In situ spectroscopy studies of CO2 adsorption in a dually functionalized microporous metal–organic framework

2015 ◽  
Vol 3 (9) ◽  
pp. 4945-4953 ◽  
Author(s):  
Yuan Chen ◽  
Hao Wang ◽  
Jing Li ◽  
Jenny V. Lockard
Keyword(s):  
Gas Adsorption ◽  
Molecular Level ◽  
Metal Organic Framework ◽  
Spectroscopic Characterization ◽  
Characterization Methods ◽  
Adsorption Processes ◽  
Metal Organic ◽  
Spectroscopy Studies ◽  
Organic Framework

The activation and CO2 gas adsorption processes in the rht-type metal-organic framework, [Cu3(TDPAT) (H2O)3]·10H2O·5DMA (TDPAT = 2,4,6-tris(3,5-dicarboxylphenylamino)-1,3,5-triazine) were investigated on the molecular level using several spectroscopic characterization methods.

3D-Printed Metal–Organic Framework Monoliths for Gas Adsorption Processes

2017 ◽  
Vol 9 (41) ◽  
pp. 35908-35916 ◽  
Author(s):  
Harshul Thakkar ◽  
Stephen Eastman ◽  
Qasim Al-Naddaf ◽  
Ali A. Rownaghi ◽  
Fateme Rezaei
Keyword(s):  
Gas Adsorption ◽  
Metal Organic Framework ◽  
Adsorption Processes ◽  
Metal Organic ◽  
3D Printed ◽  
Organic Framework

scholarly journals Dual-mode humidity detection using a lanthanide-based metal–organic framework: towards multifunctional humidity sensors

2017 ◽  
Vol 53 (32) ◽  
pp. 4465-4468 ◽  
Author(s):  
Yuan Gao ◽  
Pengtao Jing ◽  
Ning Yan ◽  
Michiel Hilbers ◽  
Hong Zhang ◽  
...  
Keyword(s):  
Impedance Spectroscopy ◽  
Humidity Sensor ◽  
Metal Organic Framework ◽  
Dual Mode ◽  
Humidity Sensors ◽  
Highly Effective ◽  
Metal Organic ◽  
Spectroscopy Studies ◽  
Organic Framework

Combined photoluminescence and impedance spectroscopy studies show that a europium-based metal–organic framework behaves as a highly effective and reliable humidity sensor, enabling dual-mode humidity detection.

scholarly journals Backbonding contributions to small molecule chemisorption in a metal–organic framework with open copper(i) centers

2021 ◽  
Author(s):  
Gregory M. Su ◽  
Han Wang ◽  
Brandon R. Barnett ◽  
Jeffrey R. Long ◽  
David Prendergast ◽  
...  
Keyword(s):  
Fine Structure ◽  
Small Molecule ◽  
Metal Organic Framework ◽  
X Ray ◽  
Metal Site ◽  
Absorption Fine ◽  
Metal Organic ◽  
X Ray Absorption ◽  
Organic Framework

In situ near edge X-ray absorption fine structure spectroscopy directly probes unoccupied states associated with backbonding interactions between the open metal site in a metal–organic framework and various small molecule guests.

An in situ investigation of the thermal decomposition of metal-organic framework NH2-MIL-125 (Ti)

2021 ◽  
Vol 316 ◽  
pp. 110957
Author(s):  
Mian Zahid Hussain ◽  
Mounib Bahri ◽  
Werner R. Heinz ◽  
Quanli Jia ◽  
Ovidiu Ersen ◽  
...  
Keyword(s):  
Thermal Decomposition ◽  
Metal Organic Framework ◽  
In Situ Investigation ◽  
Metal Organic ◽  
Organic Framework

Triple Framework Interpenetration and Immobilization of Open Metal Sites within a Microporous Mixed Metal–Organic Framework for Highly Selective Gas Adsorption

2012 ◽  
Vol 51 (9) ◽  
pp. 4947-4953 ◽  
Author(s):  
Zhangjing Zhang ◽  
Shengchang Xiang ◽  
Kunlun Hong ◽  
Madhab, C. Das ◽  
Hadi D. Arman ◽  
...  
Keyword(s):  
Gas Adsorption ◽  
Metal Organic Framework ◽  
Mixed Metal ◽  
Open Metal Sites ◽  
Metal Organic ◽  
Organic Framework
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