Melamine–terephthalaldehyde–lithium complex: a porous organic network based single ion electrolyte for lithium ion batteries

2015 ◽  
Vol 3 (9) ◽  
pp. 5132-5139 ◽  
Author(s):  
Rupesh Rohan ◽  
Kapil Pareek ◽  
Weiwei Cai ◽  
Yunfeng Zhang ◽  
Guodong Xu ◽  
...  

Melamine based porous organic frameworks as a single ion conducting electrolyte for lithium ion batteries.

2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Jaebin Nam ◽  
Eunsoo Kim ◽  
Rajeev K.K. ◽  
Yeonho Kim ◽  
Tae-Hyun Kim

Abstract A ureido-pyrimidinone (UPy)-functionalized poly(acrylic acid) grafted with poly(ethylene glycol)(PEG), designated PAU-g-PEG, was developed as a high performance polymer binder for Si anodes in lithium-ion batteries. By introducing both a ureido-pyrimidinone (UPy) unit, which is capable of self-healing through dynamic hydrogen bonding within molecules as well as with Si, and an ion-conducting PEG onto the side chain of the poly(acrylic acid), this water-based self-healable and conductive polymer binder can effectively accommodate the volume changes of Si, while maintaining electronic integrity, in an electrode during repeated charge/discharge cycles. The Si@PAU-g-PEG electrode retained a high capacity of 1,450.2 mAh g−1 and a Coulombic efficiency of 99.4% even after 350 cycles under a C-rate of 0.5 C. Under a high C-rate of 3 C, an outstanding capacity of 2,500 mAh g−1 was also achieved, thus demonstrating its potential for improving the electrochemical performance of Si anodes.


2019 ◽  
Vol 55 (47) ◽  
pp. 6715-6718 ◽  
Author(s):  
Meng Zhang ◽  
Songrui Yu ◽  
Yiyong Mai ◽  
Shaodong Zhang ◽  
Yongfeng Zhou

“Crown-PEG”-assisted Li+ migration in a hyperbranched single-ion polyelectrolyte.


2018 ◽  
Vol 44 (10) ◽  
pp. 6039-6051 ◽  
Author(s):  
Jae-Yeong Park ◽  
Jun-Woo Park ◽  
Chil-Hoon Doh ◽  
Yoon-Cheol Ha ◽  
Sang-Min Lee ◽  
...  

RSC Advances ◽  
2016 ◽  
Vol 6 (44) ◽  
pp. 38223-38227 ◽  
Author(s):  
Chih-Chia Cheng ◽  
Duu-Jong Lee

Supramolecular solid polymer electrolytes provide mechanical integrity and well-defined ion-conducting paths for rapid ion transport that can be applied in high-performance lithium-ion batteries.


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