine molecule each vertex and side, respectively. The square cavity has a dimension of 11.817 × 11.781 Å. Two guest molecules of bis(1-pyrazinylethylidene)hydrazine are clathrated in every hydrophobic host cavity, being further stabilized by π-π stacking and hydrogen bonding. The results suggest that the hydrazine molecules present in the network serve as structure-directing templates in the formation of crystal structures.


2017 ◽  
Vol 139 (24) ◽  
pp. 8312-8319 ◽  
Author(s):  
Ming Xu ◽  
Shuai Yuan ◽  
Xin-Yu Chen ◽  
Yu-Jie Chang ◽  
Gregory Day ◽  
...  

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Kiyoshi Masuyama ◽  
Tomoaki Higo ◽  
Jong-Kook Lee ◽  
Ryohei Matsuura ◽  
Ian Jones ◽  
...  

AbstractIn contrast to hypertrophic cardiomyopathy, there has been reported no specific pattern of cardiomyocyte array in dilated cardiomyopathy (DCM), partially because lack of alignment assessment in a three-dimensional (3D) manner. Here we have established a novel method to evaluate cardiomyocyte alignment in 3D using intravital heart imaging and demonstrated homogeneous alignment in DCM mice. Whilst cardiomyocytes of control mice changed their alignment by every layer in 3D and position twistedly even in a single layer, termed myocyte twist, cardiomyocytes of DCM mice aligned homogeneously both in two-dimensional (2D) and in 3D and lost myocyte twist. Manipulation of cultured cardiomyocyte toward homogeneously aligned increased their contractility, suggesting that homogeneous alignment in DCM mice is due to a sort of alignment remodelling as a way to compensate cardiac dysfunction. Our findings provide the first intravital evidence of cardiomyocyte alignment and will bring new insights into understanding the mechanism of heart failure.


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