Toward a Single-Layer Two-Dimensional Honeycomb Supramolecular Organic Framework in Water

2013 ◽  
Vol 135 (47) ◽  
pp. 17913-17918 ◽  
Author(s):  
Kang-Da Zhang ◽  
Jia Tian ◽  
David Hanifi ◽  
Yuebiao Zhang ◽  
Andrew Chi-Hau Sue ◽  
...  
Keyword(s):  
Single Layer ◽  
Two Dimensional ◽  
Organic Framework

scholarly journals The construction of a two-dimensional supramolecular organic framework with parallelogram pores and stepwise fluorescence enhancement

2015 ◽  
Vol 51 (91) ◽  
pp. 16417-16420 ◽  
Author(s):  
Shun-Qi Xu ◽  
Xiang Zhang ◽  
Cheng-Bin Nie ◽  
Zhong-Fu Pang ◽  
Xiao-Na Xu ◽  
...  
Keyword(s):  
Fluorescence Enhancement ◽  
Fluorescence Emission ◽  
Single Layer ◽  
Two Dimensional ◽  
Emission Enhancement ◽  
Organic Framework

A novel single-layer two-dimensional (2D) supramolecular organic framework (SOF) with parallelogram pores has been assembled and a stepwise fluorescence emission enhancement was observed.

scholarly journals Fluorescence enhancement through the formation of a single-layer two-dimensional supramolecular organic framework and its application in highly selective recognition of picric acid

2016 ◽  
Vol 52 (48) ◽  
pp. 7588-7591 ◽  
Author(s):  
Ying Zhang ◽  
Tian-Guang Zhan ◽  
Tian-You Zhou ◽  
Qiao-Yan Qi ◽  
Xiao-Na Xu ◽  
...  
Keyword(s):  
High Selectivity ◽  
Fluorescence Enhancement ◽  
Picric Acid ◽  
Single Layer ◽  
Fluorescent Chemosensor ◽  
Selective Recognition ◽  
Two Dimensional ◽  
Organic Framework

A novel two-dimensional (2D) supramolecular organic framework (SOF) has been assembled, which was further used as a fluorescent chemosensor to detect picric acid with high selectivity and sensitivity.

A two-dimensional single-layer supramolecular organic framework that is driven by viologen radical cation dimerization and further promoted by cucurbit[8]uril

2014 ◽  
Vol 5 (16) ◽  
pp. 4715-4721 ◽  
Author(s):  
Liang Zhang ◽  
Tian-You Zhou ◽  
Jia Tian ◽  
Hui Wang ◽  
Dan-Wei Zhang ◽  
...  
Keyword(s):  
Radical Cation ◽  
Single Layer ◽  
Two Dimensional ◽  
Organic Framework

Without or with the assistance of CB[8], a triangular radical monomer can self-assemble into 2D supramolecular organic frameworks in water.

Synthesis and Structure of a Clathrated Two-Dimensional Metal-Organic Framework: [Cd(4,4'-bpy)2(H2O)2](ClO4)2·(L)2·H2O (L = Bis(1-pyrazinylethylidene)hydrazine)

2008 ◽  
Vol 73 (1) ◽  
pp. 24-31
Author(s):  
Dayu Wu ◽  
Genhua Wu ◽  
Wei Huang ◽  
Zhuqing Wang
Keyword(s):  
Metal Organic Framework ◽  
Channel Structure ◽  
Two Dimensional ◽  
X Ray Diffraction ◽  
Guest Molecules ◽  
X Ray ◽  
Square Planar ◽  
Metal Organic ◽  
Aqueous Meoh ◽  
Organic Framework

The compound [Cd(4,4'-bpy)2(H2O)2](ClO4)2·(L)2 was obtained by the reaction of Cd(ClO4)2, bis(1-pyrazinylethylidene)hydrazine (L) and 4,4'-bipyridine in aqueous MeOH. Single-crystal X-ray diffraction has revealed its two-dimensional metal-organic framework. The 2-D layers superpose on each other, giving a channel structure. The square planar grids consist of two pairs of shared edges with Cd(II) ion and a 4,4'-bipyridine molecule each vertex and side, respectively. The square cavity has a dimension of 11.817 × 11.781 Å. Two guest molecules of bis(1-pyrazinylethylidene)hydrazine are clathrated in every hydrophobic host cavity, being further stabilized by π-π stacking and hydrogen bonding. The results suggest that the hydrazine molecules present in the network serve as structure-directing templates in the formation of crystal structures.

Two-Dimensional Metal–Organic Framework Nanosheets as an Enzyme Inhibitor: Modulation of the α-Chymotrypsin Activity

2017 ◽  
Vol 139 (24) ◽  
pp. 8312-8319 ◽  
Author(s):  
Ming Xu ◽  
Shuai Yuan ◽  
Xin-Yu Chen ◽  
Yu-Jie Chang ◽  
Gregory Day ◽  
...  
Keyword(s):  
Enzyme Inhibitor ◽  
Metal Organic Framework ◽  
Two Dimensional ◽  
Chymotrypsin Activity ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Homogeneous 2D and 3D alignment of cardiomyocyte in dilated cardiomyopathy revealed by intravital heart imaging

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Kiyoshi Masuyama ◽  
Tomoaki Higo ◽  
Jong-Kook Lee ◽  
Ryohei Matsuura ◽  
Ian Jones ◽  
...  
Keyword(s):  
Heart Failure ◽  
Dilated Cardiomyopathy ◽  
Cardiac Dysfunction ◽  
Three Dimensional ◽  
Single Layer ◽  
Specific Pattern ◽  
Two Dimensional ◽  
Heart Imaging ◽  
Novel Method ◽  
2D And 3D

AbstractIn contrast to hypertrophic cardiomyopathy, there has been reported no specific pattern of cardiomyocyte array in dilated cardiomyopathy (DCM), partially because lack of alignment assessment in a three-dimensional (3D) manner. Here we have established a novel method to evaluate cardiomyocyte alignment in 3D using intravital heart imaging and demonstrated homogeneous alignment in DCM mice. Whilst cardiomyocytes of control mice changed their alignment by every layer in 3D and position twistedly even in a single layer, termed myocyte twist, cardiomyocytes of DCM mice aligned homogeneously both in two-dimensional (2D) and in 3D and lost myocyte twist. Manipulation of cultured cardiomyocyte toward homogeneously aligned increased their contractility, suggesting that homogeneous alignment in DCM mice is due to a sort of alignment remodelling as a way to compensate cardiac dysfunction. Our findings provide the first intravital evidence of cardiomyocyte alignment and will bring new insights into understanding the mechanism of heart failure.

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