A catalytic asymmetric carbonyl–ene reaction of β,γ-unsaturated α-ketoesters with 5-methyleneoxazolines

Weiwei Luo; Jiannan Zhao; Jie Ji; Lili Lin; Xiaohua Liu; Hongjiang Mei; Xiaoming Feng

doi:10.1039/c5cc02748a

A catalytic asymmetric carbonyl–ene reaction of β,γ-unsaturated α-ketoesters with 5-methyleneoxazolines

Chemical Communications ◽

10.1039/c5cc02748a ◽

2015 ◽

Vol 51 (49) ◽

pp. 10042-10045 ◽

Cited By ~ 26

Author(s):

Weiwei Luo ◽

Jiannan Zhao ◽

Jie Ji ◽

Lili Lin ◽

Xiaohua Liu ◽

...

Keyword(s):

Ene Reaction ◽

Catalytic Asymmetric

A catalytic asymmetric carbonyl–ene reaction of β,γ-unsaturated α-ketoesters with 5-methyleneoxazolines was accomplished. The process was based on the utilization of a chiral N,N′-dioxide/MgII catalyst, providing the desired products with excellent outcomes.

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Catalytic Asymmetric Hetero-ene Reaction for Direct Customizable Allylic Functionalization

Chem ◽

10.1016/j.chempr.2017.07.013 ◽

2017 ◽

Vol 3 (2) ◽

pp. 204-206 ◽

Cited By ~ 2

Author(s):

Luc Neuville ◽

Philippe Dauban

Keyword(s):

Ene Reaction ◽

Catalytic Asymmetric

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ChemInform Abstract: Catalytic Asymmetric Glyoxylate-Ene Reaction: A Practical Access to α-Hydroxy Esters in High Enantiomeric Purities.

ChemInform ◽

10.1002/chin.199035068 ◽

1990 ◽

Vol 21 (35) ◽

Author(s):

K. MIKAMI ◽

M. TERADA ◽

T. NAKAI

Keyword(s):

Ene Reaction ◽

Hydroxy Esters ◽

Catalytic Asymmetric

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ChemInform Abstract: Catalytic Asymmetric Synthesis of Substituted Benzocycloalkenes via the Glyoxylate Ene Reaction.

ChemInform ◽

10.1002/chin.199312060 ◽

2010 ◽

Vol 24 (12) ◽

pp. no-no

Author(s):

F. T. VAN DER MEER ◽

B. L. FERINGA

Keyword(s):

Asymmetric Synthesis ◽

Ene Reaction ◽

Catalytic Asymmetric Synthesis ◽

Catalytic Asymmetric

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La/Ag Heterobimetallic Cooperative Catalysis: A Catalytic Asymmetric Conia-Ene Reaction

Angewandte Chemie International Edition ◽

10.1002/anie.201102114 ◽

2011 ◽

Vol 50 (33) ◽

pp. 7616-7619 ◽

Cited By ~ 70

Author(s):

Akinobu Matsuzawa ◽

Tomoyuki Mashiko ◽

Naoya Kumagai ◽

Masakatsu Shibasaki

Keyword(s):

Ene Reaction ◽

Cooperative Catalysis ◽

Catalytic Asymmetric

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Catalytic asymmetric glyoxylate-ene reaction: a practical access to .alpha.-hydroxy esters in high enantiomeric purities

Journal of the American Chemical Society ◽

10.1021/ja00166a035 ◽

1990 ◽

Vol 112 (10) ◽

pp. 3949-3954 ◽

Cited By ~ 252

Author(s):

Koichi Mikami ◽

Masahiro Terada ◽

Takeshi Nakai

Keyword(s):

Ene Reaction ◽

Hydroxy Esters ◽

Catalytic Asymmetric

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ChemInform Abstract: La/Ag Heterobimetallic Cooperative Catalysis: A Catalytic Asymmetric Conia-Ene Reaction.

ChemInform ◽

10.1002/chin.201201044 ◽

2011 ◽

Vol 43 (1) ◽

pp. no-no

Author(s):

Akinobu Matsuzawa ◽

Tomoyuki Mashiko ◽

Naoya Kumagai ◽

Masakatsu Shibasaki

Keyword(s):

Ene Reaction ◽

Cooperative Catalysis ◽

Catalytic Asymmetric

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Catalytic Asymmetric Aza-ene Reaction of 3-Indolylmethanols with Cyclic Enaminones: Enantioselective Approach to C3-Functionalized Indoles

The Journal of Organic Chemistry ◽

10.1021/jo500644v ◽

2014 ◽

Vol 79 (10) ◽

pp. 4635-4643 ◽

Cited By ~ 65

Author(s):

Wei Tan ◽

Bai-Xiang Du ◽

Xin Li ◽

Xu Zhu ◽

Feng Shi ◽

...

Keyword(s):

Ene Reaction ◽

Catalytic Asymmetric ◽

Cyclic Enaminones

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ChemInform Abstract: A Catalytic Asymmetric Carbonyl-Ene Reaction of β,γ-Unsaturated α-Ketoesters with 5-Methyleneoxazolines.

ChemInform ◽

10.1002/chin.201542029 ◽

2015 ◽

Vol 46 (42) ◽

pp. no-no

Author(s):

Weiwei Luo ◽

Jiannan Zhao ◽

Jie Ji ◽

Lili Lin ◽

Xiaohua Liu ◽

...

Keyword(s):

Ene Reaction ◽

Catalytic Asymmetric

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Catalytic asymmetric synthesis of substituted benzocyclo-alkenes via the glyoxylate ene reaction

Tetrahedron Letters ◽

10.1016/s0040-4039(00)61022-5 ◽

1992 ◽

Vol 33 (44) ◽

pp. 6695-6696 ◽

Cited By ~ 8

Author(s):

Froukje T. van der Meer ◽

Ben L. Feringa

Keyword(s):

Asymmetric Synthesis ◽

Ene Reaction ◽

Catalytic Asymmetric Synthesis ◽

Catalytic Asymmetric

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ChemInform Abstract: Catalytic Asymmetric Aza-ene Reaction of 3-Indolylmethanols with Cyclic Enaminones: Enantioselective Approach to C3-Functionalized Indoles.

ChemInform ◽

10.1002/chin.201445115 ◽

2014 ◽

Vol 45 (45) ◽

pp. no-no

Author(s):

Wei Tan ◽

Bai-Xiang Du ◽

Xin Li ◽

Xu Zhu ◽

Feng Shi ◽

...

Keyword(s):

Ene Reaction ◽

Catalytic Asymmetric ◽

Cyclic Enaminones

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