A new designed hydrazine group-containing ruthenium complex used for catalytic hydrogenation of esters

2015 ◽  
Vol 51 (61) ◽  
pp. 12193-12196 ◽  
Author(s):  
Xuefeng Tan ◽  
Qingli Wang ◽  
Yuanhua Liu ◽  
Fangyuan Wang ◽  
Hui Lv ◽  
...  
Keyword(s):  
Catalytic Hydrogenation ◽  
Ruthenium Complex ◽  
Ruthenium Complexes ◽  
Excellent Performance

Hydrazine group-containing nitrogen–phosphine ruthenium complexes were synthesized and used for hydrogenation of esters, and excellent performance was observed (TON up to 17 200).

A selenium-containing ruthenium complex as a cancer radiosensitizer, rational design and the important role of ROS-mediated signalling

2015 ◽  
Vol 51 (13) ◽  
pp. 2637-2640 ◽  
Author(s):  
Zhiqin Deng ◽  
Lianling Yu ◽  
Wenqiang Cao ◽  
Wenjie Zheng ◽  
Tianfeng Chen
Keyword(s):  
Rational Design ◽  
Ruthenium Complex ◽  
Ruthenium Complexes

We have described the rational design of selenium-containing ruthenium complexes and their use as cancer radiosensitizers through regulating ROS-mediated pathways.

Recent Progress in Polynuclear Ruthenium Complex-Based DNA Binders/Structural Probes and Anticancer Agents

2020 ◽  
Vol 27 (22) ◽  
pp. 3735-3752 ◽  
Author(s):  
Si-Qi Zhang ◽  
Li-Hua Gao ◽  
Hua Zhao ◽  
Ke-Zhi Wang
Keyword(s):  
Anticancer Agents ◽  
Ruthenium Complex ◽  
Ruthenium Complexes ◽  
Anticancer Activities ◽  
Bridging Ligands ◽  
Metal Centers ◽  
Dna Binders ◽  
Structural Probes ◽  
Polynuclear Ruthenium Complexes

Ruthenium complexes have stood out by several mononuclear complexes which have entered into clinical trials, such as imidazolium [trans-RuCl4(1H-imidazole)(DMSO-S)] (NAMI-A) and ([Ru(II)(4,4'-dimethyl-2,2'-bipyridine)2-(2(2'-,2'':5'',2'''-terthiophene)-imidazo[4,5-f] [1,10]phenanthroline)] 2+) (TLD-1433), opening a new avenue for developing promising ruthenium-based anticancer drugs alternative to Cisplatin. Polynuclear ruthenium complexes were reported to exhibit synergistic and/or complementary effects: the enhanced DNA structural recognition and DNA binding as well as in vitro anticancer activities. This review overviews some representative polynuclear ruthenium complexes acting as DNA structural probes, DNA binders and in vitro anticancer agents, which were developed during last decades. These complexes are reviewed according to two main categories of homo-polynuclear and hetero-polynuclear complexes, each of which is further clarified into the metal centers linked by rigid and flexible bridging ligands. The perspective, challenges and future efforts for investigations into these exciting complexes are pointed out or suggested.

Catalytic hydrogenation of all-trans-retinal to all-trans-retinol with ruthenium complexes

1991 ◽  
Vol 66 (2) ◽  
pp. L27-L31 ◽  
Author(s):  
G. Allmang ◽  
F. Grass ◽  
J.M. Grosselin ◽  
C. Mercier
Keyword(s):  
Catalytic Hydrogenation ◽  
Ruthenium Complexes

Mononuclear ruthenium complexes containing two different phosphines in trans position: II. Catalytic hydrogenation of CC and CO bonds

2007 ◽  
Vol 692 (7) ◽  
pp. 1442-1450 ◽  
Author(s):  
Luca Salvi ◽  
Antonella Salvini ◽  
Francesca Micoli ◽  
Claudio Bianchini ◽  
Werner Oberhauser
Keyword(s):  
Catalytic Hydrogenation ◽  
Ruthenium Complexes ◽  
Trans Position ◽  
In Trans

Functionalization and cancer-targeting design of ruthenium complexes for precise cancer therapy

2019 ◽  
Vol 55 (67) ◽  
pp. 9904-9914 ◽  
Author(s):  
Jinggong Liu ◽  
Haoqiang Lai ◽  
Zushuang Xiong ◽  
Bolai Chen ◽  
Tianfeng Chen
Keyword(s):  
Targeted Therapy ◽  
Cancer Therapy ◽  
Photothermal Therapy ◽  
Ruthenium Complex ◽  
Ruthenium Complexes ◽  
Cancer Targeting ◽  
Bio Imaging

Herein, the functionalized Ruthenium complex applied for bio-imaging, photodynamic/photothermal therapy, precise targeted therapy and theranostics application have been discussed.

Catalytic Hydrogenation of CO2 by Unsymmetric N−Heterocyclic Carbene−Nitrogen−Phosphine Ruthenium Complexes

2021 ◽  
Author(s):  
Li Ji ◽  
TIanhua Cui ◽  
Xufeng Nie ◽  
Yanling Zheng ◽  
Xueli Zheng ◽  
...  
Keyword(s):  
High Activity ◽  
Catalytic Hydrogenation ◽  
Ruthenium Complexes ◽  
Hydrogenation Of Co2 ◽  
First Time ◽  
Excellent Stability

Unsymmetric Ru-CNP and Ru-CN(H)P complexes are synthesized and applied in hydrogenation of CO2 to formate for the first time. Ru-CNP complex shows excellent stability and high activity. The TON is...

Catalytic hydrogenation of carbonyl and nitro compounds using an [N,O]-chelate half-sandwich ruthenium catalyst

2019 ◽  
Vol 48 (21) ◽  
pp. 7158-7166 ◽  
Author(s):  
Zi-Jian Yao ◽  
Jing-Wei Zhu ◽  
Nan Lin ◽  
Xin-Chao Qiao ◽  
Wei Deng
Keyword(s):  
Aqueous Solution ◽  
High Activity ◽  
Catalytic Hydrogenation ◽  
Ruthenium Complexes ◽  
Nitro Compounds ◽  
Ruthenium Catalyst ◽  
Half Sandwich

A series of N,O-chelate half-sandwich ruthenium complexes have been synthesized, which exhibited high activity for the catalytic hydrogenation of carbonyl and nitro compounds in aqueous solution.

Assembly of ruthenium complexes on double stranded DNA using mismatch binding ligands

2020 ◽  
Vol 56 (39) ◽  
pp. 5227-5230
Author(s):  
Lu Ni ◽  
Takeshi Yamada ◽  
Kazuhiko Nakatani
Keyword(s):  
Ruthenium Complex ◽  
Ruthenium Complexes ◽  
Double Stranded Dna

A new molecule containing an NCD moiety and a ruthenium complex was prepared, allowing the assembly of adjoining ruthenium complexes on single dsDNA.

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