A two-in-one dual channel chemosensor for Fe3+and Cu2+with nanomolar detection mimicking the IMPLICATION logic gate

2015 ◽  
Vol 3 (2) ◽  
pp. 453-460 ◽  
Author(s):  
Anil Kuwar ◽  
Rahul Patil ◽  
Amanpreet Singh ◽  
Suban K. Sahoo ◽  
Jaromir Marek ◽  
...  

A highly selective colorimetric as well as fluorescence sensor for Fe(iii) and Cu(iii) in 99% aqueous medium.

2021 ◽  
Author(s):  
Jeyaraj Belinda Asha ◽  
Murugan Karthik ◽  
Palaniswamy Suresh

A novel covalently modified graphene oxide has been synthesised and demonstrated as a carbonaceous chemosensor for the selective detection of Ru(iii) in complete water medium.


Author(s):  
Divya Singhal ◽  
Neha Gupta ◽  
Ashok Kumar Singh

4-(thiazol-2-yldiazenyl)phenol (L1) and 2-((4-hydroxyphenyl) diazenyl)-5-nitrophenol (L2) based on azo phenol were synthesised and used as selective colorimetric sensor for CN- and AcO− ion in DMSO/H2O-HEPES (v/v; 1:1, pH–7.3 ± 0.2) and showed good sensitivity with large red shifts and nanomolar detection limit for CN- and AcO- ion. The stoichiometry of L1 with CN−/AcO− ion was found to be 1:1 and L2 with CN−/AcO− ion was found to be 1:2. Binding constant for L1+ CN−, L1 + AcO−, L2 + CN− and L2 + AcO− were calculated by B-H plot as 1.6 × 103, 8.0 × 102, 8.4 × 103 and 1.7 × 102 respectively. L2 showed high selectivity towards CN− ion with low detection limit of 81 nM and large binding constant. In addition, 1H NMR titration and DFT studies also supported the deprotonation mechanism of receptors in the presence of selective anions.


ACS Omega ◽  
2020 ◽  
Vol 5 (31) ◽  
pp. 19896-19904
Author(s):  
Sanay Naha ◽  
Natesan Thirumalaivasan ◽  
Somenath Garai ◽  
Shu-Pao Wu ◽  
Sivan Velmathi

2018 ◽  
Vol 47 (4) ◽  
pp. 1082-1091 ◽  
Author(s):  
Suparna Paul ◽  
Pritam Ghosh ◽  
Samuzal Bhuyan ◽  
Subhra Kanti Mukhopadhyay ◽  
Priyabrata Banerjee

A novel chromogenic and fluorogenic chemoreceptor exhibiting a proclivity towards Cu2+and CN−, with applications in bioimaging and molecular electronics, was developed.


2004 ◽  
Vol 6 (14) ◽  
pp. 2353-2355 ◽  
Author(s):  
Jose-Maria Montenegro ◽  
Ezequiel Perez-Inestrosa ◽  
Daniel Collado ◽  
Yolanda Vida ◽  
Rafael Suau

2017 ◽  
Vol 9 (4) ◽  
pp. 1-6 ◽  
Author(s):  
Jiamin Wang ◽  
Ming Luo ◽  
Ying Qiu ◽  
Xiang Li ◽  
Jiaxin Gong ◽  
...  

Nanomaterials ◽  
2021 ◽  
Vol 12 (1) ◽  
pp. 128
Author(s):  
Lei Jia ◽  
Zhitao Xu ◽  
Rujie Chen ◽  
Xiangzhen Chen ◽  
Jun Xu

Tetracycline (TC) and oxytetracycline (OTC) are the most widely used broad-spectrum antimicrobial agents in tetracycline drugs, and their structures and properties are very similar, so it is a great challenge to distinguish and detect these two antibiotics with a single probe at the same time. Herein, a dual-channel fluorescence probe (SiCDs@mMIPs-cit-Eu) was developed by integrating two independent reaction sites with SiCDs-doped mesoporous silica molecular imprinting group and europium complex group into a nanomaterial. The synergistic influence of inner filter effect and “antenna effect” can be guaranteed to solve the distinction between TC and OTC. Moreover, this novel strategy can also sequentially detect TC and OTC in buffer solution and real samples with high sensitivity and selectivity. This method revealed good responses to TC and OTC ranging from 0 to 5.5 μM with a detection limit of 5 and 16 nM, respectively. Combined with the smartphone color-scanning application, the portable and cheap paper-based sensor was designed to realize the multi-color visual on-site detection of TC and OTC. In addition, the logic gate device was constructed according to the fluorescence color change of the probe for TC and OTC, which provided the application possibility for the intelligent detection of the probe.


RSC Advances ◽  
2020 ◽  
Vol 10 (38) ◽  
pp. 22691-22700
Author(s):  
Jayanti Mishra ◽  
Manpreet Kaur ◽  
Navneet Kaur ◽  
Ashok K. Ganguli

Two ligands 1 and 2 are synthesized and their organic nanoparticles (1-ONP and 2-ONP) are generated. 1-ONP has shown the chemosensing of Cs(i) (∼220 nm) and Al(iii) (∼377 nm) in aqueous medium while 2-ONP has not shown any chemosensing behaviour.


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