scholarly journals A one-step, modular route to optically-active diphos ligands

2015 ◽  
Vol 51 (50) ◽  
pp. 10206-10209 ◽  
Author(s):  
E. Louise Hazeland ◽  
Andy M. Chapman ◽  
Paul G. Pringle ◽  
Hazel A. Sparkes

A chlorosilane elimination reaction has been developed that allows the efficient synthesis of optically pure C1-symmetric, C1-backboned diphosphines with a wide variety of stereoelectronic characteristics.

1987 ◽  
Vol 28 (50) ◽  
pp. 6351-6354 ◽  
Author(s):  
Yasunori Kitano ◽  
Takashi Matsumoto ◽  
Takenori Wakasa ◽  
Sentaro Okamoto ◽  
Toshiyuki Shimazaki ◽  
...  

ChemInform ◽  
2005 ◽  
Vol 36 (8) ◽  
Author(s):  
J. S. Yadav ◽  
B. V. S. Reddy ◽  
G. Satheesh ◽  
P. Naga Lakshmi ◽  
S. Kiran Kumar ◽  
...  

2011 ◽  
Vol 7 ◽  
pp. 1334-1341 ◽  
Author(s):  
Sanny Verma ◽  
Suman L Jain ◽  
Bir Sain

PEG-embedded potassium tribromide ([K+PEG]Br3 −) was found to be an efficient and recyclable catalyst for the synthesis of functionalized piperidines in high yields in a one step, three component coupling between aldehyde, amine and β-keto ester. At the end of the reaction the [K+PEG]Br3 − was readily regenerated from the reaction mixture by treating the residue containing [K+PEG]Br− with molecular bromine.


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