scholarly journals Combining In Situ Techniques (XRD, IR, and 13C NMR) and Gas Adsorption Measurements Reveals CO2-Induced Structural Transitions and High CO2/CH4 Selectivity for a Flexible Metal–Organic Framework JUK-8

2021 ◽  
Author(s):  
Kornel Roztocki ◽  
Marcus Rauche ◽  
Volodymyr Bon ◽  
Stefan Kaskel ◽  
Eike Brunner ◽  
...  
Keyword(s):  
13C Nmr ◽  
Gas Adsorption ◽  
Metal Organic Framework ◽  
Structural Transitions ◽  
High Co2 ◽  
In Situ Techniques ◽  
Metal Organic ◽  
Flexible Metal ◽  
Organic Framework

scholarly journals Exceptional adsorption-induced cluster and network deformation in the flexible metal–organic framework DUT-8(Ni) observed by in situ X-ray diffraction and EXAFS

2015 ◽  
Vol 17 (26) ◽  
pp. 17471-17479 ◽  
Author(s):  
Volodymyr Bon ◽  
Nicole Klein ◽  
Irena Senkovska ◽  
Andreas Heerwig ◽  
Jürgen Getzschmann ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
X Ray Diffraction ◽  
X Ray ◽  
Gate Opening ◽  
Metal Organic ◽  
Flexible Metal ◽  
Organic Framework

The “gate opening” mechanism in flexible MOF Ni2(2,6-ndc)2dabco was elucidated in detail.

scholarly journals Flexible metal-organic framework compounds: In situ studies for selective CO2 capture

2015 ◽  
Vol 647 ◽  
pp. 24-34 ◽  
Author(s):  
A.J. Allen ◽  
L. Espinal ◽  
W. Wong-Ng ◽  
W.L. Queen ◽  
C.M. Brown ◽  
...  
Keyword(s):  
Co2 Capture ◽  
Metal Organic Framework ◽  
In Situ Studies ◽  
Metal Organic ◽  
Flexible Metal ◽  
Framework Compounds ◽  
Organic Framework

Adsorption of N/S heterocycles in the flexible metal–organic framework MIL-53(FeIII) studied by in situ energy dispersive X-ray diffraction

2013 ◽  
Vol 15 (22) ◽  
pp. 8606 ◽  
Author(s):  
Ben Van de Voorde ◽  
Alexis S. Munn ◽  
Nathalie Guillou ◽  
Franck Millange ◽  
Dirk E. De Vos ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Energy Dispersive ◽  
X Ray Diffraction ◽  
X Ray ◽  
Metal Organic ◽  
Flexible Metal ◽  
Organic Framework

N-rich zeolite-like metal–organic framework with sodalite topology: high CO2 uptake, selective gas adsorption and efficient drug delivery

2012 ◽  
Vol 3 (6) ◽  
pp. 2114 ◽  
Author(s):  
Jun-Sheng Qin ◽  
Dong-Ying Du ◽  
Wen-Liang Li ◽  
Jing-Ping Zhang ◽  
Shun-Li Li ◽  
...  
Keyword(s):  
Drug Delivery ◽  
Gas Adsorption ◽  
Metal Organic Framework ◽  
Co2 Uptake ◽  
High Co2 ◽  
Metal Organic ◽  
Organic Framework

In situ spectroscopy studies of CO2 adsorption in a dually functionalized microporous metal–organic framework

2015 ◽  
Vol 3 (9) ◽  
pp. 4945-4953 ◽  
Author(s):  
Yuan Chen ◽  
Hao Wang ◽  
Jing Li ◽  
Jenny V. Lockard
Keyword(s):  
Gas Adsorption ◽  
Molecular Level ◽  
Metal Organic Framework ◽  
Spectroscopic Characterization ◽  
Characterization Methods ◽  
Adsorption Processes ◽  
Metal Organic ◽  
Spectroscopy Studies ◽  
Organic Framework

The activation and CO2 gas adsorption processes in the rht-type metal-organic framework, [Cu3(TDPAT) (H2O)3]·10H2O·5DMA (TDPAT = 2,4,6-tris(3,5-dicarboxylphenylamino)-1,3,5-triazine) were investigated on the molecular level using several spectroscopic characterization methods.

Direct in Situ Crystallographic Visualization of a Dual Mechanism for the Uptake of CO2 Gas by a Flexible Metal–Organic Framework

2019 ◽  
Vol 58 (13) ◽  
pp. 8257-8262 ◽  
Author(s):  
Phumile Sikiti ◽  
Charl X. Bezuidenhout ◽  
Dewald P. van Heerden ◽  
Leonard J. Barbour
Keyword(s):  
Metal Organic Framework ◽  
Co2 Gas ◽  
Metal Organic ◽  
Flexible Metal ◽  
Dual Mechanism ◽  
Organic Framework

Cobalt substitution in a flexible metal–organic framework: modulating a soft paddle-wheel unit for tunable gate-opening adsorption

2019 ◽  
Vol 48 (21) ◽  
pp. 7100-7104 ◽  
Author(s):  
Jiaxing Zhu ◽  
Junye Chen ◽  
Tianze Qiu ◽  
Mingli Deng ◽  
Qingshu Zheng ◽  
...  
Keyword(s):  
Gas Adsorption ◽  
Metal Organic Framework ◽  
Paddle Wheel ◽  
Gate Opening ◽  
Cobalt Substitution ◽  
Metal Organic ◽  
Flexible Framework ◽  
Coordination Bonds ◽  
Flexible Metal ◽  
Organic Framework

We achieved a tunable Pgo for gas adsorption in a flexible framework by modulating the dynamic rearrangement of coordination bonds of paddle-wheel unit via cobalt substitution.

In situ Fe XAFS of reversible lithium insertion in a flexible metal organic framework material

2009 ◽  
Vol 11 (10) ◽  
pp. 1881-1884 ◽  
Author(s):  
Guillaume de Combarieu ◽  
Stéphane Hamelet ◽  
Franck Millange ◽  
Mathieu Morcrette ◽  
Jean-Marie Tarascon ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Lithium Insertion ◽  
Metal Organic ◽  
Flexible Metal ◽  
Organic Framework
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