What can pKa and NBO charges of the ligands tell us about the water and thermal stability of metal organic frameworks?

2014 ◽  
Vol 2 (38) ◽  
pp. 16250-16267 ◽  
Author(s):  
Ping Lu ◽  
Yong Wu ◽  
Hong Kang ◽  
Haiyan Wei ◽  
Hongke Liu ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Metal Organic Frameworks ◽  
Heterocyclic Ligands ◽  
Carboxylate Ligands ◽  
Metal Organic ◽  
Thermal Stability Of ◽  
Nbo Charges

The pKa1 values and NBO charges of 32 carboxylate ligands and 31 N-heterocyclic ligands were calculated at 298.15 K with the B3LYP/6-31+G(d,p) level of calculations, which are useful to understand the water and thermal stability of Metal–Organic Frameworks (MOFs).

Thermal Stability of Metal–Organic Frameworks and Encapsulation of CuO Nanocrystals for Highly Active Catalysis

2018 ◽  
Vol 10 (11) ◽  
pp. 9332-9341 ◽  
Author(s):  
Hsuan-Lan Wang ◽  
Hsin Yeh ◽  
Yi-Chen Chen ◽  
Yen-Chih Lai ◽  
Chih-Yuan Lin ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Metal Organic Frameworks ◽  
Highly Active ◽  
Metal Organic ◽  
Cuo Nanocrystals ◽  
Thermal Stability Of

Improvement in Thermal Stability of Sucralose by γ-Cyclodextrin Metal-Organic Frameworks

2016 ◽  
Vol 34 (2) ◽  
pp. 269-278 ◽  
Author(s):  
Nana Lv ◽  
Tao Guo ◽  
Botao Liu ◽  
Caifen Wang ◽  
Vikaramjeet Singh ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Metal Organic Frameworks ◽  
Metal Organic ◽  
Thermal Stability Of

Encapsulation of enzyme into mesoporous cages of metal–organic frameworks for the development of highly stable electrochemical biosensors

2017 ◽  
Vol 9 (21) ◽  
pp. 3213-3220 ◽  
Author(s):  
Wanwan Chen ◽  
Wensheng Yang ◽  
Yanluo Lu ◽  
Wanjun Zhu ◽  
Xu Chen
Keyword(s):  
Thermal Stability ◽  
Metal Organic Frameworks ◽  
Electrochemical Biosensors ◽  
Metal Organic ◽  
Thermal Stability Of

The thermal stability of biosensors based on the confinement of an enzyme within MOFs was significantly improved.

Chemical and Thermal Stability of Isotypic Metal–Organic Frameworks: Effect of Metal Ions

2011 ◽  
Vol 17 (23) ◽  
pp. 6437-6442 ◽  
Author(s):  
In Joong Kang ◽  
Nazmul Abedin Khan ◽  
Enamul Haque ◽  
Sung Hwa Jhung
Keyword(s):  
Thermal Stability ◽  
Metal Ions ◽  
Metal Organic Frameworks ◽  
Metal Organic ◽  
Thermal Stability Of

The thermal stability of metal-organic frameworks

2020 ◽  
Vol 419 ◽  
pp. 213388 ◽  
Author(s):  
Colm Healy ◽  
Komal M. Patil ◽  
Benjamin H. Wilson ◽  
Lily Hermanspahn ◽  
Nathan C. Harvey-Reid ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Metal Organic Frameworks ◽  
Metal Organic ◽  
Thermal Stability Of

Porous homo- and heterochiral cobalt(II) aspartates with high thermal stability of the metal-organic framework

2010 ◽  
Vol 59 (4) ◽  
pp. 733-740 ◽  
Author(s):  
M. P. Yutkin ◽  
M. S. Zavakhina ◽  
D. G. Samsonenko ◽  
D. N. Dybtsev ◽  
V. P. Fedin
Keyword(s):  
Thermal Stability ◽  
Metal Organic Framework ◽  
High Thermal Stability ◽  
Metal Organic ◽  
Thermal Stability Of ◽  
Organic Framework
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