Catalytic Asymmetric Aza-ene Reaction of 3-Indolylmethanols with Cyclic Enaminones: Enantioselective Approach to C3-Functionalized Indoles

2014 ◽  
Vol 79 (10) ◽  
pp. 4635-4643 ◽  
Author(s):  
Wei Tan ◽  
Bai-Xiang Du ◽  
Xin Li ◽  
Xu Zhu ◽  
Feng Shi ◽  
...  
Keyword(s):  
Ene Reaction ◽  
Catalytic Asymmetric ◽  
Cyclic Enaminones

A catalytic asymmetric carbonyl–ene reaction of β,γ-unsaturated α-ketoesters with 5-methyleneoxazolines

2015 ◽  
Vol 51 (49) ◽  
pp. 10042-10045 ◽  
Author(s):  
Weiwei Luo ◽  
Jiannan Zhao ◽  
Jie Ji ◽  
Lili Lin ◽  
Xiaohua Liu ◽  
...  
Keyword(s):  
Ene Reaction ◽  
Catalytic Asymmetric

A catalytic asymmetric carbonyl–ene reaction of β,γ-unsaturated α-ketoesters with 5-methyleneoxazolines was accomplished. The process was based on the utilization of a chiral N,N′-dioxide/MgII catalyst, providing the desired products with excellent outcomes.

scholarly journals Catalytic Asymmetric Hetero-ene Reaction for Direct Customizable Allylic Functionalization

Chem ◽  
2017 ◽  
Vol 3 (2) ◽  
pp. 204-206 ◽  
Author(s):  
Luc Neuville ◽  
Philippe Dauban
Keyword(s):  
Ene Reaction ◽  
Catalytic Asymmetric

La/Ag Heterobimetallic Cooperative Catalysis: A Catalytic Asymmetric Conia-Ene Reaction

2011 ◽  
Vol 50 (33) ◽  
pp. 7616-7619 ◽  
Author(s):  
Akinobu Matsuzawa ◽  
Tomoyuki Mashiko ◽  
Naoya Kumagai ◽  
Masakatsu Shibasaki
Keyword(s):  
Ene Reaction ◽  
Cooperative Catalysis ◽  
Catalytic Asymmetric

ChemInform Abstract: La/Ag Heterobimetallic Cooperative Catalysis: A Catalytic Asymmetric Conia-Ene Reaction.

ChemInform ◽  
2011 ◽  
Vol 43 (1) ◽  
pp. no-no
Author(s):  
Akinobu Matsuzawa ◽  
Tomoyuki Mashiko ◽  
Naoya Kumagai ◽  
Masakatsu Shibasaki
Keyword(s):  
Ene Reaction ◽  
Cooperative Catalysis ◽  
Catalytic Asymmetric

Cyclic enaminones. Part I: stereocontrolled synthesis using diastereoselective and catalytic asymmetric methods

2015 ◽  
Vol 51 (92) ◽  
pp. 16437-16449 ◽  
Author(s):  
Amit Kumar Chattopadhyay ◽  
Stephen Hanessian
Keyword(s):  
Stereocontrolled Synthesis ◽  
Catalytic Asymmetric ◽  
Cyclic Enaminones ◽  
Stereoselective Syntheses

Here, we summarize three approaches for stereoselective syntheses of cyclic enaminones and their functionalized derivatives. These include chiral substrates (chirons) as starting materials, syntheses employing non-catalytic (stoichiometric) reagents, and catalytic asymmetric methods.

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