Enhancement of photocatalytic performance via a P3HT-g-C3N4 heterojunction

2015 ◽  
Vol 3 (6) ◽  
pp. 2741-2747 ◽  
Author(s):  
Xiaojuan Bai ◽  
Changpo Sun ◽  
Songling Wu ◽  
Yongfa Zhu

Schematic illustration of charge separation and photocatalytic processes over g-C3N4 and P3HT-g-C3N4 photocatalysts under visible light irradiation.

Author(s):  
M. B. Tahir ◽  
T. Iqbal ◽  
I. Zeba ◽  
A. Hasan ◽  
Shabbir Muhammad ◽  
...  

Abstract The green energy production through water splitting under visible light irradiation has become an emerging challenge in the 21st century. Photocatalysis, being a cost-competitive and efficient technique, has grabbed much more attention for environmental applications, especially for hydrogen evolution. In this article, the hybrid Cu3V2O8-WO3 nanostructures were prepared through the hydrothermal method by using copper acetate, ammonium metavanadate, and Na2WO4 · 2H2O as precursors. The varying contents of Cu3V2O8 in WO3 were 0.2%, 0.5%, 1.0%, 2.0%, and 3.0%. The X-ray diffraction (XRD), scanning electron microscopy (SEM), Brunauer–Emmett–Teller (BET), UV-Vis, and photoluminescence (PL) emission spectroscopy were used to investigate the structural, morphological, surface area, and optical properties of prepared samples. The average crystalline size of the pure WO3 ranges from 10 to 15 nm and 70 to 195 nm for an optimal composite sample. The structural phase of the hybrid WO3-Cu3V2O8 nanoparticles was found to transfer from monoclinic to hexagonal by incorporating the Cu3V2O8 contents. The enhanced photocatalytic performance for hydrogen evolution was observed for 2% Cu3V2O8-WO3 composite sample. The key to this enhancement lies at the heterojunction interface, where charge separation occurs. In addition, the excellent photocatalytic activity was attributed to a higher surface area, efficient charge separation, and extended visible light absorption. This work provides an in-depth understanding of efficient separation of charge carriers and transfer processes and steer charge flow for efficient solar-to-chemical energy applications.


2021 ◽  
Vol 50 (9) ◽  
pp. 3253-3260 ◽  
Author(s):  
Shan Zhao ◽  
Junbiao Wu ◽  
Yan Xu ◽  
Xia Zhang ◽  
Yide Han ◽  
...  

CdS/Ag2S/g-C3N4 ternary composites showed excellent photocatalytic performance toward H2 evolution. Their improved photocatalytic activity could be attributed not only to the synergic effect, but also to the introduction of Ag2S.


2020 ◽  
Vol 10 (6) ◽  
pp. 1609-1618 ◽  
Author(s):  
Chao Zhang ◽  
Jiandong Liu ◽  
Xingliang Liu ◽  
Shiai Xu

Reaction mechanism for the higher photocatalytic performance of H2 production of g-C3N4NSs/TC1 under visible light irradiation (λ ≥ 400 nm).


2017 ◽  
Vol 4 (10) ◽  
pp. 1691-1696 ◽  
Author(s):  
Mumei Han ◽  
Huibo Wang ◽  
Siqi Zhao ◽  
Lulu Hu ◽  
Hui Huang ◽  
...  

10%CoO/g-C3N4 exhibits good photocatalytic performance under visible light irradiation without any sacrificial reagents.


2016 ◽  
Vol 52 (30) ◽  
pp. 5316-5319 ◽  
Author(s):  
Wenjie Fan ◽  
Haibo Li ◽  
Fengyi Zhao ◽  
Xujing Xiao ◽  
Yongchao Huang ◽  
...  

BiOI nanosheets with highly exposed (001) and surface disorders are used for efficient photocatalytic HCHO oxidation under visible light irradiation.


RSC Advances ◽  
2014 ◽  
Vol 4 (110) ◽  
pp. 64747-64755 ◽  
Author(s):  
Xuefeng Xu ◽  
Man Wang ◽  
Yanyan Pei ◽  
Changchun Ai ◽  
Liangjie Yuan

The micro/nano-structure composite SiO2@Ag/AgCl was employed as a low cost photocatalyst for the degradation of RhB in aqueous solution under visible light irradiation, which exhibited excellent photocatalytic performance and stability.


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